Structure energies of the alkali feldspars

Structural energetics of the alkali feldspars have been studied using a “lattice” or structure energy model. Electrostatic energies, U _e,for 20 well-refined, non-intergrown alkali feldspars were calculated using Bertaut's (1952) summation procedure and average about ?13,400 kcal/mol; the repulsive energies of the alkali site in each structure (～15 kcal/mol) were calculated using repulsive parameters for K-O and Na-O interactions estimated from bulk modulus data for NaF and KF and the exponential form of the repulsive potential. Using a procedure in which the position of the alkali cation was varied while the oxygen cage was kept fixed, structure energy gradients for the alkali sites of high albite and a hypersolvus Ab₄₂Or₅₈ structure were computed. In both cases, a broad structure energy well, elongated approximately parallel to c and subparallel to the observed split Na positions, was found. In both structures there is a single energy minimum corresponding closely with the observed single alkali positions. Comparison of U _e values for the alkali feldspars with different K/Na ratios shows that intermediate compositions are predicted to be less “stable” than either endmember and that the potassic end-member is predicted to be less “stable” than the sodic one, assuming that all other factors contributiong to the free energies of each phase are approximately the same. Comparison of U _e values for the high albite and low sanidine structures with different Al/Si distributions and a fixed tetrahedral framework indicates that the ordered charge distributions are 63.0 and 54.8 kcal/mol, respectively, more “stable” than the disordered distributions. Smaller, more realistic energy differences were obtained by using U _evalues averaged from four separate calculations with a +3 charge on a different T site in each and with +4 charges on the other T sites. If, in addition, the charges on cations and oxygen are reduced to half their nominal formal charges, in agreement with Pauling's electroneutrality principle and the results of recent molecular orbital calculations on silicates, the predicted electrostatic energy differences are reduced to 3.6 and 1.6 kcal/mol, respectively. These calculations also indicate that the T₁O site in the high albite structure energetically favors Al and that the Al/Si distribution determines the Na position within the alkali site.     

A 180 ka record of environmental change at Erdut (Croatia): a new chronology for the loess–palaeosol sequence and its implications for environmental interpretation

While there are numerous thick loess–palaeosol sequences preserved across the Carpathian Basin, well dated sites that provide terrestrial palaeoenvironmental records extending beyond last glacial–interglacial cycle are scarce. Robust chronologies are essential for correlations of loess with other long-term Quaternary records and to further understanding of the palaeoenvironment and climate of this important region beyond the last 125 ka. Here a new geochronology based on 13 post-infrared infrared stimulated luminescence ages focused on the lower part of the loess–palaeosol sequence at Erdut is presented. The results show that the lower part of the Erdut profile spans the penultimate glacial cycle (MIS 7 to MIS 5). The considerable sediments overlaying the investigated part of the profile suggest that this section spans two glacial cycles, rather than the previously suggested one. The most likely source of the discrepancy is the use of uncorrected infrared stimulated luminescence signal, which can cause age underestimation if not accounted for. This study demonstrates the need to revisit sites such as Erdut, re-date them using updated measurement protocols, and update existing palaeoenvironmental interpretations.     

Some results of aerosol measurements

Summary In brief a newly developed freezing nuclei meter is described. Results of measurements made with this instrument in New Jersey, California and in the Thule area, Greenland, are shown. These data are compared with measurements of condensation nuclei, simultaneously made with the General Electric and the Aitkennuclei counters. Also the results obtained from some measurements of the lightscattering function of the aerosol in industrial areas near New York City are presented.     

Identification of seismic anomalies caused by gas saturation on the basis of theoretical P and PS wavefield in the Carpathian Foredeep,SE Poland

The thin-layer build of the Carpathian Foredeep Miocene formations and large petrophysical parameter variation cause seismic images of gas-saturated zones to be ambiguous, and the location of prospection wells on the basis of anomalous seismic record is risky. A method that assists reservoir interpretation of standard recorded seismic profiles (P waves) can be a converted wave recording (PS waves). This paper presents the results of application of a multicomponent seismic survey for the reservoir interpretation over the Chałupki Dębniańskie gas deposit, carried out for the first time in Poland by Geofizyka Kraków Ltd. for the Polish Oil and Gas Company. Seismic modeling was applied as the basic research tool, using the SeisMod program based on the finite-difference solution of the acoustic wave equation and equations of motion. Seismogeological models for P waves were developed using Acoustic Logs; S-wave model (records only from part of the well) was developed on the basis of theoretical curves calculated by means of the Estymacja program calibrated with average S-velocities, calculated by correlation of recorded P and PS wavefields with 1D modeling. The conformity between theoretical and recorded wavefields makes it possible to apply the criteria established on the basis of modeling for reservoir interpretation. Direct hydrocarbon indicators (bright spots, phase change, time sag) unambiguously identify gas-prone layers within the ChD-2 prospect. A partial range of the indicators observed in the SW part of the studied profile (bright spot that covers a single, anticlinally bent seismic horizon) points to saturation of the horizon. The proposed location is confirmed by criteria determined for converted waves (continuous seismic horizons with constant, high amplitude) despite poorer agreement between theoretical and recorded wavefields.     

Particle size analysis of the sediment suspended in a proglacial stream: Glacier De tsidjiore Nouve,Switzerland

Hourly, at-a-point samples of suspended sediment taken from the outflow stream of Glacier de Tsidjiore Nouve, Switzerland, over a 60 day sampling period (n = 1440) are shown to be dominantly composed of silt-sized particles. Particle size, SEM, and XRD analyses indicate a subglacial provenance for the suspended sediment. Temporal variations in particle size and sorting correspond poorly to fluctuations in water discharge, being dominated by erratic hour-to-hour fluctuations and clockwise hysteresis over diurnal flow events. Examination of grain size and sorting dynamics over snowmelt- and icemelt-related ablation events, during precipitation events, and during glacier drainage events enables some inferences to be drawn regarding sediment source areas and supply regimes. We conclude that although the bulk of the suspended sediment in the proglacial stream of Glacier de Tsidjiore Nouve is derived directly from subglacial sources (with occasional contributions from the valley train during rapid snowmelt and heavy rainfall periods), a portion of the suspended load undergoes intermittent ‘flush-fall’ transfer through the proglacial zone, which acts as a sediment source during rising flows and as a sink during periods of waning flow.     

Re-analysis of late Quaternary dust mass accumulation rates in Serbia using new luminescence chronology for loess–palaeosol sequence at Surduk

Despite numerous palaeoenvironmental investigations of loess–palaeosol sequences across the Carpathian Basin, well-dated high-resolution records are scarce. This paper presents a new high-resolution chronology for the loess-palaeosol sequence at Surduk (Serbia), based on optically stimulated luminescence (quartz) and post-infrared infrared stimulated luminescence (polymineral) dating. The presented record spans 53–19 ka, with primary loess deposition occurring after 52±2 ka, and differs from previously published chronologies that relied on less precise and now superseded dating protocols. Based on the new chronology, mass accumulation rates (MARs) for Surduk were constructed and compared with sites in the Carpathian Basin. The results demonstrate that accumulation periods across this area are not consistent in timing or rates. The high-resolution dating strategy identifies a disturbance in sediment deposition that occurred after 45±2 ka and implies that site contains a hiatus. Finally, we show samples that failed routine dose recovery and preheat plateau tests, and had low fast ratios. Supported by bulk sample geochemical analysis it is proposed that a potential abrupt source shift, during the Last Glacial Maximum, may be the cause of the anomalous luminescence behaviour.     

Structure of mineral glasses—III. NaAlSi3O8 supercooled liquid at 805°C and the effects of thermal history

The distribution of interatomic distances in amorphous NaAlSi₃O₈ has been determined at 805°C by X-ray radial distribution analysis to investigate structural differences between the glass (T < 763°C) and the supercooled liquid (763°C < T < 1118°C). Except for slight differences attributable to thermal expansion, no significant changes were observed. The sample crystallized during the course of the experiment, but at least one crystal-free data set was obtained. The transition from the inferred six-membered ring structure of the supercooled liquid to the four-membered ring structure of the crystal was clearly visible in radial distribution function (RDF's) determined before and after crystallization.RDF's were also determined at 25°C for two NaAlSi₃O₈ glasses with different histories. The first was derived from a melt that had been cooled slowly from 1600 to 32°C above the melting point (T_f = 1118°C) to detect possible repolymerization to a more ‘crystal-like’ structure as the melt approached T_f. The second glass was prepared by holding a single crystal of Amelia albite at 50°C above T_f to see if the crystalline four-membered ring structure was preserved in melts at temperatures just above the liquidus. No significant differences were observed between these two RDF's and one obtained from a glass quenched from 1800°C. These results suggest that in addition to the destruction of formation of a periodic structure, melting and crystallization in NaAlSi₃O₈ also involves a repolymerization of tetrahedra. This would explain the observed kinetic barrier to melting and crystallization in the anhydrous system and the catalytic effect of small amounts of water or alkali oxide.     

天津市中心城区及附近热储层间的水力联系

文章利用水文地球化学和环境同位素调查方法,对天津市中心城区附近各主要热储层间的水力联系进行了探讨。研究结果表明,大气降水是天津市中心城区附近各热储层的补给水源,各大断裂是沟通各热储层间水力联系的关键因素。     

The application of well logging and seismic modeling to assess the degree of gas saturation in Miocene strata (Carpathian Foredeep, Poland)

The presence of natural gas in the pore space of reservoir rocks results in a significant decrease in P-wave velocity. Even low gas saturation can generate seismic anomalies (DHI) and false image of gas accumulation of economic importance. This article presents an attempt to evaluate gas saturation from 2D seismic section in the Miocene sandstone strata in the south-eastern part of the Carpathian Foredeep. The ESTYMACJA program and the Biot-Gassmann model were used to study the dependence between elastic parameters and saturating fluids (water and gas) recorded in wells. Series of calculations was carried out using a method of fluid substitution for various gas saturation. The applicability of seismic data for evaluating gas saturation of reservoir beds was assessed with the use of 1D modelling (synthetic seismograms) and 2D modelling (theoretical seismic section) calculated for different gas saturation. The proposed methodology can be used to identify low and high gas-saturated zones and contour the reservoir.