X-Ray Fluorescence Determination of Trace Elements in 6 B.C.S. and 5 P.R.E. Reference Materials

The concentrations of 20 trace elements in 6 British Chemical Standards (BCS) reference materials and 5 European Federation of Refractories Producers (PRE) reference materials have been determined by X-ray fluorescence spectrometry.     

Morphology and genesis of nodular chalks and hardgrounds in the Upper Cretaceous of southern England

The Upper Cretaceous chalks of southern England are a thick sequence of rhythmically bedded, bioturbated coccolith micrites, deposited in an outer shelf environment in water depths which varied between 50 and 200–300 m. The products of sea floor cementation are widely represented in the sequence, and a series of stages of progressive lithification can be recognized. These began with a pause in sedimentation and the formation of an omission surface, followed by (a) growth of discrete nodules below the sediment-water interface to form a nodular chalk, erosion of which produced intraformational conglomerates. (b) Further growth and fusion of nodules into continuous or semicontinuous layers: incipient hardgrounds. (c) Scour, which exposed the layer as a true hardground. At this stage, the exposed lithified chalk bottom was subject to boring and encrustation by a variety of organisms, whilst calcium carbonate was frequently replaced by glauconite and phosphate to produce superficial mineralized zones. In many cases, the processes of sedimentation, cementation, exposure and mineralization were repeated several times, producing composite hardgrounds built up of a series of layers of cemented and mineralized chalk, indicating a long and complex diagenetic history. Petrographic study of early cemented chalks indicates lithification was the result of the precipitation of small crystals on and between coccoliths and coccolith fragments. By analogy with known occurrences of early lithification in Recent deeper water carbonates, the cement is believed to have been either high magnesian calcite or aragonite, and more probably the former. The vast scale of operations involved in the cementation process precludes carbonate in expelled pore fluids as the source of cement, whilst quantities of aragonite incorporated in sediment are also inadequate. This, plus the observed association of horizons of early lithification with pauses in sedimentation associated with omission surfaces suggests seawater as a source of cementing materials. Stratigraphic studies indicate that processes of early lithification leading to hardground formation proceeded to completion in intervals to be measured in tens or hundreds of years. Regional studies suggest that early lithification characterized relatively shallow water phases associated with regional regression over the whole of the area, whilst in detail, the distribution of mature mineralized hardground complexes is strongly correlated with sedimentary thinning and condensation over small areas and the buried flanks of massifs. Early cementation in more basinal areas is typically in the form of nodular developments and incipient hardgrounds, whilst day contents in excess of a few percent appear to have inhibited early lithification. The striking rhythmicity of hardgrounds and nodular chalks is no more than a particular expression of the overall rhythmicity of chalk sequences. The stage of early lithification reached in any instance is dependent on sediment type, the time interval represented by the associated omission surface and the degree of associated scour and erosion (if any). Chalk hardgrounds differ from most others described in the geological literature in their widespread distribution (individual hardgrounds may cover up to 1500 km²), the presence of striking glauconite and phosphate replacements of lithified carbonate matrices, their frequently sparse epifaunas, and boring infaunas dominated by clionid sponges. These differences reflect the deeper water shelf setting of the chalk, and the more open marine, oceanic circulatory system, both strikingly different from the setting of other, shallower water hardgrounds. Litho- and biostratigraphic variation in the chalk sequences of the area studied are summarized in an appendix.     

Zircons from Syros, Cyclades, Greece--Recrystallization and Mobilization of Zircon During High-Pressure Metamorphism

Zircons were studied from high-pressure/low-temperature metamorphosedmeta-igneous lithologies from Syros. These rocks carry severalzircon generations related to each other by dissolution–reprecipitationprocesses. One generation is pristine zircon that shows growthzoning, relatively elevated contents of trivalent cations andhigh Th/U ratios. The other end-member is a skeletal zircongeneration with negligible trivalent cation contents and lowTh/U ratios (     

Evaluation of NASA GISS Post-CMIP5 Single Column Model Simulated Clouds and Precipitation Using ARM Southern Great Plains Observations

The planetary boundary layer turbulence and moist convection parameterizations have been modified recently in the NASA Goddard Institute for Space Studies(GISS) Model E2 atmospheric general circulation model(GCM; post-CMIP5,hereafter P5). In this study, single column model(SCM P5) simulated cloud fractions(CFs), cloud liquid water paths(LWPs)and precipitation were compared with Atmospheric Radiation Measurement(ARM) Southern Great Plains(SGP) groundbased observations made during the period 2002–08. CMIP5 SCM simulations and GCM outputs over the ARM SGP region were also used in the comparison to identify whether the causes of cloud and precipitation biases resulted from either the physical parameterization or the dynamic scheme. The comparison showed that the CMIP5 SCM has difficulties in simulating the vertical structure and seasonal variation of low-level clouds. The new scheme implemented in the turbulence parameterization led to significantly improved cloud simulations in P5. It was found that the SCM is sensitive to the relaxation time scale. When the relaxation time increased from 3 to 24 h, SCM P5-simulated CFs and LWPs showed a moderate increase(10%–20%) but precipitation increased significantly(56%), which agreed better with observations despite the less accurate atmospheric state. Annual averages among the GCM and SCM simulations were almost the same, but their respective seasonal variations were out of phase. This suggests that the same physical cloud parameterization can generate similar statistical results over a long time period, but different dynamics drive the differences in seasonal variations. This study can potentially provide guidance for the further development of the GISS model.     

Source,timing, frequency and flux of ice‐rafted detritus to the Northeast Atlantic margin, 30–12 ka: testing the Heinrich precursor hypothesis

Haapaniemi, A.I., Scourse, J.D., Peck, V.L., Kennedy, H., Kennedy, P., Hemming, S.R., Furze, M.F.A., Pieńkowski, A.J., Austin, W.E.N., Walden, J., Wadsworth, E. & Hall, I.R. 2010: Source, timing, frequency and flux of ice‐rafted detritus to the Northeast Atlantic margin, 30–12 ka: testing the Heinrich precursor hypothesis. Boreas, Vol. 39, pp. 576–591. 10.1111/j.1502‐3885.2010.00141.x. ISSN 0300‐9483. Increased fluxes of ice‐rafted detritus (IRD) from European ice sheets have been documented some 1000–1500 years before the arrival of Laurentide Ice Sheet (LIS)‐sourced IRD during Heinrich (H) events. These early fluxes have become known as ‘precursor events’, and it has been suggested that they have mechanistic significance in the propagation of H events. Here we present a re‐analysis of one of the main cores used to generate the precursor concept, OMEX‐2K from the Goban Spur covering the last 30 ka, in order to identify whether the British–Irish Ice Sheet (BIIS) IRD fluxes occur only as precursors before H layers. IRD characterization and planktonic foraminiferal δ¹⁸O measurements constrained by a new age model have enabled the generation of a continuous record of IRD sources, timing, frequency and flux, and of local contemporary hydrographic conditions. The evidence indicates that BIIS IRD precursors are not uniquely, or mechanistically, linked to H events, but are part of the pervasive millennial‐scale cyclicity. Our results support an LIS source for the IRD comprising H layers, but the ambient glacial sections are dominated by assemblages typical of the Irish Sea Ice Stream. Light isotope excursions associated with H events are interpreted as resulting from the melting of the BIIS, with ice‐sheet destabilization attributed to eustatic jumps generated by LIS discharge during H events. This positive‐feedback mechanism probably caused similar responses in all circum‐Atlantic ice‐sheet margins, and the resulting gross freshwater flux contributed to the perturbation of the Atlantic Meridional Overturning Circulation during H events.     

水下喷发火山碎屑岩储层特征及主控因素:以新西兰Taranaki盆地中新世Kora火山为例

新西兰Taranaki盆地中新世Kora火山是海底喷发形成的碎屑岩型火山,可代表浅埋藏火山岩的储层特征.本文根据5口钻井的孔隙度、渗透率、孔隙孔径和铸体薄片开展Kora火山的储层特征、储集空间组成、缝宽以及原生和次生孔隙之间关系的分析.研究结果如下:(1)储集空间主要为次生孔隙,然后是裂缝和原生孔隙;Kora火山具有高...     

Analyses of the United States Geological Survey Geochemical Exploration Reference Samples GXR-I to - 6

Analyses of the United States Geological Survey geochemical exploration reference samples (GXR) 1–6 are reported for 36 elements and compared with published values.     

Genesis and diagenesis of hiatus- and breccia-concretions from the mid-Cretaceous of Texas and northern Mexico

A study of septarian concretions from late Cretaceous shale sequences of Texas and northern Mexico reveals complex burial-exhumation histories. First generation concretions and pre-fossilized moulds formed in silty clays before significant compaction occurred. Syneresis cracks developed and were filled by length slow fibrous calcite with a decrease in iron content toward the centre of each vein; in some cases this was succeeded by growth of equant or bladed calcite. Subsequent erosion of enclosing sediment caused collapse and break up of concretions, leaving fragments and some unbroken concretions exposed to encrustation and boring on the sea floor. These were subsequently buried and enclosed in a second generation of concretions, which also developed syneresis cracks. The calcite that filled these latter cracks was generally bladed (sometimes followed by equant calcite) and contains more iron toward the centre of the vein. Differences between the calcite filling first and second generation septarian veins indicates changing diagenetic regimes during burial in the marine environment, without a major shift in diagenetic conditions, such as the introduction of meteoric waters. These conclusions have significant implications to cementation in ancient limestones, which show textural and chemical sequences similar to those present in the septarian concretions described.     

Use of geochemical mass balance modelling to evaluate the role of weathering in determining stream chemistry in five mid-atlantic watersheds on different lithologies

The importance of mineral weathering was assessed and compared for five mid-Atlantic watersheds receiving similar atmospheric inputs but underlain by differing bedrock. Annual solute mass balances and volume-weighted mean solute concentrations were calculated for each watershed for each year of record. In addition, primary and secondary mineralogy were determined for each of the watersheds through analysis of soil samples and thin sections using petrographic, scanning electron microscope, electron microprobe and X-ray diffraction techniques. Mineralogical data were also compiled from the literature. These data were input to NETPATH, a geochemical program that calculates the masses of minerals that react with precipitation to produce stream water chemistry. The feasibilities of the weathering scenarios calculated by NETPATH were evaluated based on relative abundances and reactivities of minerals in the watershed. In watersheds underlain by reactive bedrocks, weathering reactions explained the stream base cation loading. In the acid-sensitive watersheds on unreactive bedrock, calculated weathering scenarios were not consistent with the abundance of reactive minerals in the underlying bedrock, and alternative sources of base cations are discussed. © 1997 John Wiley & Sons, Ltd.     

Carbonate banks and slump beds in the Upper Cretaceous (Upper Turonian-Santonian) of Haute Normandie, France

Large scale sedimentary structures present in the Upper Turonian to Santonian chalks of Haute Normandie (northern France) represent the remains of a carbonate bank complex which formerly extended over an area of at least 1500 km². Cliff exposures along the Channel coast from St Valéry-en-Caux to Cauville and along the Seine from Sandouville to Lillebonne show sections of banks up to 50 m high and 1500 m across, their internal structures picked out by hardgrounds, nodular chalks and horizons of burrow flint. Associated with banks are slump sheets up to 20 m thick, slump scars, sedimentary breccias, injection phenomena and faults contemporaneous with sedimentation. Later diagenetic features include extensive dolomitization and silicification. These structures compare closely with the Waulsortian banks of the Palaeozoic, and bryozoan bioherms known from the Upper Cretaceous and Palaeocene of Denmark. Frame-building, sediment trapping and stabilizing organisms are absent, and bank development and stabilization was probably due to a plant covering, either algal or of marine angiosperms. Banks generated much of their own sediment, whilst a pelagic constituent (calcareous nannofossils and Foraminiferida) is also present. The distribution of the bank complex is related to a basement controlled swell area, whilst the life of the complex was limited to a relatively shallow water, regressive episode in the predominantly transgressive Upper Cretaceous history of the region. Les falaises littorales du Pays de Caux comprises entre Antifer et St Valèry-enCaux, et les affleurements de la basse vallée de la Seine permettent d'observer des formations du Turonien supérieur-Sénonien inférieur qui présentent des stratifications irrégulières soulignées par de nombreux hardgrounds, des horizons de craie noduleuse et des cordons de silex. Ces structures sont identifiées à des accumulations de calcilutite et calcarénite sous forme de bancs sous-marins dont la hauteur peut atteindre 50 m et qui couvrent une surface supérieure à 1500 km²; ils apparaissent au-dessus de hardgrounds subhorizontaux qui indiquent un haut-fond régional stable. Des glissements sous-marins sont associés à ces bancs et engendrent des niveaux avec des déformations souples atteignant 20 m d'épaisseur. Des brèches apparaissent localement et contiennent des blocs basculés de hardgrounds fragmentés lors du glissement; on y observe aussi de petites failles intrasédimentaires et des phénomènes d'injection. Aucun organisme constructeur ou capable de piéger et retenir le sédiment n'a été observé. La stabilisation de ces bancs serait due à une couverture végétale (algues ou angiospermes marines) dont on sait qu'elle peut disparâitre sans laisser de trace lors de la fossilisation. La croissance de ces bancs serait réalisée par un apport de sédiment comprenant une part de nourrissage autochtone comme cela existe pour les bancs récents en eau peu profonde, associée au dépôt d'une fraction pélagique.