Interactions between groundwater and surface water in a virginia coastal plain watershed. 1. Hydrological flowpaths

A field study of surface water and groundwater interactions during baseflow and stormflow conditions was performed at the Reedy Creek watershed in the Virginia Coastal Plain. Three estimates of the average saturated hydraulic conductivity (K_s) of the unconfined aquifer were in reasonable agreement (ranging from 0.0033 to 0.010 cm/s), indicating that baseflow in the creek is entirely from the drainage of shallow groundwater from the relatively thin (1–6 m thick) unconfined aquifer. This relatively permeable surficial aquifer was found to be underlain by dark, olive grey, clay-silt and diatomaceous Miocene deposits of low permeability known as the Calvert Formation, which is believed to function as a confining bed in the area. A chemical hydrograph separation technique was used to resolve the contributions of [old] (pre-event) and [new] (event) water to stormflow. Results from a major rainstorm indicated that old water dominated the stormflow response of the watershed, although the new water contribution approached 40% at the hydrograph peak. Stormflow at Reedy Creek appears to result from saturation overland flow from variable source areas which include the stream channels and a significant part of the riparian wetland area. This response appears to be attributable to the transient dynamics of the shallow groundwater flow system and to the formation of localized groundwater mounds which raise the water-table to the wetland surface.     

Prediction of episodic acidification in North‐eastern USA: an empirical/mechanistic approach

Observations from the US Environmental Protection Agency's Episodic Response Project (ERP) in the North‐eastern United States are used to develop an empirical/mechanistic scheme for prediction of the minimum values of acid neutralizing capacity (ANC) during episodes. An acidification episode is defined as a hydrological event during which ANC decreases. The pre‐episode ANC is used to index the antecedent condition, and the stream flow increase reflects how much the relative contributions of sources of waters change during the episode. As much as 92% of the total variation in the minimum ANC in individual catchments can be explained (with levels of explanation >70% for nine of the 13 streams) by a multiple linear regression model that includes pre‐episode ANC and change in discharge as independent variables. The predictive scheme is demonstrated to be regionally robust, with the regional variance explained ranging from 77 to 83%. The scheme is not successful for each ERP stream, and reasons are suggested for the individual failures. The potential for applying the predictive scheme to other watersheds is demonstrated by testing the model with data from the Panola Mountain Research Watershed in the South‐eastern United States, where the variance explained by the model was 74%. The model can also be utilized to assess ‘chemically new’ and ‘chemically old’ water sources during acidification episodes. Copyright © 1999 John Wiley & Sons, Ltd.     

Cobble cam: grain‐size measurements of sand to boulder from digital photographs and autocorrelation analyses

A new application of the autocorrelation grain size analysis technique for mixed to coarse sediment settings has been investigated. Photographs of sand‐ to boulder‐sized sediment along the Elwha River delta beach were taken from approximately 1·2 m above the ground surface, and detailed grain size measurements were made from 32 of these sites for calibration and validation. Digital photographs were found to provide accurate estimates of the long and intermediate axes of the surface sediment (r² > 0·98), but poor estimates of the short axes (r² = 0·68), suggesting that these short axes were naturally oriented in the vertical dimension. The autocorrelation method was successfully applied resulting in total irreducible error of 14% over a range of mean grain sizes of 1 to 200 mm. Compared with reported edge and object‐detection results, it is noted that the autocorrelation method presented here has lower error and can be applied to a much broader range of mean grain sizes without altering the physical set‐up of the camera (～200‐fold versus ～6‐fold). The approach is considerably less sensitive to lighting conditions than object‐detection methods, although autocorrelation estimates do improve when measures are taken to shade sediments from direct sunlight. The effects of wet and dry conditions are also evaluated and discussed. The technique provides an estimate of grain size sorting from the easily calculated autocorrelation standard error, which is correlated with the graphical standard deviation at an r² of 0·69. The technique is transferable to other sites when calibrated with linear corrections based on photo‐based measurements, as shown by excellent grain‐size analysis results (r² = 0·97, irreducible error = 16%) from samples from the mixed grain size beaches of Kachemak Bay, Alaska. Thus, a method has been developed to measure mean grain size and sorting properties of coarse sediments. Copyright © 2009 John Wiley & Sons, Ltd.     

Influence of diurnal cycles on metal concentrations and loads in streams draining abandoned mine lands: an example from High Ore Creek,Montana

Diurnal water samples were collected simultaneously at four locations along High Ore Creek (Montana, USA), a small stream with near-neutral pH that contains elevated concentrations of Zn, Mn, Cd, and As from abandoned mines near its headwaters. During the same time period, two sets of synoptic samples were collected by workers moving in opposite directions along the stream. Large diurnal fluctuations in Zn concentration were found at three of the 24-h monitoring stations, but not at the outlet to a settling pond. Because the concentrations of Zn were dropping at most locations in the creek during the day (in response to the daily cycle of day-time attenuation and night-time release), the synoptic sampler who moved upstream obtained a data set that led to the conclusion that Zn load increased with distance downstream. The sampler who moved in a downstream direction obtained the opposite results. Thus, failure to take short-term diurnal cycling into account can lead to incorrect conclusions regarding spatial or temporal trends in water quality within a watershed.     

Micro-spectroscopic investigation of selenium-bearing minerals from the Western US Phosphate Resource Area

Mining activities in the US Western Phosphate Resource Area (WPRA) have released Se into the environment. Selenium has several different oxidation states and species, each having varying degrees of solubility, reactivity, and bioavailability. In this study we are investigating the speciation of Se in mine-waste rocks. Selenium speciation was determined using bulk and micro-x-ray absorption spectroscopy (XAS), as well as micro-x-ray fluorescence mapping. Rocks used for bulk-XAS were ground into fine powders. Shale used for micro-XAS was broken along depositional planes to expose unweathered surfaces. The near edge region of the XAS spectra (XANES) for the bulk rock samples revealed multiple oxidation states, with peaks indicative of Se(-II), Se(IV), and Se(+VI) species. Micro-XANES analysis of the shale indicated that three unique Se-bearing species were present. Using the XANES data together with ab initio fitting of the extended x-ray absorption fine structure region of the micro-XAS data (micro-EXAFS) the three Se-bearing species were identified as dzharkenite, a di-selenide carbon compound, and Se-substituted pyrite. Results from this research will allow for a better understanding of the biogeochemical cycling of Se in the WPRA.     

Sulfur dioxide and other cloud-related gases as the source of the microwave opacity of the middle atmosphere of Venus

Spacecraft radio occultation measurements imply the presence of a nonuniformly mixed gaseous absorber within, but mostly below, the main cloud layer of sulfuric acid—water droplets measured by Pioneer-Venus. Preliminary considerations of the amount, distribution, and effects of sulfur dioxide and other gases, which apparently are associated with and produce the cloud, indicate that they constitute an important, and probably the predominant, source of the observed microwave opacity of the middle atmosphere of Venus.     

W-shaped occultation signatures: Inference of entwined particle orbits in charged planetary ringlets

Observed W-shaped occultation signatures of certain narrow ringlets in the ring systems of Saturn and Uranus imply a concentration of material near their inner and outer radial edges. A model is proposed where edge bunching is a natural consequence of particles in entwined elliptical orbits, with the same particles alternately defining both edges. While such orbits cross over in radius, collisions would not occur if they have small inclinations, the same fixed argument of periapse ω, and other parameters whereby the particles would “fly in formation” along compressed helical paths relative to the core of the ringlet, which is taken to be a circle in the equatorial plane. For this model to match the observed ring thickness and ringlet widths, orbit inclinations i must be much smaller than their eccentricities e, which themselves would be very small compared to unity. Thus, the meridional cross section of the resultant torus would be a very thin ellipse of thickness proportional to i∣cos ω∣, tilted slightly from the equatorial plane by (i/e)∣sin ω∣ radians. However, gravitational perturbations due to the oblateness of the planet would cause a secular change in ω so that this cross section would collapse periodically to a tilted line, and collisions would then occur. If this collapse could be prevented, the torus could remain in a continuous state of nearly zero viscosity. Stabilization against collapse appears possible due to several remarkable characteristics that are added to the model when the particles are electrically charged. First, because of inherent features of the torus structure, a weak electric force could counter the key effect of the vastly larger oblateness force. Second, because the electric perturbation also affects i, there is a large region in ω,i space where stability against cross-sectional collapse is automatic. For this region, the thickness of the elliptical cross section would expand and contract in concert with the way that the major axis of the ellipse rocks back and forth relative to the equatorial plane. The period of these “rocking and breathing” changes would be from 1 to 3 weeks for a torus in the C ring of Saturn, for example. The electric effects could change considerably without driving the parameters of the torus from the stable domain where cross-sectional collapse does not occur. While specialized and in several important ways still incomplete, the proposed model could account for the W-shaped patterns and explain how very dense ringlets might endure without energy loss due to collisions. It also appears to be capable of explaining the observed sorting of particles by size within a ringlet. Several characteristics of the model suggest definitive tests of its applicability, including its prediction that a nonsymmetrical W-shaped occultation signature could be reversed a half orbit away, and that grazing solar illumination of tilted ringlets might cast shadows that change with time in a prescribed way.     

Particle size distributions in Saturn's rings from voyager 1 radio occultation

Observations of microwave opacity τ[λ] and near forward scatter from Saturn's rings at wavelengths λ of 3.6 and 13 cm from the Voyager 1 ring occultation experiment contain information regarding ring particle sizes in the range of about a = 0.01 to 15 m radius. The opacity measurements τ[3.6] and τ[13] are sufficient to constrain the scale factor n(a₀) and index q of a power law incremental size distribution n(a) = n(a₀)[a₀/a]^q, assuming known minimum and maximum sizes and a many-particle-thick model. The families of such distributions are highly convergent in the centimeter-size range. Forward scatter at 3.6 cm can be used to solve for a general distribution over the radius range $\text{1 ? a ? 15}\text{m}$ by integral inversion and inverse scattering methods, again assuming a many-particle-thick slab-type radiative transfer model. Distributions n(a) valid over $\text{0.01 ? a ? 15}\text{m}$ are obtained by combining the results from the two types of measurements above. Mass distributions may be computed directly from n(a). Such distributions, partly measured and partly synthesized, have been obtained for four features in the ring system centered at 1.35, 1.51, 2.01, and 2.12 Saturn radii (R_s). The size and mass distributions both cut off sharply at a ? 4–5 m; the mass distribution peaks over the narrow size range $\text{3 ? a ? 4}\text{m}$ for all four locations. No single power law distribution is consistent with the data over the entire interval $\text{0.01 ? a ? 5}\text{m}$, although a power law-type model is consistent with the data over a limited size range of $\text{0.01 ? a ? 1}\text{m}$, where the indices q = 3.4 and 3.3 are obtained from the slab model for the features located at 1.51 and 2.01 R_s. The fractional contribution of the suprameter particles to the microwave opacity in each feature appears to be about $\text{1}\text{3}\text{,}\text{1}\text{3}\text{,}\text{2}\text{3}\text{,}\text{and}\text{1}$, respectively, with the fraction at 2.12 R_s being the least certain. The cumulative surface mass per unit area obtained for the classical slab model is approximately 11, 16, 41, and 132 g/cm² for the four features, respectively, if the particles are solid H₂O ice. Both the fractional opacity and the mass density estimates represent upper bounds implied by the assumption of a uniformly mixed set of particles in a many-particle-thick vertical profile; lower estimates would result if the rings were assumed to be nearly a monolayer or if the vertical distribution of particles were size dependent.     

The radio occultation method for the study of planetary atmospheres

Planets, the Moon and the Sun have a number of ‘atmospheres’ which may be measured by the radio occultation method, using radio links to spacecraft which are being occulted by the body as seen from Earth. Molecular atmospheres, ionospheres, magnetospheres, particulate atmospheres and several general-relativistic atmospheres can all affect radio signal charecteristics. Measured Doppler frequencies, signal amplitudes and wave polarizations contain information on these atmospheres. From such occultation measurements it is possible, for example, to derive profiles which are related to the changes with height of temperature, pressure, density, free electron concentration and the fractional volume occupied by particulate matter. Important clues for identifying molecular or particulate constituents can also be obtained. Even though one type of measurement may be sensitive to several different atmospheric characteristics, these characteristics can often be separated due to differences in their dependence on radio wavelength or on height above the surface.