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Keller P. Nicolini Katia C. Lombardi Wido H. Schreiner Irineu Mazzaro Fernando Wypych Antonio S. Mangrich 《Mineralogy and Petrology》2009,97(1-2):139-144
We report on a paramagnetic anisotropy study of three layered phyllosilicates. The mineral samples were characterized through X-ray powder diffraction (XRPD), X-ray photoelectron spectroscopy (XPS) and electron paramagnetic resonance (EPR). Based on EPR measurements of samples oriented parallel or perpendicular to the magnetic field lines, we show how the substitutional iron is transformed from Fe(II) (biotite) into Fe(III) (muscovite and kaolinite) species and from axial Fe(III) coordination sites (muscovite) to rhombic (kaolinite) sites in response to weathering. 相似文献
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