Experimental studies on the phase systems Fe-Ni-Pd-S and Fe-Pt-Pd-As-S applied to PGE deposits

Summary In the present paper current results of experimental investigation of the phase system Pd-Fe-Ni-S at 900°C, 725°C, 550°C and 400°C as well as of the phase system Pt-Fe-As-S at 850°C and 470°C are summarized. A preliminary note on the system Pt-Pd-As-S is added. Individual phase assemblages are presented, data on solubility of PGE in base metal sulphides/arsenides or alloys are given and solid solution ranges of important minerals are described as a function of temperature and phase assemblage. The extent and role of sulphide/arsenide melts in these systems are presented together with hints for, and examples of the application of the current experimental results for the explanation of ore-geological processes.

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Bisherige Ergebnisse experimenteller Untersuchungen in den Systemen Fe-Ni-Pd-S und Fe-Pt-Pd-As-S und ihre Bedeutung für Lagerstätten der Platin-Gruppen-Elemente

Zusammenfassung In der vorliegenden Arbeit werden bisherige Ergebnisse experimenteller Untersuchungen in den Phasensystemen Pd-Fe-Ni-S bei 900°C, 725°C, 550°C sowie 400°C, bzw. Pt-Fe-As-S bei 850°C und 470°C zusammengefasst. Vorläufige Anmerkungen zum System Pt-Pd-As-S werden gegeben. Die Phasenbeziehungen und die Löslichkeitsdaten von PGE's in Buntmetall-Sulfiden/Arseniden sowie deren Verbindungen werden präsentiert. Die Mischungsbereiche der wichtigsten Minerale werden als Funktion von Temperatur und Phasenvergesellschaftung diskutiert. Die Rolle von Sulfid/Arsenid Schmelzen in diesen Systemen und Beispiele für die Anwendung dieser experimentellen Ergebnisse zur Erklärung lagerstättenkundlicher Prozesse werden beschrieben.

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With 6 Figures     

Influencing domain of peripheral sources in the urban heavy pollution process of Beijing

Multiple cities in a diveloped economic area may consist of a city cluster,and the difusion and mixing of its pollutants result in the effect of pollutants plume between cities and the large-scale regional pollution diffusion phenomenon.The distant transfer and diffusion of pollutants occurs when massive aerosols are affected by the dynamic porcess of large-scale circulations.Research suggesten that the life span of aerosol particles whose diameters are about 1 um is the longest.The longevity …     

Water masses in the Caribbean Sea and sub-annual variability in the Guajira upwelling region

The study of water masses is important as they transport water properties affecting the biosphere and ocean dynamics. In this study, we revisit water masses in the Caribbean Sea using climatology and 11 months of observations at different depths from 3 moorings placed in the Guajira upwelling region, providing some new findings. The Caribbean Surface Water (CSW) seasonal variability is studied at the mixed layer depth. Salinity differences between CSW and the saltier North Atlantic Subtropical Underwater (SUW) determine static stability spatial and temporal variations, with implications for regional ocean dynamics. Besides, we assess the climatologic distribution of water masses below the salinity maximum using the optimum multiparameter analysis and the Thermodynamic Equation of Seawater 2010, defining their source water indices when entering the Caribbean Sea. The SUW, with its core at ~ 150 m depth, occupies 16% of the Caribbean Sea volume, complemented by 38% of Antarctic Intermediate Water, with its core at ~ 700 m depth and North Atlantic Deep Water, which as bottom water occupies 46% of the volume. Hydrographic observations do not differ from climatology, regardless of their large sub-annual variations decreasing with depth. Daily time series of dominant water fractions at different depths correlate at each mooring, indicating a common forcing. Besides, rotated wind stress, which is an indicator of the Guajira upwelling, correlates regularly with water mass fractions down to 700 m depth. However, during strong wind shifts, upwelling seems to affect them down to 1450 m depth.

     

On the origin of microrhythmic layering in arfvedsonite lujavrite from the Ilímaussaq alkaline complex, South Greenland

Microrhythmic layering is locally developed in agpaitic arfvedsonite lujavrite from the Ilímaussaq alkaline complex, South Greenland. Three–15-cm-thick laminated dark layers alternate with 1–10-cm-thick, light-coloured granular urtitic layers. Dark layers are uniform (isomodal) but the urtitic layers are enriched in early nepheline and eudialyte in their lower parts and in late analcime and REE phosphate minerals in the upper parts. The layers are separated by sharp contacts; they are draped around rafts from the overlying roof zone and lack structures indicative of current processes or post-cumulus deformation. Compared with the background arfvedsonite lujavrite of the complex, the dark layers are richer in sodalite, microcline and arfvedsonite and poorer in analcime and eudialyte. They have higher K₂O, Cl, FeO and S but lower Na₂O, H₂O⁺, Zr and P contents, the opposite of the light-coloured layers. The complementary chemistry of the two types of layers oscillates about the composition of the background arfvedsonite lujavrite. Layers probably formed in a stagnant bottom layer of the lujavrite magma chamber. Each layer started as a liquid layer which exchanged components with the underlying crystallization front. On cooling, it crystallized primocrysts and exchanged components with the overlying magma which became a new, complementary liquid layer and, during further cooling and burial within the sequence of layers, it underwent largely closed-system interstitial crystallization. Exhaustion of Cl and a sharp decrease in a_NaCl relative to a_H2O terminated the crystallization of a sodalite-rich dark layer and initiated abundant crystallization of nepheline in the overlying liquid layer (urtitic layer). The layered sequence represents a local K₂O-, Cl-rich but Na₂O-, H₂O-poor facies of arfvedsonite lujavrite and may have formed by exchanging components with sodalite-bearing rafts from the roof zone.     

Determination of [Fe2+]/[Fe3+]-ratios in arfvedsonite by Mössbauer spectroscopy

The Mössbauer absorption spectra of arfvedsonite are composed of three quadrupole doublets which are ascribed to Fe²⁺ in M₁ and M₂ sites and to Fe³⁺ in M₂ sites. The relative intensities of the resonances are a measure of the distribution of iron at the different sites, but it is necessary to correct for a difference between the recoil-free fractions. At room temperature [Fe²⁺] seems detected with an efficiency of only about 85% of that of [Fe³⁺]. Results of [Fe²⁺]/[Fe³⁺] determinations by Mössbauer spectroscopy and by wet chemical analysis of a series of arfvedsonite samples, separated from various rocks from the Ilimaussaq intrusion, south Greenland, are compared and agree reasonably well.