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排序方式: 共有462条查询结果,搜索用时 250 毫秒
1.
Non‐equilibrium concepts lead to a unified explanation of the formation of chondrules and chondrites
Milton BLANDER Arthur D. PELTON In‐Ho JUNG Richard WEBER 《Meteoritics & planetary science》2004,39(12):1897-1910
Abstract— Calculations of the formation of seven types of chondrules in Semarkona from a gas of solar composition were performed with the FACT computer program to predict the chemistries of oxides (including silicates), developed by the authors and their colleagues. The constrained equilibrium theory was used in the calculations with two nucleation constraints suggested by nucleation theory. The first constraint was the blocking of Fe and other metal gaseous atoms from condensing to form solids or liquids because of very high surface free energies and high surface tensions of the solid and liquid metals, respectively. The second constraint was the blocking of the condensation of solids and the formation of metastable liquid oxides (including silicates) well below their liquidus temperatures. Our laboratory experiments suggested subcooling of type IIA chondrule compositions of 400 degrees or more below the liquidus temperature. The blocking of iron leads to a supersaturation of Fe atoms, so that the partial pressure of Fe (pFe) is larger than the partial pressure at equilibrium (pFe(eq)). The supersaturation ratio S = pFe/pFe(eq) becomes larger than 1 and increases rapidly with a decrease in temperature. This drives the reaction Fe + H2O ? H2 + FeO to the right. With S = 100, the activity of FeO in the liquid droplet is 100 times as large as the value at equilibrium. The FeO activities are a function of temperature and provide relative average temperatures of the crystallization of chondrules. Our calculations for the LL3.0 chondrite Semarkona and our study of some non‐equilibrium effects lead to accurate representations of the compositions of chondrules of types IA, IAB, IB, IIA, IIAB, IIB, and CC. Our concepts readily explain both the variety of FeO concentrations in the different chondrule types and the entire process of chondrule formation. Our theory is unified and could possibly explain the formation of chondrules in all chondritic meteorites as well as provide a simple explanation for the complex chemistries of chondrites, and especially for type 3 chondrites. 相似文献
2.
Ho Il Yoon Myung Woo Han Byong-Kwon Park Jae-Kyung Oh Soon-Keun Chang 《Marine Geology》1997,140(3-4):265-282
High-resolution (3.5 kHz and multi-channel) seismic profiles and piston cores were collected from Maxwell Bay and its tributary embayment, Marian Cove, in the South Shetland Islands, Antarctica, during the Korea Antarctic Research Program (1992/93 and 1995/96) to elucidate the glaciomarine sedimentation processes and recent glacial history of the area. Seismic data from Maxwell Bay reveal a rugged bay margin and flattened basin floor covered with well-stratified hemipelagic muds. On the base-of-slope, acoustically transparent debris flows occur, indicating downslope resedimentation of glaciomarine sediments. Despite the subpolar and ice-proximal settings of Marian Cove, the seafloor is highly rugged with a thin sediment drape, suggesting that much of the area has been recently eroded by glaciers. Sediment cores from the cove penetrated three distinct fining-upward lithofacies: (1) basal till in the lower part of the core, accumulated just seaward of the grounding line of the tidewater glacier; (2) interlaminated sand and mud in the middle part, deposited in ice-proximal zone by a combination of episodic subglacial meltwater inflow and iceberg dumping; and (3) pebbly mud in the upper part, deposited in ice-distal zone by both surface meltwater plume and ice-rafting from the glacier front. A reconstruction of the glacial history of these areas since the late glacial maximum shows an ice sheet filling Maxwell Bay in late Wisconsin time and grounding of the tidewater glacier in Marian Cove until about 1300 yr BP. 相似文献
3.
At the circular Babi Island in the Flores tsunami (1992) and pear shaped island in the Okushiri event (1993), unexpectedly large tsunami run‐up heights in the lee of conic islands were observed. The flume and basin physical model studies were conducted in the Coastal Hydraulic Laboratory, Engineering Research and Development Center, U.S. Army Corps of Engineers to provide a better understanding of the physical phenomena and verify numerical models used in predicting tsunami wave run‐up on beaches, islands, and vertical walls. Reasonably accurate comparison of run‐up height of solitary waves on a circular island has been obtained between laboratory experimental results and two‐dimensional computation model results. In this study we apply three‐dimensional RANS model to simulate wave run‐up on conical island. In the run‐up computation we obtain that 3D calculations are in very good comparison with laboratory and 2D numerical results. A close examination of the three‐dimensional velocity distribution around conical island to compare with depth‐integrated model is performed. It is shown that the velocity distribution along the vertical coordinate is not uniform: and velocity field is weaker in the bottom layer and higher on the sea surface. The maximum difference (about 40%) appears at the time when solitary wave reached the circular island. 相似文献
4.
J. C. Kurtz N. D. Detenbeck V. D. Engle K. Ho L. M. Smith S. J. Jordan D. Campbell 《Estuaries and Coasts》2006,29(1):107-123
Coastal ecosystems are ecologically and commercially valuable, productive habitats that are experiencing escalating compromises
of their structural and functional integrity. The Clean Water Act (USC 1972) requires identification of impaired water bodies
and determination of the causes of impairment. Classification simplifies these determinations, because estuaries within a
class are more likely to respond similarly to particular stressors. We reviewed existing classification systems for their
applicability to grouping coastal marine and Great Lakes water bodies based on their responses to aquatic stressors, including
nutrients, toxic substances, suspended sediments, habitat alteration, and combinations of stressors. Classification research
historically addressed terrestrial and freshwater habitats rather than coastal habitats. Few efforts focused on stressor response,
although many well-researched classification frameworks provide information pertinent to stressor response. Early coastal
classifications relied on physical and hydrological properties, including geomorphology, general circulation patterns, and
salinity. More recent classifications sort ecosystems into a few broad types and may integrate physical and biological factors.
Among current efforts are those designed for conservation of sensitive habitats based on ecological processes that support
patterns of biological diversity. Physical factors, including freshwater inflow, residence time, and flushing rates, affect
sensitivity to stressors. Biological factors, such as primary production, grazing rates, and mineral cycling, also need to
be considered in classification. We evaluate each existing classification system with respect to objectives, defining factors,
extent of spatial and temporal applicability, existing sources of data, and relevance to aquatic stressors. We also consider
classification methods in a generic sense and discuss their strengths and weaknesses for our purposes. Although few existing
classifications are based on responses to stressors, may well-researched paradigms provide important information for improving
our capabilities for classification, as an investigative and predictive management tool. 相似文献
5.
Core A9-EB2 from the eastern Bransfield Basin, Antarctic Peninsula, consists of pelagic (diatom ooze-clay couplets and bioturbated diatom ooze) and hemipelagic (bioturbated mud) sediments interbedded with turbidites (homogeneous mud and silt–clay couplets). The cyclic and laminated nature of these pelagic sediments represents alternation between the deposition of diatom-rich biogenic sediments and of terrigenous sediments. Sediment properties and geochemical data explain the contrasting lamination, with light layers being finer-grained and relatively rich in total organic carbon and biogenic silica content. Also, the high-resolution magnetic susceptibility (MS) variations highlight distinct features: high MS values coincide with clastic-rich sections and low MS values correspond to biogenic sections. The chronology developed for core A9-EB2 accounts for anomalous ages associated with turbidites and shows a linear sedimentation rate of approximately 87 cm/103 yr, which is supported by an accumulation rate of 80 cm/103 yr calculated from 210Pb activity. The late Holocene records clearly identify Neoglacial events of the Little Ice Age (LIA) and Medieval Warm Period (MWP). Other unexplained climatic events comparable in duration and amplitude to the LIA and MWP events also appear in the MS record, suggesting intrinsically unstable climatic conditions during the late Holocene in the Bransfield Basin of Antarctic Peninsula. 相似文献
6.
Drought in Bulgaria is analyzed from the multiple viewpoints of statistical occurrence, spatial patterns, and synoptic conditions.
A new index of drought, the SD (spatial-dryness) index, characterizes drought by both intensity and spatial extent. The occurrence of the SD index is analyzed using global
gridded data sets. Examination of transitional probabilities of multiple months and years with drought occurrence suggests
persistence is sufficiently frequent to be important for climate-related environmental planning. Finally, it is shown that
specific seasonal synoptic patterns are associated with wet and dry conditions in Bulgaria.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
7.
A chemiresistor microchemical sensor has been developed to detect and monitor volatile organic compounds in unsaturated and saturated subsurface environments. A controlled study was conducted at the HAZMAT Spill Center at the Nevada Test Site, where the sensor was tested under a range of temperature, moisture, and trichloroethylene (TCE) concentrations. The sensor responded rapidly when exposed to TCE placed in sand, and it also responded to decreases in TCE vapor concentration when clean air was vented through the system. Variations in temperature and water vapor concentration impacted baseline chemiresistor signals, but at high TCE concentrations the sensor response was dominated by the TCE exposure. Test results showed that the detection limit of the chemiresistor to TCE vapor in the presence of fluctuating environmental variables (i.e., temperature and water vapor concentration) was on the order of 1000 parts per million by volume, which is about an order of magnitude higher than values obtained in controlled laboratory environments. Automated temperature control and preconcentration is recommended to improve the stability and sensitivity of the chemiresistor sensor. 相似文献
8.
Tai Ho Choo Soo Kwon Chae Hyeon Cheol Yoon Yeon Moon Choo 《Environmental Earth Sciences》2014,71(2):675-683
Discharge is an important factor in river design for water utilization, water control and hydraulic structures; therefore, an accurate estimation of the discharge is required. At present, a rating curve depicting the relationship between a stage and discharge is used to calculate the discharge from river systems. Although the rating curve has an advantage in that it can predict and use the discharge during the flood season in which the measurement is difficult, there is room for improvement as it does not reflect the hydraulic characteristics of rivers. Therefore, in this study, discharge was predicted using the convenient calculation method with empirical mediating variables of the Manning and Chezy equations which were proposed by the author’s previous research as a new methodology for estimating discharge in an open channel. This was proven, based on the data measured in a meandering open channel system in a lab at the Mississippi River in the US and at the Columbia Del Dique Canal, and an accuracy level at a coefficient of 0.8 was demonstrated. Thus, this method, which reflects the hydraulic characteristics and predicts the discharge in a simple manner, is expected to be convenient in practice. 相似文献
9.
Sequential extraction and leaching characteristics of heavy metals in abandoned tungsten mine tailings sediments 总被引:1,自引:0,他引:1
Pyeong-Koo Lee Min-Ju Kang Ho Young Jo Sang-Hoon Choi 《Environmental Earth Sciences》2012,66(7):1909-1923
The chemical speciation of potentially toxic elements (As, Cd, Cu, Pb, and Zn) in the contaminated soils and sulfides-rich tailings sediments of an abandoned tungsten mine in Korea was evaluated by conducting modified BCR sequential extraction tests. Kinetic and static batch leaching tests were also conducted to evaluate the potential release of As and other heavy metals by acidic rain water and the leaching behaviors of these heavy metals. The major sources of the elements were As-, Zn- and Pb-bearing sulfides, Pb carbonates (i.e., cerussite), and Pb sulfates (i.e., anglesite). The biggest pollutant fraction in these soil and tailing samples consists of metals bound to the oxidizable host phase, which can be released into the environment if conditions become oxidative, and/or to residual fractions. No significant difference in total element concentrations was observed between the tailings sediments and contaminated soils. For both sample types, almost no changes occurred in the mobility of As and the other heavy metals at 7 days, but the mobility increased afterwards until the end of the tests at 30 days, regardless of the initial pH. However, the mobility was approximately 5–10 times higher at initial pH 1.0 than at initial pHs of 3.0 and 5.0. The leached amounts of all the heavy metal contents were higher from tailings sediments than from contaminated soils at pH > 3.0, but were lower at pH < 3.0 except for As. Results of this study suggest that further dissolution of heavy metals from soil and tailing samples may occur during extended rainfall, resulting in a serious threat to surface and groundwater in the mine area. 相似文献
10.
Hydrometallurgical processing and recovery of molybdenum trioxide from spent catalyst 总被引:5,自引:0,他引:5
Kyung Ho Park B. Ramachandra Reddy D. Mohapatra Chul-Woo Nam 《International Journal of Mineral Processing》2006,80(2-4):261-265
Hydrometallurgical processing of spent hydrodesulphurisation (HDS) catalyst for the recovery of molybdenum using sodium carbonate and hydrogen peroxide mixtures was investigated. The results indicated that the recovery of molybdenum was largely dependent on the concentrations of Na2CO3 and H2O2 in the reaction medium, which controls the acidity of the leach liquor and carry over of impurities such as Al, Ni, P, Si and V. Leaching process was exothermic and leaching efficiency of molybdenum decreased with increasing solid to liquid ratio. Large scale leaching of spent catalyst, under optimum conditions: 20% pulp density, 85 g/L Na2CO3, 10 vol.% H2O2 and 1 h reaction, resulted a leaching efficiency of 84% Mo. The obtained leach liquor contained (g/L): Mo — 22.0, Ni — 0.015 and Al — 0.82, P — 1.1, Si — 0.094 and minor quantities of V — 8 mg/L, As and Co — < 1 mg/L. Recovery of Mo from leach solution as MoO3 of 97.30% purity was achieved by ammonium molybdate precipitation method. 相似文献