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1.
The problem of the diversity of the geochemical types of carbon dioxide waters (CDW) in petrografically and mineralogically uniform crystalline rock masses is solved with allowance made for the effect of different boundary conditions (physicochemical parameters) on the geochemical effect of interaction in the rock–water system. The formation of the entire geochemical spectrum of CDW in crystalline rock masses is shown to be explicable on the basis of a model of interaction in granite–water systems at different mass ratios of reacting rock (S) and water (L), different temperatures T, and equilibrium concentrations of dissolved CO2 (P
CO2). 相似文献
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Synthesis of regime observations of groundwater quality at deposits under operation and thermodynamic modeling of the geochemical interaction processes that govern the groundwater chemistry were used to recognize the geochemical causes and processes that bring about an increase in the groundwater fluorine content during water withdrawal accompanied by groundwater level drop and partial drying of the aquifer. The causes of the invalidity of previous forecasts are established. 相似文献
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N. S. Bortnikov V. M. Novikov A. D. Savko N. M. Boeva E. A. Zhegallo E. B. Bushueva A. V. Krainov D. A. Dmitriev 《Lithology and Mineral Resources》2013,48(5):384-397
This paper reports the results of precision structural-morphological study of kaolinite from clayey rocks taken in various areas of the Voronezh anteclise subjected to different stages of lithogenesis: primary kaolins of the weathering crust, proluvial-talus and lacustrine secondary kaolins, as well as lacustrine-swampy fireproof and deltaic-lagoonal refractory clays. The clayey material was transported over more than 300 km. The formation of the fireproof and refractory kaolin deposits in the Voronezh anteclise was related to the Devonian and Early Cretaceous stages of the geological evolution of the region. In terms of spatiotemporal and facies features, the studied genetic series of the kaolin clay deposits is unique. It was established that the sequential structural-morphological evolution o kaolinite in the considered deposits was caused by its mechanical disintegration during transport and redeposition. Interrelation between organic and mineral matters in the fireproof clays was revealed for the first time. Experimental studies of the behavior of kaolinite during sequential grinding and heating confirmed the main reasons for its natural degradation. The formation of virtually monomineral kaolin clays was provoked by the “flow-through” diagenesis, which is similar to weathering in trend. Evolution of mineral matter of the considered genetic series in kaolinite clay deposits was accompanied by the increase of δ18O values and their dispersion. Peculiarities identified in the behavior of kaolinite and related oxygen isotope characteristics of different-aged denudation and redeposition products of the Devonian weathering crust can play an indicator role in studying different stages of the lithogenesis of clayey rocks. 相似文献
4.
N. S. Bortnikov A. D. Savko V. M. Novikov N. M. Boeva S. V. Soboleva E. A. Zhegallo D. I. Dmitriev A. V. Krainov A. P. Zhukhlistov E. B. Bushueva 《Lithology and Mineral Resources》2016,51(6):425-438
This paper reports the results of our recent studies and generalizes previously known data on the geology, mineralogy, geochemistry, and genesis of the Russia’s largest Latnenskoe refractory clay deposit. It is shown that conditions of its localization were defined by regional and local factors. The regional factors controlled the distribution of the clay raw material in the region, while the local factors were responsible for the genesis and composition of refractory clays of the Latnenskoe deposit. Our studies showed that the formation of refractory clays is not only related to terrigenous but also to authigenic processes of sedimentation. The terrigenous component of clays was formed by the erosion of kaolin weathering crusts of the Voronezh anteclise crystalline basement and Paleozoic sedimentary hydromica–kaolinite rocks. Authigenic processes were significantly contributed by organic matter, which determined the environmental pH and Eh parameters. It is established that the mineral matter of clays of the deposit is represented by three morphological modifications (crystalline, amorphous, and biomorphic), which were formed subsequently and (or) simultaneously and could be transformed into each other. Application of a complex of modern precision methods allowed us to reveal a previously unknown biomorphic modification of kaolinite, the major rock-forming mineral, as well as mixed-layer kaolinite-smectite in the clays. It is shown that the distribution of major and trace elements and the sulfur isotope composition in different technological types of clay depend mainly on the facies conditions of their formation. Technological properties of clay raw material are considered. 相似文献
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6.
Ore mineralization is formed by postsedimentary (concentrated by evaporation to stage SW2) chloride brines metamorphosed in hydrogeochemical systems that are closed with respect to CO2, evolve according to “calcic” trend, and have high 2mCa2+ > mHCO 3 ? + 2mCO 3 2? ratios. In these situations at high R/W ratios (10–100) and temperatures (100–200°C), these brines concentrate ore elements (Zn, Pb, Fe, and Mn) that are geochemical analogues of Ca. The sulfide precipitation of these elements occurs under the effect of carbonate rocks at the abiogenic sulfate reduction of S(VI) of the original brines at low Eh values, which are created in carbonate rocks at higher (>100°C) temperatures. This origin of sulfide mineralization is intensified at decreasing R/W ratios during the dilution of the original brines by elision waters and an increase in the temperature. The hydrodynamics of these ore-forming brines is controlled by the elision hydrogeological regime, which is defined in hydrogeological structures by the geostatic pressure. The brines migrate into the zones of geochemical barriers during the relaxation of hydrogeological structures toward their equilibrium hydrostatic state. Hydrogeological structures, optimal for the precipitation of ore mineralization, are hydrodynamically active and able to maintain a steady (during 105-106 years) inflow of ore-forming brines into the zones of geochemical barriers and the maximum number of water-exchange cycles at these barriers. Modern analogues of these structures are miogeosyncline foredeeps with Cl-Na-Ca chloride brines with high concentrations of ore elements and overall flow rates ranging from 0.n to n m3/year. Stagnate hydrogeological platform structures in hydrostatic equilibrium cannot ensure water exchange needed for ore formation, and, hence, the brines of these structures are not able to deposit the ore elements contained in them, in spite of the high concentrations of these elements. 相似文献
7.
Shchetnikov A. A. Bezrukova E. V. Kerber E. V. Belozerova O. Yu. Kuzmin M. I. Ivanov E. V. Krainov M. A. Filinov I. A. Nechaev I. O. 《Doklady Earth Sciences》2019,486(1):503-506
Doklady Earth Sciences - The first results of tephrochronological studies of Late Pleistocene–Holocene volcanic eruptions in the Zhom-Bolok River valley (Eastern Sayan) are reported. Based on... 相似文献
8.
Based on the synthesis of hydrogeochemical materials on Sb occurrence in carbonate and thermal waters and thermodynamic simulations, genetic analysis was conducted of the transformations of probable Sb migration species (particularly oxygen-bearing and sulfide ones), and their transformations were calculated depending on the main parameters of hydrogeochemical systems (\(P_{CO_2 } \), T, R/W, Eh, and pH). The oxygen 2HSbO 2 0 + 3H2S = Sb2S3 + 4H2O (2SbO 2 ? + 3HS? + 5H+ = Sb2S3 + 4H2O) and sulfide HSb2S 4 ? + H+ = Sb2S3 cr + H2S (Sb2S 4 2? + 2H+ = Sb2S3cr + H2S) models for the genesis of hydrogenic Sb2S3(cr) were simulated. Information on occurrences of carbonate and thermal waters in various regions worldwide was generalized, and the reasons were identified for the geochemical separation of As and Sb in carbonate and thermal waters. The causes and conditions of an increase in Sb concentrations in thermal waters were revealed, and Sb migration species in carbonate and thermal waters were identified for various parameters of hydrogeochemical systems. Variations in Sb speciation were demonstrated for hydrogeochemical systems depending on their boundary conditions (\(P_{CO_2 } \), T, and R/W). Models were outlined responsible for the precipitation of Sb2S3(cr) from carbonate and thermal waters. 相似文献
9.
Vadim A. Kravchinsky Michael E. Evans John A. Peck Hideo Sakai Mikhail A. Krainov John W. King Mikhail I. Kuzmin 《Geophysical Journal International》2007,170(1):101-116
Magnetic remanence vectors for 1737 samples from two ∼100 m cores of Lake Baikal sediments are reported along with complete magnetic susceptibility profiles obtained from a pass-through system. Chronological control is established by means of two independent correlations; first, by matching susceptibility variations to the oceanic oxygen isotope record and second, by matching the relative palaeointensity variations to the SINT-800 global reference curve. These both imply an average deposition rate of 15 cm kyr–1 and a basal age of ∼640 ka. Spectral analysis reveals the presence of Milankovitch signals at ∼100 kyr (eccentricity), ∼41 kyr (obliquity) and ∼23 and ∼19 kyr (precession). Stable remanence vectors are almost all of normal polarity. The few exceptions comprise brief intervals of low and/or negative inclinations which probably represent geomagnetic excursions. However, these are far less numerous than the high sedimentation rate would lead one to expect. Furthermore, only four of them can be readily matched to the—still poorly understood—global pattern. These are the Laschamp, the Albuquerque, the Iceland Basin and perhaps the West Eifel excursions which occurred at ∼38 000, ∼146 000, at 180 000–190 000 and at 480 000–495 000 yr ago, respectively. 相似文献
10.
V. M. Kulkov Yu. G. Egorov A. M. Krainov A. E. Shakhanov R. V. Elnikov 《Solar System Research》2016,50(7):533-539
Aspects of the design of small spacecraft with electric propulsion power plants for investigating minor bodies in the Solar System are examined. The results of design and ballistic analysis of transfer into an orbit of terrestrial asteroids using electric propulsion thrusters are given. The possible concept design of the spacecraft is determined and the structure of a small spacecraft with an electric propulsion power plant is presented. Parameters of the electric propulsion power plant of a small spacecraft for a flight to the minor bodies of the Solar System are estimated. 相似文献