Stability of Temperature and Conductivity Sensors of Argo Profiling Floats

After recalibration of the temperature and conductivity sensors of three Argo profiling floats recovered after operations for four to nine months, the results indicate that the floats basically showed no significant drift, either in temperature or salinity, and adequately fulfilled the accuracy requirement of the Argo project (0.005°C for temperature and 0.01 psu for salinity). Only the third float showed a significant offset in salinity of about −0.02 psu, as expected from comparison between the float data and the shipboard conductivity-temperature-depth data. This offset was caused by the operational error of the PROVOR-type float, in which the surface water was pumped immediately after the launch, fouling the conductivity sensor cell. This revised version was published online in July 2006 with corrections to the Cover Date.     

Validity of sea surface temperature observed with the TRITON buoy under diurnal heating conditions

In order to investigate the validity of buoy-observed sea surface temperature (SST), we installed special instruments to measure near-surface ocean temperature on the TRITON buoy moored at 2.07°N, 138.06°E from 2 to 13 March 2004, in addition to a standard buoy sensor for the regular SST measurement at 1.5-m depth. Large diurnal SST variations were observed during this period, and the variations of the temperatures at about 0.3-m depth could be approximately simulated by a one-dimensional numerical model. However, there was a notable discrepancy between the buoy-observed 1.5-m-depth SST (SST_1.5m) and the corresponding model-simulated temperature only during the daytime when the diurnal rise was large. The evaluation of the heat balance in the sea surface layer showed that the diurnal rise of the SST_1.5m in these cases could not be accounted for by solar heating alone. We examined the depth of the SST_1.5m sensor and the near-surface temperature observed from a ship near the buoy, and came to the conclusion that the solar heating of the buoy hull and/or a disturbance in the temperature field around the buoy hull would contribute to the excessive diurnal rise of the SST_1.5m observed with the TRITON buoy. However, the temperature around the hull was not sufficiently homogenized, as suggested in a previous paper. For the diurnal rise of the SST_1.5m exceeding 0.5 K, the daytime buoy data became doubtful, through dynamics that remain to be clarified. A simple formula is proposed to correct the unexpected diurnal amplitude of the buoy SST_1.5m.     

X-ray observation of the Jovian impacts of comet Shoemaker - Levy 9

An ASCA observation of the Jovian impact of the comet Shoemaker-Levy 9 is reported. Four impacts of H, L, Q1 and R were observed and four impacts of B, C, G, and Q2 were observed within 60 minutes after their impacts. No significant flaring of X-ray emission was observed. Upper limit X-ray fluxes of 90 % confidence level, averaged 5 minutes just after the impacts, were 2.4 × 10^–13 erg sec^–1 cm^–2, 3.5 × 10^–13 erg sec^–1 cm^–2, 1.6 × 10^–13 erg sec^–1 cm^–2 and 2.9 × 10^–13 erg sec^–1 cm^–2 for the impacts of H, L, Q1 and R, respectively, in the 0.5(0.7 for H and Q1)–10 keV energy range. However, a hint of X-ray enhancement around Jupiter from July 17 to July 19 was detected with about 2 6 × 10^–14 erg sec^–1 cm^–2 in the 0.5–10 keV energy range.     

Preparation of a New Geological Survey of Japan Geochemical Reference Material: Coral JCp-1

A new geochemical reference material, coral Porites sp. JCp-1 has been prepared by the Geological Survey of Japan (GSJ). Provisional values for twenty one major, minor and trace elements are presented. The homogeneity tests showed that all elements studied are considered to be homogeneously distributed.     

Primary Ore Mineral Assemblage and Fluid Inclusion Study of the Batu Hijau Porphyry Cu-Au Deposit, Sumbawa, Indonesia

Abstract. The Batu Hijau porphyry Cu‐Au deposit, Sumbawa Island, Indonesia, is associated with a tonalitic intrusive complex. The temperature‐pressure condition of mineralization at the Batu Hijau deposit is discussed on the basis of fluid inclusion microthermometry. Then, the initial Cu‐Fe sulfide mineral assemblage is discussed. Bornite and chalcopyrite are major copper ore minerals associated with quartz veinlets. The quartz veinlets have been classified into ‘A’ veinlets associated with bornite, digenite, chalcocite and chalcopyrite, ‘B’ veinlets having chalcopyrite bornite along vuggy center‐line, rare ‘C’ chalcopyrite‐quartz veinlets, and late ‘D’ veinlets consisting of massive pyrite and quartz (Clode et al., 1999). Copper and gold mineralization is associated with abundant ‘A’ quartz veinlets. Abundant fluid inclusions are found in veinlet quartz consisting mainly of gas‐rich inclusions and polyphase inclusions throughout the veinlet types. The hydrothermal activity occurred in temperature‐pressure conditions of aqueous fluid immiscibility into hypersaline brine and dilute vapor. The halite dissolution (Tm[halite]) and liquid‐vapor homogenization (Th) temperatures of the polyphase inclusions in veinlet quartz range from 270 to 472d?C and from 280 to 454d?C, respectively. The estimated salinity ranges from 36 to 47 wt% (NaCl equiv.). The apparent pressures lower than 300 bars are estimated to have been along the liquid‐vapor‐halite curve for the fluid inclusions having the Th lower than the Tm that trapped the brine saturated with halite, or at slightly higher pressure relative to liquid‐vapor‐halite curve for the fluid inclusions having the Th higher than the Tm that trapped the brine unsaturated with halite. The actual temperature and pressure during the hydrothermal activity at the Batu Hijau deposit are estimated to have been around 300d?C and 50 bars. At such temperature‐pressure conditions, the principal and initial Cu‐Fe sulfide mineral assemblages are thought to be chalcopyrite + bornite solid solution (bnss) for the chalcopyrite‐bearing assemblage, and chalcocite‐digenite solid solution and bnss for the chalcopyrite‐free assemblage.     

Evolution of Hydrothermal System at the Dizon Porphyry Cu-Au Deposit, Zambales, Philippines

Abstract. Evolution of hydrothermal system from initial porphyry Cu mineralization to overlapping epithermal system at the Dizon porphyry Cu‐Au deposit in western central Luzon, Zambales, Philippines, is documented in terms of mineral paragen‐esis, fluid inclusion petrography and microthermometry, and sulfur isotope systematics. The paragenetic stages throughout the deposit are summarized as follows; 1) stockwork amethystic quartz veinlets associated with chalcopyrite, bornite, magnetite and Au enveloped by chlorite alteration overprinting biotite alteration, 2) stockwork quartz veinlets with chalcopyrite and pyrite associated with Au and chalcopyrite and pyrite stringers in sericite alteration, 3) stringer quartz veinlets associated with molybdenite in sericite alteration, and 4) WNW‐trending quartz veins associated with sphalerite and galena at deeper part, while enargite and stibnite at shallower levels associated with advanced argillic alteration. Chalcopyrite and bornite associated with magnetite in quartz veinlet stockwork (stage 1) have precipitated initially as intermediate solid solution (iss) and bornite solid solution (bnss), respectively. Fluid inclusions in the stockwork veinlet quartz consist of gas‐rich inclusions and polyphase inclusions. Halite in polyphase inclusions dissolves at temperatures ranging from 360d?C to >500d?C but liquid (brine) and gas (vapor) do not homogenize at <500d?C. The maximum pressure and minimum temperature during the deposition of iss and bnss with stockwork quartz veinlets are estimated to be 460 bars and 500d?C. Fluid inclusions in veinlet stockwork quartz enveloped in sericite alteration (stage 2) consist mainly of gas‐rich inclusions and polyphase inclusions. In addition to the possible presence of saturated NaCl crystals at the time of entrapment of fluid inclusions that exhibit the liquid‐vapor homogenization temperatures lower than the halite dissolution temperatures in some samples, wide range of temperatures of halite dissolution and liquid‐vapor homogenization of polyphase inclusions from 230d?C to >500d?C and from 270d?C to >500d?C, respectively, suggests heterogeneous entrapment of gaseous vapor and hypersaline brine. The minimum pressure and temperature are estimated to be about 25 bars and 245d?C. Fluid inclusions in veinlet quartz associated with molybdenite (stage 3) are dominated by gas‐rich inclusions accompanied with minor liquid‐rich inclusions that homogenize at temperatures between 350d?C and 490d?C. Fluid inclusions in vuggy veinlet quartz associated with stibnite (stage 4) consist mainly of gas‐rich inclusions with subordinate polyphase inclusions that do not homogenize below 500d?C. Fluid inclusions in veinlet quartz associated with galena and sphalerite (stage 4) are composed of liquid‐rich two‐phase inclusions, and they homogenize into liquid phase at temperatures ranging widely from 190d?C to 300d?C (suggesting boiling) and the salinity ranges from 1.0 wt% to 3.4 wt% NaCl equivalent. A pressure of about 15 bars is estimated for the dilute aqueous solution of 190d?C from which veinlet quartz associated with galena and sphalerite precipitated. In addition to a change in temperature‐pressure regime from lithostatic pressure during the deposition of iss and bnss with stockwork quartz veinlets to hydrostatic pressure during fracture‐controlled quartz veinlet associated with galena and sphalerite, a decrease in pressure is supposed to have occurred due to unroofing or removal of the overlying piles during the temperature decrease in the evolution of hydrothermal system. The majority of the sulfur isotopic composition of sulfides ranges from ±0 % to +5 %. Sulfur originated from an iso‐topically uniform and homogeneous source, and the mineralization occurred in a single hydrothermal system.     

Rare Earth, Major and Trace Elements in the Kunimiyama Ferromanganese Deposit in the Northern Chichibu Belt, Central Shikoku, Japan

Abstract. Rare earth, major and trace element geochemistry is reported for the Kunimiyama stratiform ferromanganese deposit in the Northern Chichibu Belt, central Shikoku, Japan. The deposit immediately overlies greenstones of mid-ocean ridge basalt (MORB) origin and underlies red chert. The ferromanganese ores exhibit remarkable enrichments in Fe, Mn, P, V, Co, Ni, Zn, Y and rare earth elements (excepting Ce) relative to continental crustal abundance. These enriched elements/ Fe ratios and Post-Archean Average Australian Shale-normalized REE patterns of the ferromanganese ores are generally analogous to those of modern hydrothermal ferromanganese plume fall-out precipitates deposited on MOR flanks. However in more detail, Mn and Ti enrichments in the ferromanganese ores are more striking than the modern counterpart, suggesting a significant contribution of hydrogenetic component in the Kunimiyama ores. Our results are consistent with the interpretation that the Kunimiyama ores were umber deposits that primarily formed by hydrothermal plume fall-out precipitation in the Panthalassa Ocean during the Early Permian and then accreted onto the proto-Japanese island arc during the Middle Jurassic. The presence of strong negative Ce anomaly in the Kunimiyama ores may indicate that the Early Permian Panthalassa seawater had a more striking negative Ce anomaly due to a more oxidizing oceanic condition than today.     

Comparative assessment of Japan's long-term carbon budget under different effort-sharing principles

This article assesses Japan's carbon budgets up to 2100 in the global efforts to achieve the 2?°C target under different effort-sharing approaches based on long-term GHG mitigation scenarios published in 13 studies. The article also presents exemplary emission trajectories for Japan to stay within the calculated budget.

The literature data allow for an in-depth analysis of four effort-sharing categories. For a 450?ppm CO₂e stabilization level, the remaining carbon budgets for 2014–2100 were negative for the effort-sharing category that emphasizes historical responsibility and capability. For the other three, including the reference ‘Cost-effectiveness’ category, which showed the highest budget range among all categories, the calculated remaining budgets (20th and 80th percentile ranges) would run out in 21–29 years if the current emission levels were to continue. A 550?ppm CO₂e stabilization level increases the budgets by 6–17 years-equivalent of the current emissions, depending on the effort-sharing category. Exemplary emissions trajectories staying within the calculated budgets were also analysed for ‘Equality’, ‘Staged’ and ‘Cost-effectiveness’ categories. For a 450?ppm CO₂e stabilization level, Japan's GHG emissions would need to phase out sometime between 2045 and 2080, and the emission reductions in 2030 would be at least 16–29% below 1990 levels even for the most lenient ‘Cost-effectiveness’ category, and 29–36% for the ‘Equality’ category. The start year for accelerated emissions reductions and the emissions convergence level in the long term have major impact on the emissions reduction rates that need to be achieved, particularly in the case of smaller budgets.

Policy relevance

In previous climate mitigation target formulation processes for 2020 and 2030 in Japan, neither equity principles nor long-term management of cumulative GHG emissions was at the centre of discussion. This article quantitatively assesses how much more GHGs Japan can emit by 2100 to achieve the 2?°C target in light of different effort-sharing approaches, and how Japan's GHG emissions can be managed up to 2100. The long-term implications of recent energy policy developments following the Fukushima nuclear disaster for the calculated carbon budgets are also discussed.     

Internal Microanatomy and Zoological Affinity of the Early Cambrian Olivooides

The early Cambrian pentamerous microfossil Olivooides/Punctatus in South China, which is characterized by a diagnostic stellate tubular apex, has been well-known for its almost complete development sequence that can be confidently traced from embryos and hatched juveniles, to conical adults. However, its zoological affinity remains highly controversial. Here we describe the internal microanatomic structures of the soft-body inside the peridermal theca of Olivooides multisulcatus Qian, 1977, including interradial pairs of tentacles, adradial and perradial frenula, perradial oral marginal lappets and twins of perradial gastric saccule-like humps as well as a circular velarium with striated coronal muscles. Particularly, one specimen shows bifurcated velarial canals along the bell aperture. Both the components of the soft-body and the external theca (or cyst) are arranged in perfect pentaradial symmetry. These characteristics are more compatible with those of living cubomedusans and co-occurring Cambrian athecate embryonic cubozoans. Concerning the presence of peridermal theca, Olivooides most likely represents an extinct thecate stem-group cubomedusae but devoid of both perradial eyes and specialized pedalia. The well-grown soft body inside the peridermal tube displays a set of mixed features of both polyp and medusa.