Heavy metal flows in aquatic systems of the Don and Kuban river deltas

This paper presents the calculated heavy metal (Fe, Mn, Zn, Ni, Cu, Cr, Co, Cd, and Pb) flows in suspended and dissolved forms in the main navigable branches of the Don and Kuban river deltas during the low-water period of 2013–2014. This work is based on the data of field studies in which water and suspended matter samples were collected and the turbidity and water discharge in deltas were measured. A quantitative estimate of heavy metal inflows into the deltas of the Don and Kuban rivers is provided. Transformation of flows of suspended and dissolved metal forms from the delta top to the sea edge is discussed. The influence of localities (Rostov-on-Don, Temryuk) on the increase in heavy metal flows downstream is shown, and the heavy metal flows in the deltas of the Don and Kuban rivers are compared.

     

Soil cover geochemistry of mining landscapes in the South-East of Transbaikalia (City of Zakamensk)

Presented is a detailed characterization of the present state and pollution of soil cover in the influence area of the Dzhidinskii tungsten-molybdenum plant which takes into consideration the spatial geological inhomogeneity and the functional purpose of urban territories. As part of the investigation, we determined the content levels of heavy metals and metalloids in background soils, and the elements which are the main pollutants of urban soils in the zones of different functional purposes, ascertained the degree of technogenic geochemical transformation of soil cover in the city of Zakamensk, and identified the leading soiland landscape-geochemical factors for accumulation of heavy metals and metalloids in the urban topsoil (0?10 cm) horizons. An assessment was also made of the ecological hazard of soil pollution by a set of heavy metals and metalloids in the main functional zones of the city. A soil-geochemical survey was carried out, and the ICP-MS method was used to determine the total content levels of 14 heavy metals and metalloids of hazard classes I?III as well as Be, Sn, Cs and Bi. The elements were determined, which are the main pollutants of the soils in Zakamensk: W, Bi, Cd, Pb and Mo. The study revealed a need to take into account the metallogenic specific character and geological inhomogeneity of the area by using the local coefficients of concentration (EF _l ) and dispersal (DF _l ) which must be calculated not with respect to the average regional background but from the individual (for each parent material) background value in order to more accurately determine the degree of technogenic geochemical transformation of soils, and the ecological hazard of pollution. It is suggested that the ecological hazard should be assessed on the basis of the Integrated Pollution Index (IPI) which is calculated with respect to the world’s average concentrations of heavy metals and metalloids in soils and takes into account hazard classes of elements.     

Polycyclic Aromatic Hydrocarbons in Urban Soils Sealed under Asphalt Concrete

Doklady Earth Sciences - For the first time, the concentrations of 11 polycyclic aromatic hydrocarbons (PAHs) in urban sealed soils (ekranozems) and asphalt concrete pavement in eastern Moscow have...     

Heavy metals in the air and snow cover of Ulan Bator

Field observations have been used to characterize air pollution in Ulan Bator by heavy metals during the 2008/2009 heating season. The degree of technogenicity of emissions and their main sources are determined. The diurnal and seasonal dynamics of atmospheric pollution are considered. It is found that many pollutants exceed maximum permissible concentrations (MPC). The most dangerous components in the urban atmosphere include Pb (up to 26 mean daily maximum permissible concentrations (MPCmd) and airborne particles (up to 21 MPCmd). The study revealed very high levels of total air pollution, especially in the center of the city (air pollution index (API) > 50)). Soluble forms of heavy metals as contained in the snow are characterized by a maximally high degree of pollution hazard for the urban environment, with a low degree corresponding to solid-phase depositions. Snow cover pollution decreases as follows: yurt districts > industrial zone > multi-storey districts.     

Sedimentation patterns in the Selenga River delta under changing hydroclimatic conditions

The Selenga River delta (Russia) is a large (>600 km²) fluvially dominated fresh water system that transfers water and sediment from an undammed drainage basin into Lake Baikal, a United Nations Educational, Scientific, and Cultural Organization World Heritage Site. Through sedimentation processes, the delta and its wetlands provide important environmental services, such as storage of sediment‐bound pollutants (e.g., metals), thereby reducing their input to Lake Baikal. However, in the Selenga River delta and many other deltas of the world, there is a lack of knowledge regarding impacts of potential shifts in the flow regime (e.g., due to climate change and other anthropogenic impacts) on sedimentation processes, including sediment exchanges between deltaic channels and adjacent wetlands. This study uses field measurements of water velocities and sediment characteristics in the Selenga River delta, investigating conditions of moderate discharge, which have become more frequent over the past decades (at the expense of peak flows, Q > 1,350 m³ s^?1). The aims are to determine if the river system under moderate flow conditions is capable of supporting sediment export from the main distributary channels of the delta to the adjacent wetlands. The results show that most of the deposited sediment outside of the deltaic channels is characterized by a large proportion of silt and clay material (i.e., <63 μm). For example, floodplain lakes function as sinks of very fine sediment (e.g., 97% of sediment by weight < 63 μm). Additionally, bed material sediment is found to be transported outside of the channel margins during conditions of moderate and high water discharge conditions (Q ≥ 1,000 m³ s^?1). Submerged banks and marshlands located in the backwater zone of the delta accumulate sediment during such discharges, supporting wetland development. Thus, these regions likely sequester various metals bound to Selenga River sediment.