Force–displacement response of in‐plane‐loaded URM walls with a dominating flexural mode

This article presents a new mechanical model for the non‐linear force–displacement response of unreinforced masonry (URM) walls developing a flexural rocking mode including their displacement capacity. The model is based on the plane‐section hypothesis and a constitutive law for the masonry with zero tensile strength and linear elastic behaviour in compression. It is assumed that only the compressed part of the wall contributes to the stiffness of the wall and therefore the model accounts for a softening of the response due the reduction of the effective area. Stress conditions for limit states are proposed that characterise the flexural failure. The new model allows therefore linking local performance levels to global displacement capacities. The limit states criteria describe the behaviour of modern URM walls with cement mortar of normal thickness and clay bricks. The model is validated through comparison of local and global engineering demand parameters with experimental results. It provides good prediction of the effective stiffness, the force capacity and the displacement capacity of URM walls at different limit states. Copyright © 2015 John Wiley & Sons, Ltd.     

Evaluation of force-based and displacement-based out-of-plane seismic assessment methods for unreinforced masonry walls through refined model simulations

The performance of force-based and displacement-based seismic assessment methods for the life-safety limit state check of out-of-plane loaded unreinforced masonry walls is evaluated on the basis of refined numerical simulations. For this purpose, a discrete element model of a vertically spanning wall is built and validated against experimental results from static and dynamic test conditions. The model is then analysed for a large range of wall configurations. For each configuration, a static pushover analysis and a series of incremental dynamic analyses are run, the latter permitting to determine the capacity of the wall under dynamic loading. The accuracy of the assessment methods in predicting the acceleration at which the walls collapse is evaluated. It is found that the displacement-based method is more accurate, robust, and safe than the force-based method. The comparison also shows that for walls characterised by a relatively high ratio of axial load to Euler's critical load, both assessment methods lead to an overestimation of the wall capacity. As a remedy, a modification to the methods based on a recently developed mechanical model is put forward and tested. For the force-based method, it is additionally suggested to set for walls with relatively high overburden ratios the behaviour factor equal to 1. To ensure reproducibility of this study, all input and output files of the numerical simulations are made publicly available.     

The household production function approach to valuing climate: the case of Japan

According to household production function theory households combine marketed goods and nonmarket environmental goods to produce service flows of direct value to the household. This readily explains why, as an input to household production activities, households might have preferences over the climate. Using techniques more frequently employed to account for differences in the demographic composition of households we use household production function theory to estimate climate equivalence scales using household expenditure data drawn from 51 Japanese cities over the period 2000–2009. Our results indicate that warmer temperatures result in a small but statistically highly significant reduction in the cost of living. Combining these estimates with climate change scenarios associated with the IPCC A2, A1B, and B1 emissions scenarios other things being equal points to a slight reduction in Japanese households’ cost of living.     

Flood frequencies reveal Holocene rapid climate changes (Lower Moulouya River,northeastern Morocco)

Current high‐resolution palaeoenvironmental records reveal short‐term Holocene coolings. One of these major Holocene rapid climate changes occurred between 3.2 and 2.7 cal. ka BP. The sensitivity of river systems vis‐à‐vis slight and short‐term Holocene climatic variations is a subject of controversy in the scientific community. In this paper, we present a 4.0 to 1.4 cal ka BP palaeoflood record from the Lower Moulouya River (northeastern Morocco) to demonstrate the high sensitivity of semiarid rivers in the southwestern Mediterranean towards Holocene environmental changes. The Lower Moulouya flood deposits are characterised by thick, well‐stratified, predominantly clayey to silty overbank fine sediments. These cohesive sediments show evidence of excellent preservation conditions against fluvial erosion and contain a continuous record of mid to late Holocene flood sequences. The Moulouya palaeoflood record can be interpreted in the context of regional and global high‐resolution proxy data, revealing a strong coupling with Holocene rapid climate changes. The centennial‐scale Moulouya palaeohydrological history will be discussed with palaeoenvironmental data from the same record (palaeomagnetics, sedimentary charcoal record, anthracological analyses, snail analyses) to generate new ideas about the mid to late Holocene hydrological cycle in the southwestern Mediterranean. The deduced features of pronounced Lower Moulouya flooding and the decreased fire recurrence during Holocene cooling remain somewhat inconsistent with the interpretation of other palaeohydrological and paleaoecological records from the southwestern Mediterranean. However, enhanced Lower Moulouya flood frequencies between 3.2 and 2.7 cal. ka BP agree with increased floodplain aggradation in other major river systems of Mediterranean North Africa. Copyright © 2009 John Wiley & Sons, Ltd.     

Carbon dioxide on the satellites of Saturn: Results from the Cassini VIMS investigation and revisions to the VIMS wavelength scale

Several of the icy satellites of Saturn show the spectroscopic signature of the asymmetric stretching mode of C-O in carbon dioxide (CO₂) at or near the nominal solid-phase laboratory wavelength of 4.2675 μm (2343.3 cm⁻¹), discovered with the Visible-Infrared Mapping Spectrometer (VIMS) on the Cassini spacecraft. We report here on an analysis of the variation in wavelength and width of the CO₂ absorption band in the spectra of Phoebe, Iapetus, Hyperion, and Dione. Comparisons are made to laboratory spectra of pure CO₂, CO₂ clathrates, ternary mixtures of CO₂ with other volatiles, implanted and adsorbed CO₂ in non-volatile materials, and ab initio theoretical calculations of CO₂ * nH₂O. At the wavelength resolution of VIMS, the CO₂ on Phoebe is indistinguishable from pure CO₂ ice (each molecule’s nearby neighbors are also CO₂) or type II clathrate of CO₂ in H₂O. In contrast, the CO₂ band on Iapetus, Hyperion, and Dione is shifted to shorter wavelengths (typically ∼4.255 μm (∼2350.2 cm⁻¹)) and broadened. These wavelengths are characteristic of complexes of CO₂ with different near-neighbor molecules that are encountered in other volatile mixtures such as with H₂O and CH₃OH, and non-volatile host materials like silicates, some clays, and zeolites. We suggest that Phoebe’s CO₂ is native to the body as part of the initial inventory of condensates and now exposed on the surface, while CO₂ on the other three satellites results at least in part from particle or UV irradiation of native H₂O plus a source of C, implantation or accretion from external sources, or redistribution of native CO₂ from the interior.The analysis presented here depends on an accurate VIMS wavelength scale. In preparation for this work, the baseline wavelength calibration for the Cassini VIMS was found to be distorted around 4.3 μm, apparently as a consequence of telluric CO₂ gas absorption in the pre-launch calibration. The effect can be reproduced by convolving a sequence of model detector response profiles with a deep atmospheric CO₂ absorption profile, producing distorted detector profile shapes and shifted central positions. In a laboratory blackbody spectrum used for radiance calibration, close examination of the CO₂ absorption profile shows a similar deviation from that expected from a model. These modeled effects appear to be sufficient to explain the distortion in the existing wavelength calibration now in use. A modification to the wavelength calibration for 13 adjacent bands is provided. The affected channels span about 0.2 μm centered on 4.28 μm. The maximum wavelength change is about 10 nm toward longer wavelength. This adjustment has implications for interpretation of some of the spectral features observed in the affected wavelength interval, such as from CO₂, as discussed in this paper.     

A hydropedological approach to simulate streamflow and soil water contents with SWAT+

Reflecting internal catchment hydrological processes in hydrological models is important for accurate predictions of the impact of climate and land-use change on water resources. Characterizing these processes is however difficult and expensive due to their dynamic nature and spatio-temporal variability. Hydropedology is a relatively new discipline focusing on the synergistic integration of hydrology, soil physics and pedology. Hydropedological interpretations of soils and soil distribution can be used to characterize key hydrological processes, especially in areas with no or limited hydrometric measurements. Here we applied a hydropedological approach to reflect flowpaths through detailed routing in SWAT+ for a 157 ha catchment (Weatherley) in South Africa. We compared the hydropedological approach and a standard (no routing) approach against measured streamflow (two weirs) and soil water contents (13 locations). The catchment was treated as ‘ungauged’ and the model was not calibrated against hydrometric measurements in order to determine the direct contribution of hydropedology on modelling efficiency. Streamflow was predicted well without calibration (NSE > 0.8; R² > 0.82) for both approaches at both weirs. The standard approach yielded slightly better streamflow predictions. The hydropedological approach resulted in considerable improvements in the simulation of soil water contents (R² increased from 0.40 to 0.49 and PBIAS decreased from 40% to 20%). The routing capacity of SWAT+ as employed in the hydropedological approach reduced the underestimation of wetland water regimes drastically and resulted in a more accurate representation of the dominant hydrological processes in this catchment. We concluded that hydropedology can be a valuable source of ‘soft data’ to reflect internal catchment structure and processes and, potentially, for realistic calibrations in other studies, especially those conducted in areas with limited hydrometric measurements.     

Revised stratigraphy and eruption rates of Ceboruco stratovolcano and surrounding monogenetic vents (Nayarit,Mexico) from historical documents and new radiocarbon dates

More than a dozen new radiocarbon dates reconstruct the eruptive history of Ceboruco volcano. Six of these further constrain previous results for the important plinian Jala eruption, which occurred near 1060 ± 55 yr BP. A calibrated radiocarbon age of AD 990–1020 was obtained as best overlap range for all samples. Pottery fragments found directly underneath the pumice deposit indicate that this area was inhabited by human populations that witnessed the eruption. This age therefore represents an important time marker in the prehistory of this region, because an area of > 560 km2 was devastated and covered by a thickness of > 50 cm of pumice and ash fallout.     

Palynofacies and sea-level changes in the Upper Cretaceous of the Vocontian Basin, southeast France

Upper Cretaceous platform carbonates of the Vocontian Basin (southeastern France) have been investigated in a cross-section from the proximal deposits exposed in the lower Rhône Valley to the distal part of the basin in the Southern Subalpine Ranges north of Nice. The stratigraphic interval studied in detail spans the uppermost Turonian and Coniacian.Palynofacies patterns were used to detect eustatic signals at a third-order scale and are the tool for correlation of proximal and distal platform deposits. The organic constituents observed in the studied samples have been grouped into a continental fraction, including higher plant debris (phytoclasts) and sporomorphs, and a marine fraction with dinoflagellate cysts, acritarchs, prasinophytes, and foraminiferal test linings. The main factors influencing the stratigraphic and spatial distribution of land-derived, allochthonous, and marine, relatively autochthonous, organic particles are the proximity of land, the organic productivity, the degree of biodegradation and the hydrodynamic conditions of the depositional system. Palynofacies parameters used for the sequence stratigraphic interpretation are: (1) the ratio of continental to marine constituents (CONT/MAR ratio); (2) the ratio of opaque to translucent phytoclasts (OP/TR ratio); (3) the phytoclast particle size and shape; and (4) the relative proportion and species diversity of marine plankton. Ternary diagrams illustrating significant proximality changes were used to decipher transgressive-regressive trends within the succession.High amounts of translucent phytoclasts and decreasing values of the CONT/MAR ratio occur during the phase of relative sea-level rise in the upper Turonian. The stratigraphic interval of maximum flooding around the Turonian/Coniacian boundary is marked by the highest abundance and species diversity of dinoflagellate cysts, and by high percentages of opaque, equidimensional particles within the phytoclast group. The OP/TR ratio is still high within the lower Coniacian representing the early highstand deposits, whereas the relative abundance of marine constituents is again decreasing. Sedimentary organic matter of the upper Coniacian is dominated by large, blade-shaped, mainly opaque phytoclasts, which are a characteristic palynofacies signature of late highstand deposits.The present study demonstrates the high potential of palynofacies analysis in high-resolution stratigraphy and correlation of sedimentary series of shallow epeiric seas.     

Persistent halogenated compounds in black guillemots (Cepphus grylle) from Greenland--levels, compound patterns and spatial trends

Twenty-seven black guillemot eggs and 39 livers were analysed for polychlorinated biphenyls (PCBs), chlorinated pesticides including chlordane-related compounds and toxaphene, and polybrominated diphenylethers (PBDEs). The samples were collected at Qeqertarsuaq (Godhavn, West Greenland) and Ittoqqortoormiit (Scoresbysund, East Greenland). The concentrations of halogenated organic compounds in samples from East Greenland were somewhat higher than the corresponding concentrations from West Greenland. Differences in compound patterns were found between West and East Greenland, with higher percentages of the heavier PCB molecules, p,p(')-DDE and alpha-HCH in the samples from Ittoqqortoormiit. Similarly, different levels and different compositions were observed for eggs and livers. The eggs had generally higher concentrations of all compounds as well as higher percentages of CHB-50, CHB-62 and alpha-HCH than liver samples from the same area. Dividing the liver samples into age groups revealed increasing concentrations with age.     

Sorption and Chemical Reactions of PAHs with Dissolved Humic Substances and Related Model Polymers

Sorption coefficients measured for PAHs on dissolved humic substances by SPME and FQT were found to be inevitably different and method‐dependent – SPME provides activity‐based and FQT concentration‐based sorption coefficients. Poly(acrylic acid) esters as well‐defined model polymers were used in sorption experiments, leading to the conclusion that short aliphatic chains are more effective in binding PAHs than aromatic moieties. FQT was inappropriate to measure sorption coefficients for the interaction of pyrene with poly(acrylic acid) esters but the experiments revealed a characteristic shift in the fluorescence spectrum. Using pyrene as a probe for the molecular environment in the sorbed state, the observed spectral shift indicated a highly hydrophobic microenvironment. The empirical relationships between lg K_DOC and lg K_OW were generalized on the basis of a modified Flory‐Huggins concept. Introducing only one sorbent‐specific parameter, the solubility parameter δ_DOM, the calculation of sorption coefficients became possible for a wide range of HOCs using fundamental data readily available from the literature. Long‐term experiments showed that reactive PAHs (such as acenaphthylene and 9‐methylanthracene) are able to react with HAs under strictly abiotic and anoxic conditions, whereas less reactive PAHs (such as naphthalene and dihydroanthracene) do not form bound residues. The HA reveals two functions in the interaction, behaving as a reaction partner and as a protecting ligand.