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Karina Marshall-Bowman Dimitri A. Sverjensky Robert M. Hazen 《Geochimica et cosmochimica acta》2010,74(20):5852-5861
The abiotic polymerization of amino acids may have been important for the origin of life, as peptides may have been components of the first self-replicating systems. Though amino acid concentrations in the primitive oceans may have been too dilute for significant oligomerization to occur, mineral surface adsorption may have provided a concentration mechanism. As unactivated amino acid polymerization is thermodynamically unfavorable and kinetically slow in aqueous solution, we studied mainly the reverse reaction of polymer degradation to measure the impact of mineral surface catalysis on peptide bonds.Aqueous glycine (G), diglycine (GG), diketopiperazine (DKP), and triglycine (GGG) were reacted with minerals (calcite, hematite, montmorillonite, pyrite, rutile, or amorphous silica) in the presence of 0.05 M, pH 8.1, KHCO3 buffer and 0.1 M NaCl as background electrolyte in a thermostatted oven at 25, 50 or 70 °C. Below 70 °C, reaction kinetics were too sluggish to detect catalytic activity over amenable laboratory time-scales. Minerals were not found to have measurable effects on the degradation or elongation of G, GG or DKP at 70 °C in solution. At 70 °C pyrite was the most catalytic mineral with detectible effects on the degradation of GGG, although several others also displayed catalytic behavior. GGG degraded ∼1.5-4 times faster in the presence of pyrite than in control reactions, depending on the ratio of solution concentration to mineral surface area. The rate of pyrite catalysis of GGG hydrolysis was found to be saturable, suggesting the presence of discrete catalytic sites on the mineral surface. The mineral-catalyzed degradation of GGG appears to occur via a GGG → DKP + G mechanism, rather than via GGG → GG + G, as in solution-phase reactions. These results are compatible with many previous findings and suggest that minerals may have assisted in peptide synthesis in certain geological settings, specifically by speeding the approach to equilibrium in environments where amino acids were already highly concentrated, but that minerals may not significantly alter the expected solution-phase equilibria. Thus the abiotic synthesis of long peptides may have required activating agents, dry heating at higher temperatures, or some form of phase separation. 相似文献
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Riparian plants can adapt their water uptake strategies based on climatic and hydrological conditions within a river basin. The response of cold-alpine riparian trees to changes in water availability is poorly understood. The Lhasa River is a representative cold-alpine river in South Tibet and an under-studied environment. Therefore, a 96 km section of the lower Lhasa River was selected for a study on the water-use patterns of riparian plants. Plant water, soil water, groundwater and river water were measured at three sites for δ18O and δ2H values during the warm-wet and cold-dry periods in 2018. Soil profiles differed in isotope values between seasons and with the distance along the river. During the cold-dry period, the upper parts of the soil profiles were significantly affected by evaporation. During the warm-wet period, the soil profile was influenced by precipitation infiltration in the upper reaches of the study area and by various water sources in the lower reaches. Calculations using the IsoSource model indicated that the mature salix and birch trees (Salix cheilophila Schneid. and Betula platyphylla Suk.) accessed water from multiple sources during the cold-dry period, whereas they sourced more than 70% of their requirement from the upper 60–80 cm of the soil profile during the warm-wet period. The model indicated that the immature rose willow tree (Tamarix ramosissima Ledeb) accessed 66% of its water from the surface soil during the cold-dry period, but used the deeper layers during the warm-wet period. The plant type was not the dominant factor driving water uptake patterns in mature plants. Our findings can contribute to strategies for the sustainable development of cold-alpine riparian ecosystems. It is recommended that reducing plantation density and collocating plants with different rooting depths would be conducive to optimal plant growth in this environment. 相似文献
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Alatorre-Ibargüengoitia Miguel A. Hernández-Urbina Karina Ramos-Hernández Silvia G. 《Natural Hazards》2021,106(1):1011-1035
Natural Hazards - The 1982 eruption of El Chichón volcano constitutes the worst volcanic disaster in Mexico producing more than 2000 fatalities, thousands of displaced people and severe... 相似文献
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Area usage estimation and spatiotemporal variability in distribution patterns of southern right whales,Eubalaena australis,of southern Brazil
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Eduardo Pires Renault‐Braga Karina Rejane Groch Paulo A. de Carvalho Flores Eduardo R. Secchi Luciano Dalla‐Rosa 《Marine Ecology》2018,39(3)
Southern right whales—Eubalaena australis (Desmoulins, 1822)—migrate seasonally from high‐latitude feeding grounds to coastal breeding and calving grounds at lower latitudes such as the southern coast of Brazil. Understanding how these whales are distributed along the coast is important for monitoring their postwhaling recovery and defining management strategies. In this study, we applied Kernel density estimators to aerial survey data to determine main occurrence and concentration areas of right whales in southern Brazil and investigate inter‐ and intra‐annual distribution patterns between 2003 and 2012. Our results show considerable variation in area usage within and among years, and changes in the general distribution pattern of right whales in the last years of the study. Intra‐annually, higher concentration area tended to expand from July to September and decrease in November. Some areas stood out as high‐density areas for right whales: Ribanceira/Ibiraquera, Itapirubá Sul/Sol, and from Arroio to Gaivota. Some evidences also suggest preferential areas for mother–calf pairs. The higher concentration area of right whales in southern Brazil was estimated at 52,541 km2 and the occurrence area was 682.69 km2, which is the whole study area. As right whale distribution in the region is likely expanding due to this population's current recovery, our study provides essential information for management plan of the Right Whale Environmental Protection Area. 相似文献
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Sources of dissolved REE in mountainous streams draining granitic rocks, Sierras Pampeanas (Córdoba, Argentina) 总被引:1,自引:0,他引:1
M. Gabriela García Karina L. Lecomte Andrea I. Pasquini Stella M. Formica Pedro J. Depetris 《Geochimica et cosmochimica acta》2007,71(22):5355-5368
Stream waters draining granitic terrains from the highest part (850 to 2200 m a.s.l.) of Sierras Pampeanas (Córdoba, Argentina, ∼32°S, ∼65°W) were sampled in order to define sources and distribution of dissolved rare earth elements (REE), and to describe the geochemical processes that govern their mobility. The contribution of the regional granite to the dissolved REE pool in stream water is limited due to the physical conditions predominating in the area (i.e., steep slopes and semiarid climate). Therefore, precipitation is considered a seasonally significant source controlling REE concentration in stream water. Dissolved REE concentrations are inversely correlated with monthly precipitation and rainfall frequency. During the rainy season (i.e., the austral summer) REE concentrations in stream water are lower than during the dry season (i.e., austral winter). Such low concentrations reflect the balance between the REE input from precipitation and their removal by adsorption. In contrast, during the dry season, the longer residence time of water within fractures and colluvium determines an increased REE concentration in the base flow. Lower pH values also contribute to raise REE concentration through desorption from mineral surfaces. 相似文献
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Tropospheric refractivity and zenith path delays from least-squares collocation of meteorological and GNSS data 总被引:1,自引:0,他引:1
Karina Wilgan Fabian Hurter Alain Geiger Witold Rohm Jarosław Bosy 《Journal of Geodesy》2017,91(2):117-134
Precise positioning requires an accurate a priori troposphere model to enhance the solution quality. Several empirical models are available, but they may not properly characterize the state of troposphere, especially in severe weather conditions. Another possible solution is to use regional troposphere models based on real-time or near-real time measurements. In this study, we present the total refractivity and zenith total delay (ZTD) models based on a numerical weather prediction (NWP) model, Global Navigation Satellite System (GNSS) data and ground-based meteorological observations. We reconstruct the total refractivity profiles over the western part of Switzerland and the total refractivity profiles as well as ZTDs over Poland using the least-squares collocation software COMEDIE (Collocation of Meteorological Data for Interpretation and Estimation of Tropospheric Pathdelays) developed at ETH Zürich. In these two case studies, profiles of the total refractivity and ZTDs are calculated from different data sets. For Switzerland, the data set with the best agreement with the reference radiosonde (RS) measurements is the combination of ground-based meteorological observations and GNSS ZTDs. Introducing the horizontal gradients does not improve the vertical interpolation, and results in slightly larger biases and standard deviations. For Poland, the data set based on meteorological parameters from the NWP Weather Research and Forecasting (WRF) model and from a combination of the NWP model and GNSS ZTDs shows the best agreement with the reference RS data. In terms of ZTD, the combined NWP-GNSS observations and GNSS-only data set exhibit the best accuracy with an average bias (from all stations) of 3.7 mm and average standard deviations of 17.0 mm w.r.t. the reference GNSS stations. 相似文献
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Shin Giek Goh Stéphane Bayen David Burger Barry C. Kelly Ping Han Vladan Babovic Karina Yew-Hoong Gin 《Marine pollution bulletin》2017,114(1):627-634
Water quality in Singapore's coastal area was evaluated with microbial indicators, pathogenic vibrios, chemical tracers and physico-chemical parameters. Sampling sites were grouped into two clusters (coastal sites at (i) northern and (ii) southern part of Singapore). The coastal sites located at northern part of Singapore along the Johor Straits exhibited greater pollution. Principal component analysis revealed that sampling sites at Johor Straits have greater loading on carbamazepine, while turbidity poses greater influence on sampling sites at Singapore Straits. Detection of pathogenic vibrios was also more prominent at Johor Straits than the Singapore Straits. This study examined the spatial variations in Singapore's coastal water quality and provided the baseline information for health risk assessment and future pollution management. 相似文献
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Ole Baltazar Andersen Karina Nielsen Per Knudsen Chris W. Hughes Rory Bingham Luciana Fenoglio-Marc 《Marine Geodesy》2013,36(6):517-545
AbstractThe ocean mean dynamic topography (MDT) is the surface representation of the ocean circulation. The MDT may be determined by the ocean approach, which involves temporal averaging of numerical ocean circulation model information, or by the geodetic approach, wherein the MDT is derived using the ellipsoidal height of the mean sea surface (MSS), or mean sea level (MSL) minus the geoid as the geoid. The ellipsoidal height of the MSS might be estimated either by satellite or coastal tide gauges by connecting the tide gauge datum to the Earth-centred reference frame. In this article we present a novel approach to improve the coastal MDT, where the solution is based on both satellite altimetry and tide gauge data using new set of 302 tide gauges with ellipsoidal heights through the SONEL network. The approach was evaluated for the Northeast Atlantic coast where a dense network of GNSS-surveyed tide gauges is available. The typical misfit between tide gauge and satellite or oceanographic MDT was found to be around 9?cm. This misfit was found to be mainly due to small scale geoid errors. Similarly, we found, that a single tide gauge places only weak constraints on the coastal dynamic topography. 相似文献