The magnetic susceptibility record in the Polish and western Ukrainian loess-palaeosol sequences conditioned by palaeoclimate

The magnetic susceptibility of loess-palaeosol sequences in southern Poland and western Ukraine varies mainly with the degree of decomposition of detrital magnetite grains conditioned by palaeoclimate. Relatively high susceptibility values were observed in the unweathered loess horizons and in accumulation horizons of the non-gleyed soils which contain relatively high amounts of paramagnetic fraction and pedogenic (?) magnetite. The susceptibility curves characteristic for Polish and western Ukrainian loess-palaeosol sequences may be directly correlated with oxygen-isotope fluctuations in deep-sea sediments. This correlation is more complex than that for the Chinese or Alaskan loess-palaeosol sequences. The major causes of the complexities are the relatively small thicknesses of the investigated sections (especially their older horizons) and the heterogeneity of geochemical processes that affected loess surface in the interglacial and interstadial times.     

Modelling the hydrological response of mediterranean catchments,Prades, Catalonia. The use of distributed models as aids to hypothesis formulation

This paper attempts to extend the physical arguments underlying the distributed TOPMODEL concepts in an application to the strongly seasonal contributing area responses in two adjacent small mediterranean catchments in the Prades region of Catalonia, Spain. A perceptual model of hydrological response in these catchments is used to suggest possible modifications of the model in a hypothesis testing framework, including an attempt to modify the topographic index approach to reflect the expansion of the effective area of subsurface flow during the wetting-up sequence. It is found that slight improvements in modelling efficiency are possible but that different model parameter distributions are appropriate for different parts of the record. The model was much more successful for the catchment producing the higher runoff volumes. © 1997 John Wiley & Sons, Ltd.     

Extremal climatic states simulated by a 2‐dimensional model

Different climatic simulations have been obtained by using a 2‐Dim horizontal energy balance model (EBM), which has been constrained to satisfy several extremal principles on dissipation and convection. Moreover, 2 different versions of the model with fixed and variable cloud‐cover have been used. The assumption of an extremal type of behaviour for the climatic system can acquire additional support depending on the similarities found with measured data for past conditions as well as with usual projections for possible future scenarios.     

Meganodular anhydritization: a new mechanism of gypsum to anhydrite conversion (Palaeogene–Neogene,Ebro Basin,North‐east Spain)

A number of Palaeogene to Early Neogene gypsum units are located along the southern margins of the Ebro Basin (North‐east Spain). These marginal units, of Eocene to Lower Miocene age, formed and accumulated deposits of Ca sulphates (gypsum and anhydrite) in small, shallow saline lakes of low ionic concentration. The lakes were fed mainly by ground water from deep regional aquifers whose recharge areas were located in the mountain chains bounding the basin, and these aquifers recycled and delivered Ca sulphate and Na chloride from Mesozoic evaporites (Triassic and Lower Jurassic). In outcrop, the marginal sulphate units are largely secondary gypsum after anhydrite and exhibit meganodules (from 0·5 to >5 m across) and large irregular masses. In the sub‐surface these meganodules and masses are mostly made of anhydrite, which replaced the original primary gypsum. The isotopic composition (11·1 to 17·4‰ for δ¹⁸O_VSMOW; 10·7 to 15·3‰ for δ³⁴S_VCDT) of secondary gypsum in this meganodular facies indicates that the precursor anhydrite derived from in situ replacement of an initial primary gypsum. As a result of ascending circulation of deep regional fluid flows through the gypsum units near the basin margins, the gypsum was partly altered to anhydrite within burial conditions from shallow to moderate depths (from some metres to a few hundred metres?). At such depths, the temperatures and solute contents of these regional flows exceeded those of the ground water today. These palaeoflows became anhydritizing solutions and partly altered the subsiding gypsum units before they became totally transformed by deep burial anhydritization. The characteristics of the meganodular anhydritization (for example, size and geometry of the meganodules and irregular masses, spatial arrangement, relations with the associated lithologies and the depositional cycles, presence of an enterolithic vein complex and palaeogeographic distribution) are compared with those of the anhydritization generated both in a sabkha setting or under deep burial conditions, and a number of fundamental differences are highlighted.     

Glauberite–halite association of the Zaragoza Gypsum Formation (Lower Miocene, Ebro Basin, NE Spain)

Glauberite is the most common mineral in the ancient sodium sulphate deposits in the Mediterranean region, although its origin, primary or diagenetic, continues to be a matter of debate. A number of glauberite deposits of Oligocene–Miocene age in Spain display facies characteristics of sedimentologic significance, in particular those in which a glauberite–halite association is predominant. In this context, a log study of four boreholes in the Zaragoza Gypsum Formation (Lower Miocene, Ebro Basin, NE Spain) was carried out. Two glauberite–halite lithofacies associations, A and B, are distinguished: association (A) is composed of bedded cloudy halite and minor amounts of massive and clastic glauberite; association (B) is made up of laminated to thin‐bedded, clear macrocrystalline, massive, clastic and contorted lithofacies of glauberite, and small amounts of bedded cloudy halite. Transparent glauberite cemented by clear halite as well as normal‐graded and reverse‐graded glauberite textures are common. This type of transparent glauberite is interpreted as a primary, subaqueous precipitate. Gypsum, thenardite or mirabilite are absent in the two associations. The depositional environment is interpreted as a shallow perennial saline lake system, in which chloride brines (association A) and sulphate–(chloride) brines (association B) are developed. The geochemical study of halite crystals (bromine contents and fluid inclusion compositions) demonstrates that conditions for co‐precipitation of halite and glauberite, or for precipitation of Na‐sulphates (mirabilite, thenardite) were never fulfilled in the saline lake system.     

LAKE-ICE BLISTERS, TERRA NOVA BAY AREA, NORTHERN VICTORIA LAND, ANTARCTICA

Ice blisters, typically 0.2–0.8 m high and 5–20 m long, develop annually on perennially frozen lakes in Northern Victoria Land. They are believed to be caused by hydrostatic pressures generated through progressive freezing of solute-rich water beneath the lake-ice cover during winter. Lake-ice blisters in the study area differfrom icing blisters described from the northern hemisphere. The latter are caused by hydraulic pressures and are found at locations such as river beds or spring sites on sloping terrain. The Antarctic lake-ice blisters reflect the occurrence of dry-based perennially frozen lakes with high salt contents in an extremely cold and arid environment.     

EVIDENCES FROM HISTORICAL DOCUMENTS OF LANDSCAPE EVOLUTION AFTER LITTLE ICE AGE OF A MEDITERRANEAN HIGH MOUNTAIN AREA,SIERRA NEVADA,SPAIN (EIGHTEENTH TO TWENTIETH CENTURIES)

The Sierra Nevada is the highest mountain system on the Iberian Peninsula (Mulhacén 3482 m; Veleta 3308 m) and is located in the extreme SE region of Spain (lat 37°N, long 3°W). Bibliographic resources, particularly from the eighteenth to twentieth centuries, provide insights into the changing summit landscape as the effects of cold, ice, snow and wind shaped its morphology. The selected references emphasize the Sierra's evolving climate reflected in the glaciers and snow hollows, and in the sparse vegetation above certain altitudes. Scientists had established bioclimatic conditions for the entire range in the early nineteenth century, and their works reflect the progression of ideas, particularly in the area of natural sciences, that influenced the period chosen for this study. This information, in addition to current knowledge about the morphogenetic dynamics of the Sierra Nevada, provides the basis for a comparison of the dominant environments from the Little Ice Age to the present, using the most significant high mountain morphological features as a guide. The most relevant findings indicate that cold climate processes (soli‐gelifluction, frost creep and nivation) were more predominant during the eighteenth and nineteenth centuries than they are today.