Fluid flow reconstruction in karstified Panormide platform limestones (north-central Sicily): Implications for hydrocarbon prospectivity in the Sicilian fold and thrust belt

Diagenetic analysis based on field and petrographic observations, isotope and microthermometric data was used to reconstruct the fluid flow history of the Cretaceous shallow water limestones from the Panormide platform exposed in north-central Sicily. Analysis focused on diagenetic products in cavities and dissolution enlarged fractures of the karstified limestones that occur just below a regional unconformity. The fluid flow history could be broken down into five stages that were linked to the kinematic and burial history of the region. (1) Petrography (zoned cathodoluminescence and speleothem textures) and stable isotopes (6.5 < δ¹⁸O_V-PDB < ?3.5‰ and 0 < δ¹³C_V-PDB < ?14‰) indicate that the earliest calcite phase was associated with karstification during emergence of the platform. Limestone dissolution at this stage is important with regard to possible reservoir creation in the Panormide palaeogeographic domain. (2) Fine-grained micrite sedimentation, dated as latest Cretaceous by nannopalaeontology and its ⁸⁷Sr/⁸⁶Sr isotope ratio (0.7078), marks replacement by marine fluids during subsequent submergence of the karstified platform. (3) The following calcite cement was still precipitated by marine-derived fluids (?7.0 < δ¹⁸O_V-PDB < ?5.0‰ and ?3.0 < δ¹³C_V-PDB < 0.5‰/T_m = ?2 to ?5 °C), but at increasingly higher temperatures (T_h = 60–120 °C). This has been interpreted as precipitation during Oligocene foredeep burial. (4) Hot (T_h = 130–180 °C), low saline (T_m < ?2.5 °C) fluids with increasingly higher calculated δ¹⁸O_SMOW signatures (+6 to +14‰) subsequently invaded the karst system. These fluids most likely migrated during fold and thrust belt development. The low salinity and relatively high δ¹⁸O_SMOW signatures of the fluids are interpreted to be the result of clay dewatering reactions. The presence of bitumen and associated fluorite with hydrocarbon inclusions at this stage in the paragenesis constrains the timing of oil migration in the region. (5) Finally, high saline fluids with elevated ⁸⁷Sr/⁸⁶Sr (0.7095–0.7105) signatures invaded the karst system. This last fluid flow event was possibly coeval with localized dolomitization and calcite cementation along high-angle faults of Pliocene age, as suggested by identical radiogenic signatures of these diagenetic products.     

Gully-head morphology and implications for gully development on abandoned fields in a semi-arid environment,Sierra de Gata,southeast Spain

In this paper we examine whether gully-head morphology can be used as an indicator for gully development and, hence, for sediment production. A survey was conducted at five hillslopes in the Sierra de Gata where different types of channel heads occur close to each other. The survey included measurements of morphologic and pedologic properties, ground surface, channel and catchment characteristics of every gully head present (n = 59). On the basis of the observed morphologies, the heads were subdivided into four types: gradual, transitional (a short inclined section), abrupt and rilled-abrupt. The analyses showed that it is possible to explain the differences of gully heads and the role of some environmental factors on the basis of their morphologies, at least for the gradual and the abrupt types. The results suggested that steep headcuts (abrupt) were formed from secondary headcuts in the channel, which migrated upstream. The abrupt headcuts were always formed in more than one soil layer of which one was a resistant (stony) layer. However, shear strength measurements (at saturation) showed that the top layer was not always the most resistant one. Width–depth relationships indicated that gradual type headcuts were controlled by fluvial processes and abrupt headcuts by a combination of fluvial and mass-wasting processes. Gradual types occurred more downslope than the abrupt types suggesting that the incisions started by fluvial processes and migrated upwards when knickpoints developed in the channel. The rilled-abrupt types are still actively retreating. Thus, the abrupt types correspond to slower retreat rates. Abrupt gully heads may deteriorate into transitional types when plunge-pool erosion becomes less effective. The conceptual model is supported by data from ephemeral gullies in two other study areas (Sierra de la Torrecilla, Spain, and Alentejo, Portugal). Copyright © 1999 John Wiley & Sons, Ltd.     

Regional mapping and characterisation of old landslides in hilly regions using LiDAR-based imagery in Southern Flanders

Analysis of LiDAR-derived imagery led to the discovery of more than 330 pre-Holocene to recent landslides in Southern Flanders (4850 km²). The morphology of three landslides, including the 266.5 ha deep-seated gravitational slope deformation in Alden Biesen, was investigated in more detail. The analysis of the morphological and topographical characteristics (width–length relation, frequency–area distribution and topographical threshold) of the landslides revealed important differences compared to the characteristics reported in other landslide studies, and helped understanding possible landslide triggering mechanisms. Especially the possibility of a seismic origin of the landslides was investigated. Finally, a heuristic model for region-wide landslide susceptibility mapping was successfully tested. The susceptibility model and map allow prediction of future landslide locations and contribute to better understanding the role of individual causal factors on landslide location and spatial density. The results suggest that landslides on low-gradient, soil-mantled hills are a more important contributor to landscape evolution of hilly areas than was hitherto thought. The morphology of all hilly regions of Flanders is clearly marked by landslide processes and higher landslide densities often coincide with the presence of quaternary active faults. This study further shows that high-resolution topographical data such as LiDAR significantly contributes to a better detection of old, previously unknown landslides.     

Fluid flow reconstruction in hanging and footwall carbonates: Compartmentalization by Cenozoic reverse faulting in the Northern Oman Mountains (UAE)

In this paper, the diagenesis from either side of a major Cenozoic reverse fault in the Northern Oman Mountains is documented. Detailed petrographical and geochemical analysis of calcite-filled fractures in carbonate strata of Late Triassic and Early Cretaceous age in the hanging wall and footwall in Wadi Ghalilah reflect a different diagenetic history. In both hanging wall and footwall most of the fractures are pre-burial, extensional in origin, formed by a crack-seal mechanism, and the calcite vein infill has a host-rock buffered signature. In the hanging wall, the fluid responsible for calcite precipitation of these extensional fractures was a marine fluid at 60 °C. These veins predate deep burial and contractional tectonic deformation and consequently do not provide any information about syntectonic fluid flow. Neither do the pre-burial extension fractures in the footwall which are also host-rock buffered. The fractures post-dating the tectonic stylolitization in the footwall, by contrast, show evidence of syntectonic migration of saline formation waters at temperatures between 80 and 160 °C during contractional deformation. These fluids probably were sourced from the subsurface via the reverse fault, which acted as a fluid conduit. At the same time, however, this fault functioned as a permeability barrier towards the hanging wall, since no evidence of syntectonic fluid flow is present here. In this way compartmentalization of the hanging wall and footwall block was realized.     

Paleo-fluids characterisation and fluid flow modelling along a regional transect in Northern United Arab Emirates (UAE)

In the Northern Emirates, Jurassic and Lower Cretaceous platform carbonates of the Musandam parautochthonous units are tectonically overlain by siliciclastic units of the Hawasina–Sumeini allochthon, which derive from the former paleo-slope domain and a more distal basinal portion of the Arabian margin of the Tethys, respectively. All these tectonic units display numerous evidences of paleo-fluid circulations, accounting for dolomitisation and recrystallisation of the rock matrix (Musandam Platform units), as well as cementation of fractures. Polymict breccias of Upper Cretaceous Ausaq Formation which underlay the sole thrust of the Hawasina–Sumeini allochthon also record episodes of hydraulic fracturing, whereas fluid inclusion data indicate precipitation at high temperature in relation to paleo-fluid flow. Petrography of thin-sections (conventional and cathodoluminescence microscopic techniques) as well as fluid inclusion and stable isotopes analyses, were combined with micro-tectonic studies. These analytical data document (1) the paragenetic sequence of diagenetic products for the Musandam Platform (which constitutes a carbonate reservoir analogue) and Sumeini units of the Dibba Zone, as well as (2) the nature of the paleo-fluids circulating along fractures and the sole thrust of the Hawasina–Sumeini allochthon. The main results of this petrographic approach are qualitative, evidencing (1) the rapid and vertical transfer of hot fluids in the vicinity of the former slope to platform transition, accounting for episodes of hydrothermal dolomitisation, as well as (2) early (i.e. pre-orogenic) and late (i.e. post-orogenic) episodes of emersion of the carbonate units, accounting for additional interactions with meteoric fluids and karstification. In order to better link these diagenetic events with the overall burial, thermal and kinematic evolution of the Arabian margin, basin modelling with Ceres2D, including fluid flow and pore-fluid pressure modelling, was subsequently performed along a regional transect (D4) located in the vicinity of the samples localities and cross-cutting the Northern Oman Mountains from Dibba in the east up to the Arabian Gulf in the west. New subsurface constraints provided by deep seismic profiles were used to constrain the architecture of the cross-section, and to test various hypotheses on the lateral and vertical connection, timing and hydrodynamic behaviour of the faults. This Ceres basin modelling also provides new quantitative estimates of the paleo-fluid pathways, of the timing and velocities of the fluid transfers and of the evolution of pore-fluid pressures. Ultimately, this integration of petrographic studies on surface samples and coupled kinematic and fluid flow basin modelling provides an updated scenario for the succession of tectonically controlled episodes of fluid rock interactions, namely dolomitisation and karstification recorded in the Mesozoic platform carbonates of the Northern Emirates.     

Occurrence of anthropogenic and naturally-produced organohalogenated compounds in tissues of Black Sea harbour porpoises

Harbour porpoises are one of the three cetacean species inhabiting the Black Sea. This is the first study to report on polybrominated diphenyl ethers (PBDEs) and naturally-produced compounds, methoxylated PBDEs (MeO-PBDEs) and polybrominated hexahydroxanthene derivatives (PBHDs), in tissues (kidney, brain, blubber, liver, muscle) of male harbour porpoises (11 adults, 9 juveniles) from the Black Sea. Lipid-normalized concentrations decreased from muscle > blubber > liver > kidney > brain for the sum of polychlorinated biphenyls (PCBs) and for the sum of PBDEs. Among the naturally-produced compounds, levels of PBHDs were higher than of MeO-PBDEs, with tri-BHD and 6-MeO-BDE 47 being the dominant compounds for both groups, respectively. Concentrations of naturally-produced compounds decreased from blubber to brain, similarly to the sum of DDT and metabolites (DDXs). Concentrations of DDXs were highest, followed by PCBs, HCB, PBHDs, PBDEs and MeO-PBDEs. Levels of PCBs and PBDEs in blubber were lower than concentrations reported for harbour porpoises from the North Sea, while concentrations of DDXs were higher.