Formation of saline groundwaters in the Baltic region through freezing of seawater during glacial periods

Typical Ca---Cl brines occur in crystalline and metamorphic rocks below freshwater horizons at various localities in Sweden and Finland. Total dissolved solids (TDS) range in concentration between 2 and 120 gl⁻¹ and have long been thought to derive from water-rock interactions. The relationships between Na, Cl and Br in these brines suggest, however, that they were derived from freezing of seawater during glacial periods. The brines were subsequently diluted by meteoric waters and their Ca/Mg ratio was increased through water-rock interactions in the subsurface. The hydrogeological model for both the formation of freeze-derived marine brines and their lateral intrusion involves restricted inland marine basins in recent and subrecent polar climatic belts. Seawater in such basins gradually freezes in response to glaciation. The solutes which concentrate in the remaining water body are residual after precipitation of a sequence of minerals which include carbonates, mirabilite and hydrohalite. Hydraulic pressure of the growing ice sheet over the frozen seas is gradually added to the ambient hydrostatic pressure exerted on the brines. This, together with their increased density, increases the intrusional potential of the brines. As the land ice cannot exert hydraulic pressure on continental groundwater in the aquifers, the balance of pressure favours deep landward intrusion of brines. Post-glacial processes cause the subsurface dilution and replacement of the brines both by seawater and fresh waters. The presence of such brines also far from present-day coastal settings reflects the shifting of coastlines as a result of isostatic movements and eustatic sea-level changes associated with glaciation and deglaciation.     

Upwelling, species, and depth effects on coral skeletal cadmium-to-calcium ratios (Cd/Ca)

Skeletal cadmium-to-calcium (Cd/Ca) ratios in hermatypic stony corals have been used to reconstruct changes in upwelling over time, yet there has not been a systematic evaluation of this tracer’s natural variability within and among coral species, between depths and across environmental conditions. Here, coral skeletal Cd/Ca ratios were measured in multiple colonies of Pavona clavus, Pavona gigantea and Porites lobata reared at two depths (1 and 7 m) during both upwelling and nonupwelling intervals in the Gulf of Panama (Pacific). Overall, skeletal Cd/Ca ratios were significantly higher during upwelling than during nonupwelling, in shallow than in deep corals, and in both species of Pavona than in P. lobata. P. lobata skeletal Cd/Ca ratios were uniformly low compared to those in the other species, with no significant differences between upwelling and nonupwelling values. Among colonies of the same species, skeletal Cd/Ca ratios were always higher in all shallow P. gigantea colonies during upwelling compared to nonupwelling, though the magnitude of the increase varied among colonies. For P. lobata, P. clavus and deep P. gigantea, changes in skeletal Cd/Ca ratios were not consistent among all colonies, with some colonies having lower ratios during upwelling than during nonupwelling. No statistically significant relationships were found between skeletal Cd/Ca ratios and maximum linear skeletal extension, δ¹³C or δ¹⁸O, suggesting that at seasonal resolution the Cd/Ca signal was decoupled from growth rate, coral metabolism, and ocean temperature and salinity, respectively. These results led to the following conclusions, (1) coral skeletal Cd/Ca ratios are independent of skeletal extension, coral metabolism and ambient temperature/salinity, (2) shallow P. gigantea is the most reliable species for paleoupwelling reconstruction and (3) the average Cd/Ca record of several colonies, rather than of a single coral, is needed to reliably reconstruct paleoupwelling events.     

Catch-quota balancing in multispecies individual fishing quotas

Individual fishery quotas (IFQs) are an increasingly prevalent form of fishery management around the world, with more than 170 species currently managed with IFQs. Yet, because of the difficulties in matching quota holdings with catches, many argue that IFQs are not appropriate for multispecies fisheries. Using on-the-ground-experience with multispecies IFQ fisheries in Iceland, New Zealand, Australia, and Canada, we assess the design and use of catch-quota balancing mechanisms. Our methodology includes a mix of interviews with fishery managers, industry representatives, and brokers, literature review, and data analysis. We find that a combination of incentives and limits on use rates for the mechanisms provide sufficient flexibility to the quota owner without the fishery manager incurring excessive levels of overexploitation risk. Contrary to some opinions, these programs are evidence that it is possible to implement IFQ programs for multispecies fisheries and that they can be profitable and sustainable.     

Regional variation in springtime ichthyoplankton assemblages in the northeast Pacific Ocean

The coastal regions of the northeast Pacific support large, economically valuable fishery resources and provide nursery areas for many fish species. Over the last few decades, there have been dramatic shifts in species abundance and composition in this area. In this paper, we examine the springtime spatial patterns in the ichthyoplankton of three oceanographically different regions, the Southeast Bering Sea, the Gulf of Alaska and the U.S. West Coast. The data examined are a subset of a larger database (comprising data from cruises conducted from 1972 to 1997) that is being used to investigate spatial, seasonal and interannual patterns in ichthyoplankton of the northeast Pacific in relation to environmental conditions. Ichthyoplankton were collected during seven cruises using 60-cm bongo nets. Spatial patterns of ichthyoplankton were examined using both classification and ordination techniques. Relative Bray-Curtis dissimilarity coefficients calculated from the log₁₀ (n+1) of abundance data were used as input to the numerical classification of species and stations. Nonmetric multidimensional scaling was also applied to the abundance data to examine geometric patterns in the data. The numerical analyses of the species abundance data sets for each cruise revealed spatial patterns in the ichthyoplankton that suggest the occurrence of geographically distinct assemblages of fish larvae in each region. For all three sampling regions, the assemblage structure is primarily related to bathymetry, and Shelf, Slope, and Deep-Water assemblages are described. This shallow to deep-water gradient in species occurrence and abundance reflects the habitat preference and spawning location of the adult fish. Another degree of complexity is superimposed on this primary assemblage structure in each region and seems to be related to local topography and the prevailing current patterns. The patterns in ichthyoplankton assemblages of the three regions in the northeast Pacific Ocean described here form the basis for future investigations of spatial and temporal patterns in the ichthyoplankton of the subarctic Pacific.Regional Index Terms: Northeast Pacific Ocean, Southeast Bering Sea, Gulf of Alaska, U.S. West Coast.     

Pore pressure profiles in fractured and compliant rocks1

Fluid permeability in fractured rocks is sensitive to pore-pressure changes. This dependence can have large effects on the flow of fluids through rocks. We define the permeability compliance γ= 1/k(k/δp_p)_pc, which is the sensitivity of the permeability k to the pore pressure p_p at a constant confining pressure p_c, and solve the specific problems of constant pressure at the boundary of a half-space, a cylindrical cavity and a spherical cavity. The results show that when the magnitude of permeability compliance is large relative to other compliances, diffusion is masked by a piston-like pressure profile. We expect this phenomenon to occur in highly fractured and compliant rock systems where γ may be large. The pressure profile moves rapidly when fluids are pumped into the rock and very slowly when fluids are pumped out. Consequently, fluid pressure, its history and distribution around injection and production wells may be significantly different from pressures predicted by the linear diffusion equation. The propagation speed of the pressure profile, marked by the point where δp_p/δx is a maximum, decreases with time approximately as and the amplitude of the profile also dissipates with time (or distance). The effect of permeability compliance can be important for fluid injection into and withdrawal from reservoirs. For example, excessive drawdown could cause near-wellbore flow suffocation. Also, estimates of the storage capacity of reservoirs may be greatly modified when γ is large. The large near-wellbore pressure gradients caused during withdrawal by large γ can cause sanding and wellbore collapse due to excessive production rates.     

Chemical fingerprints of life in terrestrial soils and their possible use for the detection of life on Mars and other planets

Organic carbon in oxidizable forms and nitrogen are the only elements among some 40 elements studied that are significantly enriched in terrestrial soils as compared to the crust. This enrichment is due to and reflecting life activity in soils, and is characterized by a unique profile distribution. It is suggested that these facts can constitute the basis for the future chemical-biological search for life in planetary soils.     

GGR Critical Review of Analytical Developments in 2004–2005

In 2005 Geostandards and Geoanalytical Research embarked upon a new initiative for its readers. Key researchers in various fields of geoanalytical technique development and their application were identified and invited to provide reviews pertinent to their expertise. As noted in the first of these publications "…instead of revisiting the historical context or decades of development in each analytical technique, the goal here has been to capture a snapshot of "hot topics" across a range of fields as represented in the… literature" (Hergt et al . 2005). Rather than prepare an annual review, a decision was taken earlier this year to provide a biennial summary of progress and accomplishments, in this case for the years 2004–2005. The principal techniques employed in Earth and environmental sciences are covered here, and include laser ablation and multicollector ICP-MS, ICP-AES, thermal ionisation and secondary ion mass spectrometry, as well as neutron activation analysis, X-ray fluorescence and atomic absorption spectrometry. A comprehensive review of the development of reference materials, often essential to these techniques, is also provided. The contributions assembled serve both to keep readers informed of advances they may be unfamiliar with, but also as a means of showcasing examples of the breadth and depth of work being conducted in these fields.     

Historic Dead Sea Level Fluctuations Calibrated with Geological and Archaeological Evidence

The Dead Sea, the Holocene terminal lake of the Jordan River catchment, has fluctuated during its history in response to climatic change. Biblical records, calibrated by radiocarbon-dated geological and archaeological evidence, reinforce and add detail to the chronology of the lake-level fluctuations. There are three historically documented phases of the Dead Sea in the Biblical record: low lake levels ca. 2000–1500 B.C.E. (before common era); high lake levels ca. 1500–1200 B.C.E.; and low lake levels between ca. 1000 and 700 B.C.E. The Biblical evidence indicates that during the dry periods the southern basin of the Dead Sea was completely dry, a fact that was not clear from the geological and archaeological data alone.