Isotope fractionation of neon during stepheating extraction?: a comment on ‘Re‐interpretation of the existence of a primitive plume under Australia based on neon isotope fractionation during step heating’ by Gautheron and Moreira (2003)

Using a Rayleigh distillation fractionation model, we calculate that the maximum isotope fractionation potentially achievable is less than 5% during the early stages of gas release from a sample. Our calculation corrects the erroneous conclusions of Gautheron and Moreira (2003), who re‐interpreted the plume‐like neon isotopic compositions found in metasomatic apatite from a south‐eastern Australian xenolith (Matsumoto et al., 1997) to be the result of Rayleigh‐type isotope fractionation of originally MORB‐type neon during stepheating gas extraction. We stress that the modelling of neon isotopic fractionation by Gautheron and Moreira (2003) is incorrect, and that the finding of a plume‐like neon isotopic composition in the apatite by Matsumoto et al. (1997) remains a quite valid and robust conclusion.     

Damage identification method using harmonic excitation force considering both modelling and measurement errors

A method of structural damage identification using harmonic excitation force is presented. It considers the effects of both measurement and modelling errors in the baseline finite element model. Damage that accompanies changes in structural parameters can be estimated for a damaged structure from the change between measured vibration responses and ones calculated from the analytical model of the intact structure. In practice, modelling errors exist in the analytical model due to material and geometric uncertainties and a reduction in the degrees of freedom as well as measurement errors, making identification difficult. To surmount these problems, bootstrap hypothesis testing, which enables statistical judgment without information about these errors, was introduced. The method was validated by numerical simulation using a three‐dimensional frame structure and real vibration data for a three‐storey steel frame structure. Copyright © 2005 John Wiley & Sons, Ltd.     

In situ strength measurements on natural upper-mantle minerals

Using in situ strength measurements at pressures up to 10 GPa and at room temperature, 400, 600, and 700°C, we examined rheological properties of olivine, orthopyroxene, and chromian-spinel contained in a mantle-derived xenolith. Mineral strengths were estimated using widths of X-ray diffraction peaks as a function of pressure, temperature, and time. Differential stresses of all minerals increase with increasing pressure, but they decrease with increasing temperature because of elastic strain on compression and stress relaxation during heating. During compression at room temperature, all minerals deform plastically at differential stress of 4–6 GPa. During subsequent heating, thermally induced yielding is observed in olivine at 600°C. Neither orthopyroxene nor spinel shows complete stress relaxation, but both retain some stress even at 700°C. The strength of the minerals decreases in the order of chromian-spinel ≈ orthopyroxene > olivine for these conditions. This order of strength is consistent with the residual pressure of fluid inclusions in mantle xenoliths.     

Gravity Anomaly and Tectonics in the Northern Part of the North Fiji Basin - Preliminary Result of the 1994 NOFI Cruise under the NEW STARMER Programme

A surface ship gravity survey was carried out in the northern part of the North Fiji Basin during the NOFI cruise by the R/V l'Atalante in August-September, 1994. The two ridges inside the study area, the South Pandora Ridge and the Tripartite Ridge, present different structures and states of isostatic equilibrium in terms of gravity anomaly and its tectonic implications. The former is supported by a restoring force of an imaginary elastic plate in the crust and the latter by the Airy type isostasy. These characteristics can be derived from the difference in magmatic activity, as influenced by the difference in lithospheric structure. The latter is characterised by greater active magmatism and hydrothermalism underneath the ridge than the former. Such a difference in the magmatic activity and the horizontal scale of the shallow subsurface structure is derived from the difference in the stiffness or viscosity of the lithosphere beneath the two ridges.     

Active spreading and hydrothermalism in North Fiji Basin (SW Pacific). Results of Japanese French Cruise Kaiyo 87

The aim of the Japanese-French Kaiyo 87 cruise was the study of the spreading axis in the North Fiji Basin (SW Pacific). A Seabeam and geophysical survey allowed us to define the detailed structure of the active NS spreading axis between 16° and 22° S and its relationships with the left lateral motion of the North Fiji Fracture Zone. Between 21° S and 18°10′ S, the spreading axis trends NS. From 18°10 S to 16°40 S the orientation of the spreading axis changes from NS to 015°. North of 16°40′ S the spreading axis trends 160°. These two 015° and 160° branches converge with the left lateral North Fiji fracture zone around 16°40′ S to define an RRFZ triple junction. Water sampling, dredging and photo TV deep towing give new information concerning the hydrothermal activity along the spreading axis. The discovery of hydrothermal deposits associated with living communities confirms this activity.     

Effects of salinity downshock on dimethylsulfide production

During time-series observations in Sagami Bay, Japan, the concentration of dissolved dimethylsulfoniopropionate (DMSP_d), a precursor of dimethylsulfide (DMS), was negatively correlated with salinity. In the laboratory, low-salinity shock reduced DMS production rates of the natural bacterial community and induced rapid DMSP release from a dinophyte, Heterocapsa triquetra, suggesting that low-salinity shock reduced DMSP_d consumption but enhanced DMSP_d production, which agrees with the negative correlation between DMSP_d and salinity observed in Sagami bay. In addition, low-salinity shock did not affect DMSP lyase activity of H. triquetra. Low-salinity shock would increase the contribution from algae in DMS production, leading to an increase in potential DMS productivity in the environment.     

Simple determination of dimethylsulfide (DMS) and dimethylsulfoniopropionate (DMSP) using solid-phase microextraction and gas chromatography-mass spectrometry

Solid-phase microextraction (SPME) is a simple, sensitive and less destructive method for the determination of dimethylsulfide (DMS) in seawater. Combined with detection by gas chromatography-mass spectrometry (GC-MS), the method had sufficient sensitivity (minimum detectable concentration of DMS was 0.05 nM), and practical levels of reproducibility (relative standard deviation ≤7%) and linearity (r ² > 0.995) over a wide concentration range (0.5 to 910 nM). The protocol developed was applied to a Sagami Bay water sample to determine concentrations of DMS and DMSP, and in situ DMSP-lyase activity.     

Model simulations of carbon sequestration in the northwest Pacific by patch fertilization

Iron fertilization of nutrient-rich surface waters of the ocean is one possible way to help slow the rising levels of atmospheric CO₂ by sequestering it in the oceans via biological carbon export. Here, I use an ocean general circulation model to simulate a patch of nutrient depletion in the subpolar northwest Pacific under various scenarios. Model results confirm that surface fertilization is an inefficient way to sequester carbon from the atmosphere (Gnanadesikan et al., 2003), since only about 20% of the exported carbon comes initially from the atmosphere. Fertilization reduces future production and thus CO₂ uptake by utilizing nutrients that would otherwise be available later. Effectively, this can be considered as leakage when compared to a control run. This “effective” leakage and the actual leakage of sequestered CO₂ cause a significant, rapid decrease in carbon retention (only 30–45% retained after 10 years and less than 20% after 50 years). This contrasts markedly with the almost 100% retention efficiency for the same duration using the same model, when carbon is disposed directly into the northwest Pacific (Matsumoto and Mignone, 2005). As a consequence, the economic effectiveness of patch fertilization is poor in two limiting cases of the future price path of carbon. Sequestered carbon in patch fertilization is lost to the atmosphere at increasingly remote places as time passes, which would make monitoring exceedingly difficult. If all organic carbon from one-time fertilization reached the ocean bottom and remineralized there, acidification would be about −0.05 pH unit with O₂ depletion about −20 μmol kg⁻¹. These anomalies are probably too small to seriously threaten deep sea biota, but they are underestimated in the model because of its large grid size. The results from this study offer little to advocate purposeful surface fertilization as a serious means to address the anthropogenic carbon problem.     

Amorphous interstellar grains: Wavelength dependence of far-infrared emission efficiency

It is shown theoretically that the emission efficiency of amorphous grains with radii smaller than 100 Å has a _-1-dependence in the wavelength region longer than 100 , whereas those of crystalline, metallic, and larger amorphous grains are proportional to _-2 in far infrared. Astrophysical implications of the amorphous grains are discussed.     

Quantitative reconstruction of the lake water paleotemperature of Daihai Lake, Inner Mongolia, China and its significance in paleoclimate

By measuring Sr/Ca ratios of the ostracod shells (Limnocthere cf. inopinata) in sediments of the Daihai Lake, and combined with Sr²⁺/Ca²⁺ ratios of the lake water, this paper obtained paleosalinity of the lake water. Vaporizing experiment of the lake water in laboratory showed that there was a quantitative relationship between salinity and oxygen isotope. Using this relationship, oxygen isotope values of the paleo-lake water were calculated. By measuring the oxygen isotope of the authigenic carbonate in the lake’s sediments, and in combination with the oxygen isotope values of the paleo-lake water, the paleotemperature of the lake water was calculated. Finally, based on these proxies, the paleoclimate in the lake basin was explored.