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CHRIS W. LEE 《Geology Today》1991,7(4):133-136
Each year many hundreds, if not thousands, of Earth-science students visit the coastline at Ogmore-by-Sea, mid-Glamorgan. They study the excellent exposures of Lower Carboniferous Limestone, with their well-preserved coral and other shelly faunas, together with the presumed late Triassic 'breccias'* that rest unconformably on top. A study of the cements within the breccias may give an insight into syndepositional mineralization and the formation of sedimentary basins linked to the opening of the Atlantic in early Mesozoic times. 相似文献
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Oil-weathering processes in ice-free subarctic and Arctic waters include spreading, evaporation, dissolution, dispersion of whole-oil droplets into the water column, photochemical oxidation, water-in-oil emulsification, microbial degradation, adsorption onto suspended particulate material, ingestion by organisms, sinking, and sedimentation. While many of these processes also are important factors in ice-covered waters, the various forms of sea ice (depending on the active state of ice growth, extent of coverage and/or decay) impart drastic, if not controlling, changes to the rates and relative importance of different oil-weathering mechanisms. Flow-through seawater wave-tank experiments in a cold room at −35°C and studies in the Chukchi Sea in late winter provide data on oil fate and effects for a variety of potential oil spill scenarios in the Arctic. Time-series chemical weathering data are presented for Prudhoe Bay crude oil released under and encapsulated in growing first-year columnar ice through spring breakup. 相似文献
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Geochemistry and Intrusive History of the Ashland Pluton, Klamath Mountains, California and Oregon 总被引:3,自引:1,他引:2
GRIBBLE ROBERT F.; BARNES CALVIN G.; DONATO MARY M.; HOOVER JAMES D.; KISTLER RONALD W. 《Journal of Petrology》1990,31(4):883-923
The Ashland pluton is a calc-alkaline plutonic complex thatintruded the western Paleozoic and Triassic belt of the KlamathMountains in late Middle Jurassic time. The pluton comprisesa series of compositionally distinct magma pulses. The oldestrocks are hornblende gabbro and two-pyroxene quartz gabbro withinitial 87Sr/86Sr = 0{dot}7044, 18O = 8{dot}7%, and REE patternswith chondrite normalized La/Lu = 7. These units were followedby a suite of tonalitic rocks (LaN/LuN = 7) and then by a suiteof K2O- and P2O5 rocks of quartz monzodioritic affinity (LaN/LuN= 1321; LaN/SmN = 2{dot}43{dot}) The quartz monzodioriticrocks were then intruded by biotite granodiorite and granitewith lower REE abundances but more fractionated LREE(LaN/LuN= 1319; LaN/SmN = 4{dot}36 and they, in turn,were host to dikes and bosses of hornblende diorite. The latestintrusive activity consisted of aplitic and granitic dikes.Combined phase equilibria and mineral composition data, indicateemplacement conditions of approximately Ptotal = 2{dot}3kb,PH2O between 1{dot}5 and 2{dot}2 kb, and fO2 between the nickel-nickeloxide and hematite-magnetite buffers. Successive pulses of magma display increasing SiO2 togetherwith increasing 18O and decreasing initial 87Sr/86Sr. The isotopicdata are consistent with either (1) combined fractional crystallizationof andesitic magma and concurrent assimilation of crustal materialcharacterized by low Sr1 and high (18O or, more probably, (2)a series of partial melting events in which sources were successivelyless radiogenic but richer in 18O Each intrusive stage displaysevidence for some degree of crystal accumulation and/or fractionalcrystallization but neither process adequately accounts fortheir compositional differences. Consequently, each stage appearsto represent a distinct partial melting or assimilation event. The P2O5-rich nature of the quartz monzodiorite suite suggestsaccumulation of apatite. However, the suite contains abundantmafic microgranitoid enclaves and most apatite in the suiteis acicular. These observations suggest that magma mixing affectedthe compositional variation of the quartz monzodiorite suite.Mass balance calculations are consistent with a simple mixingprocess in which P2O5-rich alkalic basalt magma (representedby the mafic microgranitoid enclaves) was combined with a crystal-poorfelsic magma (represented by the tonalite suite), yielding aquartz monzodioritic magma that then underwent differentiationby crystal fractionation and accumulation. 相似文献
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The complex pattern of biological accretion, internal sedimentation, early lithification, and biological destruction, that characterizes modern reefs and many fossil reefs has been recognized in archaeocyathid-rich patch reefs of Lower Cambrian age in the Forteau Formation, southern Labrador. Patch reefs occur as isolated masses or complex associations of many discrete masses of archaeocyathid-rich limestone and skeletal lime sands, surrounded by well-bedded skeletal limestones and shales. Each reef is composed of many loafshaped mounds stacked on top of one another. The limestone of each mound comprises archaeocyathids and Renalcis or Renalcis-like structures in a matrix of argillaceous lime mud rich in sponge spicules, trilobite and salterellid skeletons. Numerous growth cavities roofed by pendant Renalcis-like organisms and Renalcis are partially to completely filled with geopetal sediment indicating that much of the matrix was deposited as internal sediment. Two stages of diagenetic alteration are recognized: (1) syn-depositional, which affected only the reefs, and (2) post-depositional, which affected both reefs and inter-reef sediments. On the sea floor reef sediments were pervasively cemented and fibrous carbonate was precipitated in intraskeletal and growth cavities. These limestones and cements as well as archaeocyathid skeletons, were subsequently bored by endolithic organisms. Later post-depositional subaerial diagenesis resulted first in dissolution of certain skeletons and precipitation of calcite cement above the water table, followed by extensive precipitation of pore-filling calcite below the water table. These carbonate reefs are similar in structure to the basal pioneer accumulations of much younger lower and middle Palaeozoic reefs. They did not develop into massive ‘ecologic’ reefs because archaeocyathids never developed the necessary large, massive, hemispherical skeletons. This occurrence indicates that reefs developed more or less coincident with, and not long after, the appearance of skeletal metazoans in the Lower Cambrian. 相似文献
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Molar tooth (MT) structures are enigmatic, contorted millimetre‐ to decimetre‐long veins and spheroids of microcrystalline calcite that formed during very early diagenesis in Precambrian sediments. MT structures in the ca 2·6 Ga Monteville Formation are 600–800 Myr older than previously reported occurrences and establish that conditions necessary for MT genesis were met locally throughout much of the Precambrian. In the Monteville Formation, MT structures were formed shallow subtidally, extending to depths near storm wave base, in shale host sediments intercalated with storm‐generated carbonate sand lenses. They are filled with microcrystalline calcite and rare pyrite. Microcrystalline calcite identical to that in MT structures fills other pore space, including porosity between grains in carbonate sand lenses, moldic porosity in sand grains, sheet cracks in columnar stromatolites, and shallow cracks on sandy bedding planes. Relationships in the Monteville Formation demonstrate that microcrystalline CaCO3 precipitated in fluid‐filled cracks and pores; microcrystalline calcite characteristics, as well as the paucity of carbonate mud in host rocks, are inconsistent with injection of lime mud as the origin of MT structures. Locally, MT cracks were filled by detrital sediment before or during precipitation. Precipitation occurred in stages, and MT CaCO3 evolved from granular cores to a rigid mass of cores with overgrowths – allowing both plastic and brittle deformation of MT structures, as well as reworking of eroded MT structures as rigid clasts and lime mud. Crystal size distributions and morphology suggest that cores precipitated through nucleation, Ostwald ripening and size‐dependent crystal growth, whereas overgrowths formed during size‐independent crystal growth. 相似文献
9.
Capture of Helium and Other Volatiles during the Growth of Olivine Phenocrysts in Picritic Basalts from the Juan Fernandez Islands 总被引:1,自引:0,他引:1
Olivine crystals in basalt contain helium that can be extractedfor isotopic analysis. Helium-bearing olivine phenocrysts inpicritic tholeiites from the Juan Fernandez Islands, SE Pacific,crystallized from moderately differentiated liquids. None arexenocrysts of mantle peridotite. The helium occurs in cavitiesor bubbles in inclusions best seen at high magnification inthe olivine. The olivine grew around spinel, sulfide, and bubblesthat preferentially nucleated on crystal surfaces. Inclusionswithin these phases range from large cavities to tiny, facetedpits arranged in rows. Many crystals contain curving trainsof inclusions along annealed features. The inclusions formedduring mixing between cooler differentiated magma and hotterolivine-charged magma, which accelerated vesiculation. Bubblesnucleated on the olivine as they do on ice when stirred in carbonatedwater. Mixing also induced thermal stress fracturing, like thecracking of ice dropped into water. Cracking, irregular extinction,and subgrain formation occurred when faceted crystals collidedwith each other or with conduit walls. Boundary layer meltsand bubbles were drawn quickly into the fractures. Thus fewinclusions contain equilibrium proportions of minerals and vapor.Mantle-derived helium clearly permeated into shallow storagereservoirs, including rift zones where magmatic differentiation,mixing, and vapor exsolution were fairly extensive. KEY WORDS: Juan Fernandez; volatiles; inclusions; olivine; picrite 相似文献
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Phase Petrology and Mineral Chemistry of Coexisting Amphiboles from Telemark, Norway 总被引:1,自引:1,他引:1
Electron microprobe analyses of coexisting amphiboles, garnet,and cordierite in specimens collected from a single outcropprovide the basis for phase diagrams thought to be representativeof fixed external conditions in the sillimanite zone. A projectionthrough the compositions of quartz and plagioclase is employedto characterize the mineral facies and to facilitate comparisonswith other metamorphic terrains. Limiting recalculations whichbracket the possible range of Fe+3 contents in calcic amphiboleanalyses by electron probe permit an additional projection throughthe composition of magnetite, a ubiquitous phase. From thesedata the apparent non-ideality exhibited by various combinationsof coexisting cumming-tonite, anthophyllite, gedrite, and calcicamphibole is explained by intracrystalline cation ordering. 相似文献