An automatic system for continuous monitoring of CO2, H2S, SO2 and meteorological parameters in the atmosphere of volcanic areas

An automatic system for the continuous monitoring of CO₂, H₂S, SO₂ and meteorological parameters in atmosphere has been developed. The system has been tested in the laboratory in order to verify the stability and reliability of each sensor and of the whole system. A field test for a period of one month, at the Solfatara of Pozzuoli has also been carried out. The acquired data during the field test reveal a correlation between the wind speed and the concentrations of CO₂, H₂S, and SO₂ in the atmosphere. With a wind speed of over 4 ms^-1 the concentration of the three gases reached constant background values of 600 ppm for CO₂ and about 2 ppm vol. for H₂S and SO₂. The different ratios of H₂S/SO₂ measured in the fumaroles (~100) and in the atmosphere (1–0.1) clearly indicate that H₂S is oxidized to SO₂ during the transport.     

Chemical composition of precipitation at Mt. Vesuvius and Vulcano Island,Italy: volcanological and environmental implications

Natural precipitation and water samples from passive devices were collected at Mt. Vesuvius and Vulcano Island, Italy, during the period 2004–2006, in order to investigate its possible interactions with fumarolic gases. Evidence of chemical reactions between fumarolic fluids and rain samples before and after its deposition into the sampling devices was found at Vulcano Island. Very low pH values (down to 2.5) and significant amounts of chlorine and sulfate (up to 22 mEq/l) were measured at sampling points located close to the fumarolic field. In contrast, anthropogenic contributions and/or dissolution of aerosols (both maritime and continental) influence the chemistry of rainwaters at Mt. Vesuvius, which show inter-annual variations that are highly consistent with those recorded at the coastal site at Vulcano Island. Chemistry of waters directly exposed to fumarolic fluids may then give useful information about its temporal evolution, holding the signal of the “maximum” chemical event occurred in the meanwhile. In addition, the observation of the health status of vegetation colonizing the immediate surroundings of the fumarolic fields, due to its strong dependence on the interactions with these fluids, may work as a possible biomarker of volcanic activity.     

Restricted rifting and its coexistence with compressional structures: results from the CROP 3 traverse (Northern Apennines, Italy)

A geological interpretation of the deep seismic reflection line CROP 3 (Italian program CROsta Profonda: deep crust, profile no. 3), which crosscuts the Northern Apennines from the Tyhrrenian to the Adriatic coast, is presented. The profile images the lithosphere up to 15 s TWT and highlights several peculiarities: (a) the lower crust is bedded by discontinuous sub parallel reflective markers which terminate at ≈ 7 s beneath the western side of the profile; (b) in the same area a notable reflection is recognizable at 10 s and is interpreted as the top of the asthenosphere; (c) east-plunging shear zones are recognizable throughout the crust. By contrast, the Adriatic (outer) side of this line shows: (a) reflections deepening westward, from 13 to 15 s TWT, related to the base of the crust (33–38 km depth); (b) the absence of thick bedding of reflective markers within the lower crust; and (c) tectonic structures affecting the basement which are different from those which deform the cover of the Northern Apennines. Geological interpretation is based on the eastward migration of ductile shear zones which have been recognized on the seismic line. The bending of the outer zone crust is considered to be a consequence of the rifting process with the application of pushing forces against the Adriatic lithosphere which cannot escape toward east.     

Extensional shear zones as imaged by reflection seismic lines: the Larderello geothermal field (central Italy)

The Larderello geothermal field is located in the Inner Northern Apennines, in an area which has been subject to extension since the Early Miocene. The latest extensional episode (Pliocene–Present) has resulted in the formation of NW-trending, NE-dipping listric normal faults, whose geometry is controlled down to 3 km by borehole data. In this paper, we integrate a new interpretation of seismic reflection lines with existing seismic, field, and borehole data to analyse the relations among listric normal faults, the top of the brittle–ductile transition, and the migration of geothermal fluids.In accordance with previous interpretations, we consider the strong reflector (K-horizon) marking the top of the reflective mid-lower crust, and located at a depth of 3–5 km in the geothermal area, to represent the top of the brittle–ductile transition. Its reflectivity most probably derives from the presence of overpressured fluids. We identify three main NW-trending, NE-dipping extensional brittle shear zones, showing listric geometry and soling out in the vicinity of the K-horizon. The latter appears to be dislocated in correspondence of the soling out of the shear zones. These shear zones, because of the associated intense fracturing, represent the most natural channels of upward migration of geothermal fluids from the magmatic sources located below the K-horizon.We suggest that these two conclusions—that listric normal faults root at or near the brittle–ductile transition, and that they act as preferential upward migration paths for magmatic fluids—may be of general validity for geothermal fields located in extensional settings.     

Migration of geothermal fluids in extensional terrains: the ore deposits of the Boccheggiano-Montieri area (southern Tuscany, Italy)

An integrated study based on fluid inclusion, δ¹⁸O composition and structural analyses was carried out on a Pliocene fossil hydrothermal system, located to the South of the present active Larderello geothermal field, in the Boccheggiano-Montieri area. The study area is typified by mineralized cataclastic levels related to Late Oligocene–Early Miocene thrust surfaces, and to the following two generations of normal faults of Miocene and Pliocene ages, respectively. Within the damage zone of the Pliocene Boccheggiano fault, the mineralization is mainly made up of quartz and pyrite. Quartz + Pb–Zn sulfides, or quartz + Pb–Zn sulfides + fluorite + carbonates assemblages occur instead in the older cataclastic levels. Two generations of liquid-rich fluid inclusions were recognized in quartz and fluorite: the first one, with homogenization temperatures ranging between 172 and 331°C and salinity between 0.0 and 8.8 wt.% NaCl_equiv., records the early stage of hydrothermal activity. The second generation of fluid inclusions documents a later stage, with homogenization temperature from 124 to 288°C and salinity from 0.2 to 1.9 wt.% NaCl_equiv.. Fluid inclusions analyses also indicate that mixing of fluid with distinct salinities and/or temperatures was a widespread process during the early stage, and that fluid temperatures decreased moving from the Boccheggiano fault toward the more distal and older cataclastic levels. The δ¹⁸O values of water in equilibrium with hydrothermal quartz, which range from −5.7 to −0.1‰, are related to the circulation of meteoric water mixed with saline water that leached the evaporite level and enriched in δ¹⁸O through water–rock interaction, and/or with magmatically derived fluids. Results indicate that the damage zone of the Pliocene Boccheggiano fault represented the main channel for the flow of meteoric water, which was heated at depth, then mixed with high salinity fluids, and finally ascend to infiltrate along the older cataclastic levels. Our results, based on fluid inclusions, oxygen isotopic compositions and structural analyses indicate that a single fluid flow path run through the damage zone of the Boccheggiano fault and the older cataclasites, which were thus hydraulically connected.     

Multiparametric Approach in Investigating Volcano-Hydrothermal Systems: the Case Study of Vulcano (Aeolian Islands, Italy)

Seismic activity, ground deformation, and soil and fumarole temperatures acquired during 2004–2007 at Vulcano (Aeolian Islands) are analysed and the time relations among the different time series are discussed. Changes in temperature of fumarolic gases took place during four “anomalous” periods (November 2004–March 2005; October 2005–February 2006; August–October 2006; July–December 2007) at the same time as an increasing number of volcano-seismic events. In particular, the temperatures at high temperature vents and at steam heated soil ranged in time from 180 to 440°C and from 20 to 90°C, respectively. The maximum daily number of volcano-seismic events was 57, reached during the second anomalous period. This seismicity, characterised by focal depth generally lower than 1?km below sea level (b.s.l.) and composed of different kinds of events associated to both resonance and shear failure processes, is related to the shallow dynamics of the hydrothermal system. During the analysed period, very few volcano-tectonic earthquakes took place and tilt recordings showed no sharp or important changes. In light of such observations, the increases in both temperature and volcano-seismic events number were associated to increases in the release of gas from a deep and stable magma body, without magma intrusions within the shallow hydrothermal system. Indeed, a greater release of gas from depth leads to increased fluid circulation, that can promote increases in volcano-seismic events number by both fracturing processes and resonance and vibration in cracks and conduits. The different trends observed in the measured geochemical and geophysical series during the anomalous periods can be due to either time changes in the medium permeability or a changing speed of gas release from a deep magma body. Finally, all the observed variations, together with the changing temporal distribution of the different seismic event kinds, suggest that the hydrothermal system at Vulcano can be considered unsteady and dynamic.     

Pressure–temperature evolution of the late Hercynian Calabria continental crust: compatibility with post‐collisional extensional tectonics

The late Hercynian tectonic evolution of the Calabria crust is characterized by peak metamorphic conditions up to 800 °C and 1000 MPa, and coeval mid‐crustal granitoid emplacement at 304–300 Ma. To check if a post‐collisional extensional framework, similar to that of other Hercynian massifs, can explain petrologic data, we model the pressure–temperature evolution of the crust during extension following granitoid emplacement. Model parameters are constrained by petrologic, geochemical and structural data. Computed P–T paths are characterized by nearly isothermal decompression followed by isobaric cooling, which show a good fit to petrologic P–T paths for duration of extension between 5 and 10 Ma. The model results, therefore, support an interpretation of the magmatic and metamorphic evolution of the Calabria crust in terms of the late Hercynian extension. In this framework, slab break‐off is a reasonable explanation for the common evolution of the southern European Hercynian massifs.     

A novel pilot scale multistage semidry anaerobic digestion reactor to treat food waste and cow manure

An innovative two-stage AD system to treat food waste with cow manure is presented to address the problem of ammonia inhibition and improve the stability of methanogenic reactor. The liquid digestate recirculation in the first phase was adopted to enhance the hydrolysis rate and the solubilization of organic matter. A stable long-term run (80 days) was found. The reactor configuration and the digestate post-treatment with natural zeolite led to a low ammonia concentration in reactor outlet. The biogas production in the methanogenic reactor was very stable and high: The specific biogas production in the second phase was equal to 0.68–0.92 Nm³/kg_TVSadded and the average methane concentration was equal to 85%. Good performances were also found for the first-stage digestate, with 75% soluble COD removal efficiency. The high reactor performances were related to two-stage configuration, no ammonia and VFA inhibition.     

Sb–Hg ore deposit distribution controlled by brittle structures: The case of the Selvena mining district (Monte Amiata, Tuscany, Italy)

This paper deals with the tectonic control on the hydrothermal system that gave rise to Sb–Hg ore deposits in the Monte Amiata area that was one of the most relevant mining district for the exploitation of mercury in Italy. The study area (Selvena mining district) is located in southern Tuscany (inner Northern Apennines) one of the most important mineralized area in the western Mediterranean region. Southern Tuscany was severely affected by Middle–Late Miocene low-angle normal faults, later dissected by Pliocene–Pleistocene faults, coeval magmatism (Late Miocene–Pleistocene) and hydrothermal activity (Pliocene–Present). The Selvena mining district is located south of Middle Pleistocene Monte Amiata volcanic complex. Our structural and kinematic study is based on the integration among fieldwork, borehole and mine data. The results highlight two Pleistocene–Holocene left-lateral transtensional shear zones linked by normal faults, defining a coeval pull-apart structure. Here, the Sb–Hg mineralization, transported by meteoric hydrothermal fluids mainly, is particularly diffuse and concentrated in the cataclasites and in damage zones of the normal faults. Furthermore, a widespread mineralization also occurs in the cataclasites of Miocene low-angle normal faults. Mine evidence suggests that ore-bearing fluids percolated through structural conduits located along the fault planes and resulting parallel to the intermediate stress axis. Geological structures and ore deposit distribution are related to a single hydrothermal circuit, with meteoric water channelled to depth through conduits parallel to the intermediate stress axis of the transcurrent shear zones; then, hydrothermal fluids mainly ascended through the almost vertical deformation zones located at the intersection between normal and strike-slip faults. Thus, hydrothermal fluids permeated also the Middle–Late Miocene cataclasites. This study shed light on the relationships between geological structures and mineralization in southern Tuscany and underlines the importance to investigate mine areas to understand hydrothermal fluids path.