Starburst activity in a ROSAT narrow emission-line galaxy

We present multiwaveband photometric and optical spectropolarimetric observations of the R =15.9 narrow emission-line galaxy R117_A which lies on the edge of the error circle of the ROSAT X-ray source R117. The overall spectral energy distribution of the galaxy is well modelled by a combination of a normal spiral galaxy and a moderate-strength burst of star formation. The far-infrared and radio emission is extended along the major axis of the galaxy, indicating an extended starburst.
On positional grounds, the galaxy is a good candidate for the identification of R117, and the observed X-ray flux is very close to what would be expected from a starburst of the observed far-infrared and radio fluxes. Although an obscured high-redshift QSO cannot be entirely ruled out as contributing some fraction of the X-ray flux, we find no candidates to K =20.8 within the X-ray error box, and so conclude that R117_A is responsible for a large fraction, if not all, of the X-ray emission from R117.
Searches for indicators of an obscured AGN in R117_A have so far proven negative; deep spectropolarimetric observations show no signs of broad lines to a limit of 1 per cent and, for the observed far-infrared and radio emission, we would expect 10 times greater X-ray flux if the overall emission were powered by an AGN. We therefore conclude that the X-ray emission from R117 is dominated by starburst emission from the galaxy R117_A.     

Anoxic nitrification: Evidence from Humber Estuary sediments (UK)

Conventional understanding of the nitrogen cycle in marine sediments has changed in recent years with the discovery of an alternative pathway for ammonia oxidation via the reduction of manganese oxides (during anoxic nitrification). In anoxic sediments, the potential for manganese oxides to serve as oxidant for nitrification may be considerable yet previous work on manganese-rich sediments has suggested anoxic nitrification may not be significant. In this study, the potential for anoxic nitrification in a range of sediment types was investigated. Laboratory incubation of sediment from three sites on the Humber Estuary, a microbially diverse environment, showed anoxic accumulation of nitrate, nitrite and dinitrogen gas, with and without the addition of synthetic manganese oxides. Incubation experiments confirmed anoxic nitrification as microbially mediated, with heat-killed controls yielding negative results. The anoxic nitrification reaction significantly depleted ammonia concentrations, and occurred simultaneously with manganese-, iron- and sulphate reduction, and methanogenesis. Taken in conjunction with other studies, results suggest anoxic nitrification may not only be dependent on total manganese concentrations but on manganese dynamics. Anoxic nitrification may be explained as a non-steady state reaction, dependent on the recent stability of a sediment system. Physical perturbation of sediments may cause the redistribution and/or introduction of manganese oxides and promote anoxic nitrification. The significance and persistence of anoxic nitrification is likely to depend on the frequency and magnitude of sediment perturbation, which explains why the reaction varies so widely across studied sites, and why it may not occur in some manganese-rich sediment.     

Atmospheric forcing of fine-sand transport on a low-energy inner shelf: south-central Louisiana,USA

Hydrodynamic and sediment transport measurements from instrumentation deployed during a 54-day winter period at two sites on the Louisiana inner shelf are presented. Strong extratropical storms, with wind speeds of 7.8 to 15.1 m s^-1, were the dominant forcing mechanism during the study. These typically caused mean oscillatory flows and shear velocities about 33% higher than fair weather (averaging 12.3 and 3.2 cm s^-1 at the landward site, and 11.4 and 2.7 cm s^-1 at the seaward site, respectively). These responses were coupled with mean near-bottom currents more than twice as strong as during fair weather (10.3 and 7.5 cm s^-1 at the landward and seaward sites, respectively). These flowed in approximately the same direction as the veering wind, causing a net offshore transport of fine sand. Weak storms were responsible for little sediment transport whereas during fair weather, onshore sand transport of approximately 25-75% of the storm values appears to have occurred. This contradicts previous predictions of negligible fair-weather sediment movement on this inner shelf.     

The importance of extratropical and tropical cyclones on the short-term evolution of barrier islands along the northern Gulf of Mexico, USA

Data are presented indicating the complexity and highly variable response of beaches to cold front passages along the northern Gulf of Mexico, in addition to the impacts of tropical cyclones and winter storms. Within the past decade, an increase in the frequency of tropical storms and hurricanes impacting the northern Gulf has dramatically altered the long-term equilibrium of a large portion of this coast. A time series of net sediment flux for subaerial and nearshore environments has been established for a section of this coast in Florida, and to a lesser extent, Mississippi. The data incorporate the morphological signature of six tropical storms/hurricanes and more than 200 frontal passages.

Data indicate that (1) barrier islands can conserve mass during catastrophic hurricanes (e.g., Hurricane Opal, a strong category 4 hurricane near landfall); (2) less severe hurricanes and tropical storms can promote rapid dune aggradation and can contribute sediment to the entire barrier system; (3) cold fronts play a critical role in the poststorm adjustment of the barrier by deflating the subaerial portion of the overwash terrace and eroding its marginal lobe along the bayside beach through locally generated, high frequency, steep waves; and (4) barrier systems along the northern Gulf do not necessarily enter an immediate poststorm recovery phase, although nested in sediment-rich nearshore environments. While high wave energy conditions associated with cold fronts play an integral role in the evolution and maintenance of barriers along the northern Gulf, these events are more effective in reworking sediment after the occurrence of extreme events such as hurricanes. This relationship is even more apparent during the clustering of tropical cyclones.

It is anticipated that these findings will have important implications for the longer term evolution of barrier systems in midlatitude, microtidal settings where the clustering of storms is apparent, and winter storms are significant in intensity and frequency along the coast.     

Cross-shelf distribution of copepods and the role of event-scale winds in a northern California upwelling zone

Cross-shelf distribution and abundance of copepod nauplii and copepodids were measured during three summer upwelling seasons (2000–2002) in a coastal upwelling zone off northern California. These 3 years varied considerably in the intensity of winds, abundance of chlorophyll, and water temperature. The cruises in 2000 were characterized by relaxation conditions, with generally high levels of chlorophyll and high water temperature. The cruises in 2001 and 2002 were dominated by strong and persistent upwelling events, leading to lower chlorophyll and water temperatures. The copepod assemblage was dominated by Oithona spp., Acartia spp. and Pseudocalanus spp., with Metridia pacifica (lucens), Microsetella rosea, Oncaea spp. and Tortanus discaudatus also common during all 3 years. The cross-shelf distribution of copepods was generally shifted offshore during upwelling and onshore during relaxation events, although some variability between species occurred. Abundance of all life stages generally exhibited a negative correlation with cross-shelf transport averaged over at least 1–4 days and lagged by 0–3 days, indicating lower abundances during and immediately after active upwelling. However, copepod nauplii seemed to respond positively to wind events lasting 1–5 days followed by a period of relaxation lasting 6 or 7 days. These rapid rates of change in abundance are probably too great to be due to in situ growth and reproduction alone; physical processes must also play a role. These results suggest a highly dynamic relationship between copepods and upwelling events off northern California, with species-specific responses to upwelling to be expected.     

Influence of physiology and climate on δD of leaf wax n-alkanes from C3 and C4 grasses

We measured hydrogen isotope compositions (δD) of high-molecular-weight n-alkanes (C₂₇-C₃₃) from grasses grown in greenhouses and collected from the US Great Plains. In both cases, n-alkanes from C₄ grasses are enriched in D by more than 20‰ relative to those from C₃ grasses. The apparent enrichment factor (ε_C29-GW) between C₂₉n-alkane and greenhouse water is −165 ± 12‰ for C₃ grasses and −140 ± 15‰ for C₄ grasses. For samples from the Great Plains, δD values of C₂₉n-alkanes range from −280 to −136‰, with values for C₄ grasses ca. 21‰ more positive than those for C₃ grasses from the same site. Differences in C₃ and C₄ grass n-alkane δD values are consistent with the shorter interveinal distance in C₄ grass leaves, and greater back-diffusion of enriched water from stomata to veins, than in C₃ grass leaves. Great Plains’ grass n-alkane isotopic ratios largely reflect precipitation δD values. However, the offset or apparent fractionation between n-alkanes and precipitation is not uniform and varies with annual precipitation and relative humidity, suggesting climatic controls on lipid δD values. The dryer sites exhibit smaller absolute apparent fractionation indicative of D-enrichment of source waters through transpiration and/or soil evaporation. To explore the relationship between climate and n-alkane δD values, we develop three models. (1) The ‘direct analog’ model estimates δD_C29 values simply by applying the apparent enrichment factors, ε_C29-GW, observed in greenhouse grasses to precipitation δD values from the Great Plains. (2) The ‘leaf-water’ model uses a Craig-Gordon model to estimate transpirational D-enrichment for both greenhouse and field sites. The transpiration-corrected enrichment factors between C₂₉ and bulk leaf-water, ε_C29-GW, calculated from the greenhouse samples (−181‰ for C₃ and −157‰ for C₄) are applied to estimate δD_C29 values relative to modeled bulk leaf-water δD values. (3) The ‘soil- and leaf-water’ model estimates the combined effects of soil evaporation, modeled by analogy with a flow-through lake, and transpiration on δD_C29 values. Predictions improve with the addition of the explicit consideration of transpiration and soil evaporation, indicating that they are both important processes in determining plant lipid δD values. D-enrichment caused by these evaporative processes is controlled by relative humidity, suggesting that important climatic information is recorded in leaf wax n-alkane δD values. Calibration studies such as this one provide a baseline for future studies of plant-water-deuterium systematics and form the foundation for interpretation of plant wax hydrogen isotope ratios as a paleo-aridity proxy.     

Cosmogenic-nuclide ages for New England coastal moraines, Martha's Vineyard and Cape Cod, Massachusetts, USA

Cosmogenic-nuclide exposure ages for 13 glacially transported boulders atop the Martha's Vineyard moraine, MA, USA, indicate that the southeastern margin of the Laurentide ice sheet reached its maximum extent during the last glaciation 23,200±500 yr ago. Another 10 age determinations from the younger Buzzards Bay moraine near Woods Hole, MA, indicate that this moraine complex was formed 18,800±400 yr ago. These ages correlate approximately with the terminations of cooling cycles recorded in Greenland ice cores and coeval ice-rafting events, suggesting that the marginal position of this sector of the ice sheet was tightly coupled to North Atlantic climate during the last glacial maximum.     

δC of low-molecular-weight organic acids generated by the hydrous pyrolysis of oil-prone source rocks

Low-molecular-weight (LMW) aqueous organic acids were generated from six oil-prone source rocks under hydrous-pyrolysis conditions. Differences in total organic carbon-normalized acid generation are a function of the initial thermal maturity of the source rock and the oxygen content of the kerogen (OI). Carbon-isotope analyses were used to identify potential generation mechanisms and other chemical reactions that might influence the occurrence of LMW organic acids. The generated LMW acids display increasing ¹³C content as a function of decreasing molecular weight and increasing thermal maturity. The magnitudes of observed isotope fractionations are source-rock dependent. These data are consistent with δ¹³C values of organic acids presented in a field study of the San Joaquin Basin and likely reflect the contributions from alkyl-carbons and carboxyl-carbons with distinct δ¹³C values. The data do not support any particular organic acid generation mechanism. The isotopic trends observed as a function of molecular weight, thermal maturity, and rock type are not supported by either generation mechanisms or destructive decarboxylation. It is therefore proposed that organic acids experience isotopic fractionation during generation consistent with a primary kinetic isotope effect and subsequently undergo an exchange reaction between the carboxyl carbon and dissolved inorganic carbon that significantly influences the carbon isotope composition observed for the entire molecule. Although generation and decarboxylation may influence the δ¹³C values of organic acids, in the hydrous pyrolysis system described, the nondestructive, pH-dependent exchange of carboxyl carbon with inorganic carbon appears to be the most important reaction mechanism controlling the δ¹³C values of the organic acids.     

Using Hydrogeochemical Methods To Evaluate Complex Quaternary Subsurface Stratigraphy Block Island,Rhode Island,USA

One of the major problems in hydrogeologic investigations of glaciated regions is the determination of complex stratigraphic relationships in the subsurface where insufficient information is available from drilling and geophysical records. In this paper, chemical characteristics of groundwater were used to identify stratigraphic changes in glacial deposits that were previously inferred on Block Island, Rhode Island, USA, an emergent remnant of the late Wisconsinan terminal moraine, located approximately 16 km south of the Rhode Island mainland. Two chemically distinct water types are recognized on the island: 1) high-iron, characterized by dissolved silica levels in excess of 20 mg/L, bicarbonate greater than 30 mg/L and dissolved iron ranging from 1-20 mg/L; and 2) low-iron, characterized by dissolved silica levels below 16 mg/L, bicarbonate less than 30 mg/L, and less than 0.3 mg/L dissolved iron. The spatial distribution of iron-bearing minerals and organic matter and the resulting redox conditions are believed to control the occurrence of high-iron groundwater. The high-iron waters occur almost exclusively in the eastern half of the island and appear to coincidence with the presence of allochthonous blocks of Cretaceous-age coastal-plain sediments that were incorporated into Pleistocene-age deposits derived from the Narragansett Bay-Buzzard's Bay lobe of the Late Wisconsinan Laurentide ice sheet. The low-iron waters occur in the western half of the island, where the occurrence of these Cretaceous-age blocks is rare and the sediments are attributed to a sublobe of the Hudson-Champlain lobe of the Late Wisconsinan ice-sheet. RÉSUMÉ: L'un des principaux problèmes dans les études hydrogeologiques des régions qui ont été englacées est la définition des relations stratigraphiques complexes sous la surface, lá où les informations fournies par les forages et par la géophysique sont insuffisantes. Dans l'exemple traité, les caractéristiques chimiques de l'eau souterraine sont utilisées pour identifier les variations stratigraphiques dans les dépôts glaciaires qui avaient auparavant été supposées, sur l'île de Block (Rhode Island), restes émergeant d'une moraine terminale du Wisconsinien récent, situé à environ 16 km au sud de Rhode Island. Deux types d'eau chimiquement distincts ont été reconnus dans l'île: 1) à fortes teneurs en fer, caractérisées par des concentrations en silice supérieures à 20 mg/L, en bicarbonates supérieures à 30 mg/L et en fer comprises entre 1 et 20 mg/L; et 2) à faibles teneurs en fer, marquées par des concentrations en silice inférieures à 16 mg/L, en bicarbonate inférieures à 30 mg/L et en fer dissous inférieures à 0.3 mg/L. La distribution spatiale des minéraux riches en fer et de la matière organique et les conditions redox résultantes contrôlent probablement la présence de fer dans les eaux souterraines à fortes concentrations. Les eaux à fortes teneurs en fer sont connues presque exclusivement dans la moitié orientale de l'île et semblent coïncider avec la présence de blocs allochtones provenant des sédiments côtiers crétacés, introduits dans les formations pléistocènes liées au lobe glaciaire des baies de Narragansett et du Busard de la calotte glaciaire laurentide du Wisconsinien récent. Les eaux à faibles teneurs en fer apparaissent dans la moitié occidentale de l'île, là où ces blocs de Crétacé sont rares et où les sédiments sont attrbués à une digitation du lobe de l'Hudson-Champlain de la calotte glaciaire du Wisconsinien récent. RESUMEN: Uno de los mayores problemas en la investigación hidrogeológica en regiones glaciares es la determinación de las complejas relaciones estratigráficas en el subsuelo, donde la información procedente de registros de perforaciones y de geofísica no es suficiente. En este artículo, se han usado las características químicas del agua subterránea para identificar unos cambios estratigráficos que se habían predicho previamente en unos depósitos glaciares en Block Island, Rhode Island (Estados Unidos), un remanente emergente de la morrena terminal del Winsconsiniense tardío, situada unos 16 km al sur de la Rhode Island continental. En la isla se encuentran dos tipos de agua distintos: 1) de alto contenido en hierro, caracterizada por niveles de sílice disuelto superando los 20 mg/L, bicarbonatos por encima de 30 mg/L y hierro disuelto oscilando entre 1-20 mg/L; y 2) de bajo contenido en hierro, caracterizada por niveles de sílice disuelto inferiores a 16 mg/L, bicarbonatos por debajo de 30 mg/L y menos de 0.3 mg/L de hierro disuelto. La distribución espacial de los minerales ricos en hierro y de la materia orgánica, así como las condiciones redox resultantes se supone que condicionan la presencia de aguas de alto contenido en hierro. Estas aguas aparecen casi exclusivamente en la mitad oriental de la isla y parecen coincidir con la presencia de bloques alóctonos de sedimentos costeros, de edad cretácica, que se incorporaron a los depósitos de edad pleistocena procedentes del lóbulo de la Bahía de Narragansett-Bahía de Buzzard, correspondiente a la capa glaciar del Winsconsiniense-Lauréntido tardío. Las aguas de bajo contenido en hierro aparecen en la mitad occidental de la isla, donde la presencia de estos sedimentos de edad cretácica es rara y los sedimentos se suponen procedentes de un sublóbulo del lóbulo de Hudson-Camplain, correspondiente a la capa glaciar del Winsconsiniense tardío.