Historical record of polycyclic aromatic hydrocarbons (PAH) and heavy metals in floodplain sediments from the Rhine River (Hessisches Ried, Germany)

The depth-related content of polycyclic aromatic hydrocarbons (PAH) and heavy metals was determined for two soil profiles (i.e. one Fluvisol and one Gleyic Cambisol) which developed in sediments from floodplains located at an old meander of the Rhine river. The meander had been cut off from the main river in 1829. The separation of the meander from the main river caused a change in sediment deposition (i.e. from sand to silt) which is clearly visible in the soil-profiles. Since that time, approximately 100 cm of sediments have accumulated due to temporary flooding of the area. Each soil profile was separated into 18 samples. The samples were analysed for their content of PAH after solvent extraction. Additionally, several trace elements (Co, Ni, Cd, Pb, Zn, Cr and Cu) were determined in the same sample set, and depth-related concentration profiles for both PAH and trace elements were developed. The distribution patterns of PAH with more than 3 condensed rings did not provide any evidence for PAH biodegradation or vertical transport after deposition of the sediments. Thus, in the case of PAH, the historical record can be derived not only from subhydric sediments but also from floodplain sediments. It was not possible to distinguish between atmospheric and fluvial input of PAH into the sediments from the observed distribution patterns due to the same origin of PAH from pyrolytic processes. A source determination of the PAH was not possible except for perylene, for which biogenic formation can be assumed. A comparison of the results shows that the depth-related PAH and trace element concentrations display similar trends over most of the total profiles. In the uppermost section of the profiles, the concentration of most trace elements declines whereas the PAH concentration remains high. This indicates the presence of different sources for PAH and trace elements in the last decades.     

A new independent limit on the cosmological constant/dark energy from the relativistic bending of light by Galaxies and clusters of Galaxies

We derive new limits on the value of the cosmological constant, Λ, based on the Einstein bending of light by systems where the lens is a distant galaxy or a cluster of galaxies. We use an amended lens equation in which the contribution of Λ to the Einstein deflection angle is taken into account and use observations of Einstein radii around several lens systems. We use in our calculations a Schwarzschild–de Sitter vacuole exactly matched into a Friedmann–Robertson–Walker background and show that a Λ-contribution term appears in the deflection angle within the lens equation. We find that the contribution of the Λ-term to the bending angle is larger than the second-order term for many lens systems. Using these observations of bending angles, we derive new limits on the value of Λ. These limits constitute the best observational upper bound on Λ after cosmological constraints and are only two orders of magnitude away from the value determined by those cosmological constraints.