Coulometric TCO2 analyses for marine studies; an introduction

Progress in the introduction of coulometry for the analysis of total carbon dioxide (TCO₂) in marine waters is described. An extractor—stripper removes CO₂ that is measured coulometrically by the quantity of electricity (coulombs) used to electrogenerate OH^? ions for the titration of the acid formed by the reaction of CO₂ and ethanolamine. The equivalence point is detected photometrically with thymolphthalein as the indicator, and Faraday's Law relates coulombs to equivalents of titrant generated and CO₂ determined so that there are no standard curves needed or titrants to standardize or store. Accuracy was determined by adding gelatin capsules containing 100–1500 μg C of pure CaCO₃ into the stripper, and accuracies of better than ± 1 μg C were achieved. The best precision for natural seawater (± 1 standard error) of ± 0.5 μmol l^?1 was found for 17 samples of Bermuda coastal waters having a mean TCO₂ of 2007.2 μmol l^?1 (0.05% CV). Sources of error and precautions are discussed. This method, which has been used successfully at sea, can be used to study a variety of marine phenomena involving TCO₂.     

Deformation styles as a key for interpreting glacial depositional environments

Lithostratigraphical and lithofacies approaches used to interpret glacial sediments often ignore deformation structures that can provide the key to environment of formation. We propose a classification of deformation styles based on the geometry of structures rather than inferred environment of formation. Five styles are recognised: pure shear (P), simple shear (S), compressional (C), vertical (V) and undeformed (U). These dictate the first letter of the codes; the remaining letters conveying the evidence. This information can be used to reconstruct palaeostress fields and to infer physical properties of sediments when they deformed. Individual structures are not diagnostic of particular environments but the suite of structures, their relative scale, stratigraphical relationships, and orientation relative to palaeoslopes and to palaeoice‐flow directions can be used to infer the environment in which they formed. This scheme is applied at five sites in west Wales. The typical succession is interpreted as subglacial sediments overlain by meltout tills, flow tills and sediment flows. Paraglacial redistribution of glacial sediments is widespread. Large‐scale compressional deformation is restricted to sites where glaciers readvanced. Large‐scale vertical deformation occurs where water was locally ponded near the ice margin. There is no evidence for glaciomarine conditions. Copyright © 2003 John Wiley & Sons, Ltd.     

Coronal mass ejection associated with the stationary post-flare arch of 21–22 May 1980

By using a combination of X-ray (HXIS), H (Haleakala), white-light corona (Solwind), and zodiacal light (Helios) images on 21–22 May, 1980 we demonstrate, and try to explain, the co-existence of a coronal mass ejection with a stationary post-flare coronal arch. The mass ejection was seen, both by Solwind and Helios, in prolongation of the path of a powerful spray, whereas the active region filament did not erupt. A tentative comparison is made with other occurrences of stationary, or quasi-stationary post-flare coronal arches.     

Flare stars and solar bursts: High resolution in time and frequency

Coronal loops on the Sun and nearby stars are investigated using observations at 20 cm wavelength with high resolution in time and frequency. Observations of the dwarf M star AD Leonis with high time resolution using the Arecibo Observatory have resulted in the discovery of a quasi-periodic train of circularly polarized spikes with a mean periodicity of 32 ± 5 ms and a total duration of 150 ms. The individual spikes had rise times of 5 ms, leading to an upper limit to the linear size L 1.5 × 10⁸ cm for the spike emitter. This size is only 0.005 of the estimated radius of AD Leonis. Provided that the emitter is symmetric, it has a brightness temperature of T _B 10¹⁶ K, suggesting a coherent burst mechanism such as an electron-cyclotron maser. Coronal oscillations might modulate the maser output, producing the quasi-periodic spikes. Observations at closely spaced wavelengths, or high frequency resolution, using the Very Large Array have revealed narrow-band structure (v/v 0.01) in solar bursts and in the slowly-varying radiation of the dwarf M star YZ Canis Minoris. The narrow-band emission cannot be explained by continuum emission processes, but it might be attributed to electron-cyclotron maser radiation. Maser action at the second or first harmonic of the gyrofrequency implies magnetic field strengths of 250 and 500 G, respectively. Thus, observations with high resolution in time and frequency suggest coherent processes in the coronae of the Sun and dwarf M stars. The scientific potential of these discoveries may be best fulfilled by the construction of a solar-stellar synthesis radiotelescope.Proceedings of the Workshop on Radio Continua during Solar flares, held at Duino (Trieste), Italy, 27–31 May, 1985.     

激光拉曼光谱法分析多种显微组分荧光变化及其应用

利用激发488 nm激光的氩离子激光器作为RENISHAW inVia型激光拉曼光谱仪的光源,建立了多种显微组分荧光变化(FAMM)分析方法,并对镜质体反射率明显抑制的东营凹陷有效烃源岩进行了测定。结果表明,东营凹陷有效烃源岩的有机质类型越好,镜质体反射率抑制程度越高,有效烃源岩的真实成熟度应主要处于0.64%~1.30%,而不是实测镜质体反射率所反映的0.37%~1.10%。     

高效液相色谱-等离子体质谱技术在溴元素形态分析中的应用

溴是一种在自然水体中都含有的元素,通常以B r-的形式存在。目前最常用的水净化方式就是向水中通入臭氧以杀灭细菌;而臭氧分解的副产物即为B r-转换成的B rO3-,这是一种公认的致癌物质。本实验室曾使用阴离子交换高效液相色谱(HPLC)与等离子体质谱(ICP-MS)联用分析B rO3-和B r-,方法虽能有效地将这两种溴形态分离,但分析每个样品需8 m in。本文试图建立新的方法缩短分析时间,并验证该方法应用于实际水样分析时测定其他含溴化合物的能力。1实验部分1.1高效液相色谱分析条件表1列出了等度淋洗和梯度淋洗两种模式下HPLC的分析条件,完成形态的分离。等度淋洗和梯度淋洗在分析中显示出不同     

Kinetics of Cd sorption, desorption and fixation by calcite: A long-term radiotracer study

Time-dependent sorption and desorption of Cd on calcite was studied over 210 days utilizing ¹⁰⁹Cd as a tracer to distinguish between ‘labile’ and ‘non-labile’ forms of sorbed Cd. Stabilizing the calcite suspensions for 12 months under atmospheric P_CO2 and controlled temperature was necessary to reliably follow Cd dynamics following initial sorption. Results revealed time-dependant Cd sorption and marked desorption hysteresis by calcite under environmentally relevant conditions. Data obtained were fitted to a first-order kinetic model and a concentric shell diffusion model. Both models described the progressive transfer of Cd²⁺ to a less reactive form within calcite and subsequent desorption of Cd subject to different initial contact times. The kinetic model provided a better fit to the combined sorption and desorption data (R² = 0.992). It differentiates between two ‘pools’ of sorbed Cd²⁺ on calcite, ‘labile’ and ‘non-labile’, in which labile sorbed Cd is in immediate equilibrium with the free Cd²⁺ ion activity in solution whereas non-labile Cd is kinetically restricted. For the diffusion model (R² = 0.959), the rate constants describing Cd dynamics in calcite produced a half-life for Cd desorption of ∼175 d, for release to a ‘zero-sink’ solution. Results from this study allow comment on the likely mechanisms occurring at the calcite surface following long-term Cd sorption.     

Historical space as narrative medium: on the configuration of spatial narratives of time at historical sites

This paper examines how narratives of history are organized spatially at historical sites and memorial spaces, especially in urban settings and in places invested with a sense of collective memory. Much recent research has focused on landscape, memory, and place and how relationships of political and social power influence the representation of historical events in public spaces. Although the meaning of such sites may be hotly contested for long periods of time, we focus here on narrative theory and the related, but unexplored, issue of how such historical stories are configured on the ground at actual historical sites. We identify a number of narrative strategies which are frequently used to configure historical stories in space. Declamatory strategies using markers presenting a snapshot of an event are common, but sequential and non-sequential linear strategies are also used, as are thematic strategies that cross-cut space and time to present complex historical stories at various spatial scales. Examples are drawn from a range of historical sites in North America, Europe and Israel.