Oxygen Isotope Evidence for Chemical Interaction of Ki lauea Historical Magmas with Basement Rocks

Klauea historical summit lavas have a wide range in matrix ¹⁸O_VSMOWvalues (4·9–5·6) with lower values in rockserupted following a major summit collapse or eruptive hiatus.In contrast, ¹⁸O values for olivines in most of these lavasare nearly constant (5·1 ± 0·1). The disequilibriumbetween matrix and olivine ¹⁸O values in many samples indicatesthat the lower matrix values were acquired by the magma afterolivine growth, probably just before or during eruption. BothMauna Loa and Klauea basement rocks are the likely sources ofthe contamination, based on O, Pb and Sr isotope data. However,the extent of crustal contamination of Klauea historical magmasis probably minor (< 12%, depending on the assumed contaminant)and it is superimposed on a longer-term, cyclic geochemicalvariation that reflects source heterogeneity. Klauea's heterogeneoussource, which is well represented by the historical summit lavas,probably has magma ¹⁸O values within the normal mid-ocean ridgebasalt mantle range (5·4–5·8) based on thenew olivine ¹⁸O values. KEY WORDS: Hawaii; Klauea; basalt; oxygen isotopes; crustal contamination     

A study of microearthquake seismicity and focal mechanisms within the Sea of Marmara (NW Turkey) using ocean bottom seismometers (OBSs)

We have carried out seismological observations within the Sea of Marmara (NW Turkey) in order to investigate the seismicity induced after Gölcük–İzmit (Kocaeli) earthquake (M_w 7.4) of August 17, 1999, using ocean bottom seismometers (OBSs). High-resolution hypocenters and focal mechanisms of microearthquakes have been investigated during this Marmara Sea OBS project involving deployment of 10 OBSs within the Çınarcık (eastern Marmara Sea) and Central-Tekirdağ (western Marmara Sea) basins during April–July 2000. Little was known about microearthquake activity and their source mechanisms in the Marmara Sea. We have detected numerous microearthquakes within the main basins of the Sea of Marmara along the imaged strands of the North Anatolian Fault (NAF). We obtained more than 350 well-constrained hypocenters and nine composite focal mechanisms during 70 days of observation. Microseismicity mainly occurred along the Main Marmara Fault (MMF) in the Marmara Sea. There are a few events along the Southern Shelf. Seismic activity along the Main Marmara Fault is quite high, and focal depth distribution was shallower than 20 km along the western part of this fault, and shallower than 15 km along its eastern part. From high-resolution relative relocation studies of some of the microearthquake clusters, we suggest that the western Main Marmara Fault is subvertical and the eastern Main Marmara Fault dips to south at 45°. Composite focal mechanisms show a strike-slip regime on the western Main Marmara Fault and complex faulting (strike-slip and normal faulting) on the eastern Main Marmara Fault.     

The effects of possible contamination by sample holders on samples to be returned by Hayabusa2

Chemical compositions of materials used for new sample holders (vertically aligned carbon nanotubes [VACNTs] and polyimide film), which were developed for the analysis of Hayabusa2‐return samples, were determined by instrumental neutron activation analysis and/or instrumental photon activation analysis, to estimate contamination effects from the sample holders. The synthetic quartz plate used for the sample holders was also analyzed. Ten elements (Na, Al, Cr, Mn, Fe, Ni, Eu, W, Au, and Th) and 14 elements (Na, Al, K, Sc, Ti, Cr, Zn, Ga, Br, Sb, La, Eu, Ir, and Au) could be detected in the VACNTs and polyimide film, respectively. The VACNT data show that contamination by this material with respect to the Murchison meteorite is negligible in terms of the elemental ratios (e.g., Fe/Mn, Na/Al, and Mn/Cr) used for the classification of meteorites due to the extremely low density of VACNTs. However, for the Au/Cr ratio, even small degrees (1.7 wt%) of contamination by VACNTs will change the Au/Cr ratio. Elemental ratios used for the classification of meteorites are only influenced by large amounts of contamination (>60 wt%) of polyimide film, which is unlikely to occur. In contrast, detectable effects on Ti isotopic compositions are caused by >0.1 and >0.3 wt% contamination by VACNTs and polyimide film, respectively, and Hf isotopic changes are caused by >0.1 wt% contamination by VACNTs. The new sample holders (VACNTs and polyimide film) are suitable for chemical classification of Hayabusa2‐return samples, because of their ease of use, applicability to multiple analytical instruments, and low contamination levels for most elements.     

Dewatering Behaviour of a Uranium Ore Slurry Containing Clays

The main objective of this paper was to investigate the dewatering behaviour of a clayey uranium ore slurry. The slurry (containing 28% clay size) exhibited moderate water adsorption (w _l  = 83% and w _p  = 30%). Primarily composed of muscovite (46%) and quartz (30%), the clay minerals included illite (8%), chlorite (5%) and kaolinite (2%) alongside a CEC of 41 (cmol(+)/kg) with Ca²⁺ and Mg²⁺ as the dominant cations. Likewise, the high EC (17,600 μS/cm) and ionic strength (1.15 mol/L) indicated a flocculated microstructure due to the presence of SO₄ ^2? (22,600 mg/L) and Mg²⁺ (1340 mg/L) in the slurry water. Settling included sedimentation and consolidation at low initial solids condition (25–35%) whereas only consolidation was observed at high initial solids contents (40–50%). The average k reduced from 1.2 × 10^?6 m/s (initial s = 25%) to 5.3 × 10^?8 m/s (initial s = 50%) along with a void ratio reduction from 7.4 to 2.6. Due to thixotropic strength, volume compressibility during consolidation showed apparent pre-consolidation at low effective stress (0.3–2 kPa) with a reduction in void ratio from 2.6 to 2.5. The e _s was found to be 2.46 at σ′ = 2 kPa and was followed by a steeper slope with the void ratio reducing to 2.1 at σ′ = 31 kPa. Likewise, the hydraulic conductivity during consolidation decreased from 2.6 × 10^?9 m/s (at e = 2.6) to 2.0 × 10^?10 m/s (at e = 2.1).     

Distributions of polycyclic aromatic hydrocarbons and alkylated polycyclic aromatic hydrocarbons in Osaka Bay,Japan

Contaminations in sediments by polycyclic aromatic hydrocarbons (PAHs) and alkylated PAHs were investigated at 44 sites in Osaka Bay, Japan. Concentrations of total PAHs and alkylated PAHs were in the range 6.40–7800 ng/g dry weights and 13.7–1700 ng/g dry weights, respectively. The PAH concentrations tended to be higher along the shoreline in the vicinities of big ports, industrialized areas, and densely populated regions such as the cities of Osaka and Kobe. The major sources appeared to be pyrogenic or both pyrogenic and petrogenic at most of the sites. PAH concentrations were remarkably high at a site near Kobe, where the concentrations of dibenzo(a,h)anthracene and benzo(g,h,i)perylene exceeded the effects-range-medium concentration and eight PAHs were above the corresponding effects-range-low concentrations. Those PAHs may have been derived from the great fire associated with the large earthquake in 1995.     

Crustal structure in and around the region of the 1995 Kobe Earthquake deduced from a wide-angle and refraction seismic exploration

Abstract The 1995 Kobe (Hyogo-ken Nanbu) earthquake (M_JMA 7.2, M_w 6.9) occurred on Jan. 17, 1995, at a depth of 17 km, beneath the areas of southern part of Hyogo prefecture and Awaji Island. To investigate P-wave velocity distribution and seismological characteristics in the aftershock area of this great earthquake, a wide-angle and refraction seismic exploration was carried out by the Research Group for Explosion Seismology (RGES) . The profile including 6 shot points and 205 observations was 135 km in length, extending from Keihoku, Northern Kyoto prefecture, through Kobe, to Seidan on Awaji Island. The charge of each shot was 350–700 kg. The P-wave velocity structure model showed a complicated sedimentary layer which is shallower than 2.5 km, a 2.5 km-thick basement layer whose velocity is 5.5 km/s, overlying the crystalline upper crust, and the boundary between the upper and lower crust.
Almost all aftershock hypocenters were located in the upper crust. However, the structure model suggests that the hypocenters of the main shock and some aftershock clusters were situated deeper than the boundary between the upper and lower crust. We found that the P-velocity in the upper crust beneath the northern part of Awaji Island is 5.64 km/s which is 3% lower than that of the surrounding area. The low-velocity zone coincides with the region where the high stress moment release was observed.     

Frequency-dependent Attenuation of High-frequency P and S Waves in the Upper Crust in Western Nagano, Japan

—Borehole seismograms from local earthquakes in the aftershock region of the 1984 western Nagano Prefecture, Japan earthquake were analyzed to measure the frequency-dependent characteristics of P- and S-wave attenuation in the upper crust. The records from a three-component velocity seismometer at the depth of 145m exhibit high S/N-ratio in a wide frequency range up to 100 Hz. Extended coda normalization methods were applied to bandpass-filtered seismograms of frequencies from 25 to 102 Hz. For the attenuation of high-frequency P and S waves, our measurements show Q _P ^-1? 0.052?^-0.66 and Q _S ^-1? 0.0034?^-0.12 respectively. The frequency dependence of the quality factor of S waves is very weak as compared with that of P waves. The ratio of Q _P ^-1/Q _S ^-1 is larger than unity in the entire analyzed frequency range.     

Transition enthalpies and entropies of high pressure zinc metasilicates and zinc metagermanates

The enthalpies of transition at T= 298 K between zinc metasilicate assemblages, measured by molten oxide solution calorimetry, are:

The partitioning of Pt-Re-Os between solid and liquid metal in the Fe-Ni-S system at high pressure: Implications for inner core fractionation

Coupled ¹⁸⁶Os/¹⁸⁸Os and ¹⁸⁷Os/¹⁸⁸Os enrichments of plume-derived lavas have been suggested to reflect contributions of materials from the outer core (Brandon et al., 1998). This hypothesis is based on the assumption that the Earth’s liquid outer core has high Pt/Os and slightly high Re/Os ratios as a result of the crystallization of the solid inner core, and shows coupled enrichments in the ¹⁸⁶Os/¹⁸⁸Os and ¹⁸⁷Os/¹⁸⁸Os ratios, reflecting the decay of ¹⁹⁰Pt and ¹⁸⁷Re to ¹⁸⁶Os and ¹⁸⁷Os, respectively. Partitioning experiments of Pt-Re-Os between solid and liquid metal were performed at 5-20 GPa and 1250-1400 °C, to examine the effects of pressure in the Fe-Ni-S system. The ratios (D_Os/D_Pt, D_Os/D_Re) of measured partition coefficients of Pt, Re and Os are almost constant with increasing pressure. D_Os/D_Pt increases significantly, whereas D_Os/D_Re decreases, with increasing sulphur content in the liquid metal. On the basis of the present experimental results, it is unlikely that the required Pt-Re-Os fractionation is generated during inner core crystallization, assuming that the light element in the Earth’s core is sulphur.     

The use of microstructures for discriminating turbiditic and hemipelagic muds and mudstones

The microstructures of turbiditic and hemipelagic muds and mudstones were investigated using a scanning electron microscope to determine whether there are microstructural features that can differentiate turbiditic from hemipelagic sedimentary processes. Both types of muddy deposits are, in general, characterized by randomly‐oriented clay particles. However, turbiditic muds and mudstones also characteristically contain aggregates of ‘edge‐to‐face’ contacts between clay particles with long‐axis lengths of up to 30 μm. Based on observations of the clay fabric of the experimentally‐formed muds settled from previously agitated muddy fluids, these types of aggregates, hereafter referred to as ‘aggregates of clay particles’, are interpreted as having been formed by the collision of component flocs in turbulent fluids. Furthermore, some aggregates of clay particles have ‘face‐to‐face’ contacts between clay particles; this is similar to face‐to‐face aggregates characteristically developed in fluid‐mud deposits that are commonly recognized only in turbiditic mudstones, indicating the possibility of a final stage of deposition under highly‐dense conditions, such as temporary fluid muds. In conjunction with earlier proposed lithofacies‐based and ichnofacies‐based criteria, aggregates of clay particles should be useful for the differentiation of turbiditic and hemipelagic muddy deposits, particularly with limited volumes of non‐oriented samples from deep‐water successions.