Effects of pulp bleach plant effluents on hepatic xenobiotic biotransformation enzymes in fish: Laboratory and field studies

The present preliminary report on studies of the influence of pulp bleach plant effluents on hepatic biotransformation enzymes in fish is a part of a major characterisation of biochemical and physiological effects of effluents from pulp industries in Sweden. Our studies on the xenobiotic biotransformation enzymes demonstrate, so far, that the pulp effluents have the potential to strongly induce 7-ethoxyresorufin-O-deethylase activity (EROD) in fish liver and that fish living in the receiving water of an effluent from a pulp bleach plant have induced hepatic EROD activities as well as higher hepatic UDP glucuronyltransferase activities than those living in an unpolluted area. It is thus apparent that measures of induction of biotransformation enzymes in fish liver may be a useful approach in monitoring the presence of potential hazardous compounds released from pulp industries.     

Ionic medium effects in sea water — A comparison of acidity constants of carbonic acid and boric acid in sodium chloride and synthetic sea water

It is shown that the values of pK_1C and pK_2C for carbonic acid, pK_B for boric acid and the ionic product of water, pK_w, in sea water may be explained on the basis of their determination in 0.7 M_w sodium chloride and the formation of the following ion-pairs: NaSO₄^?, MgSO₄, CaSO₄, MgCO₃, CaCO₃, MgHCO₃⁺, CaHCO₃⁺, MgOH⁺, HSO₄^?, MgB(OH)₄⁺ and CaB(OH)₄⁺. On the whole the calculated stability constants are lower than those given by Garrels and Thompson (1962).     

International and national climate policies for aviation: a review

Aviation constitutes about 2.5% of all energy-related CO₂ emissions and in addition there are non-CO₂ effects. In 2016, the ICAO decided to implement a Carbon Offsetting and Reduction Scheme for International Aviation (CORSIA) and in 2017 the EU decided on faster emission reductions in its Emissions Trading System (EU ETS), which since 2012 includes the aviation sector. The effects of these policies on the expected development of air travel emissions from 2017 to 2030 have been analyzed. For the sample country Sweden, the analysis shows that when emissions reductions in other sectors are attributed to the aviation sector as a result of the EU ETS and CORSIA, carbon emissions are expected to reduce by ?0.8% per year (however if non-CO₂ emissions are included in the analysis, then emissions will increase). This is much less than what is needed to achieve the 2°C target. Our analysis of potential national aviation policy instruments shows that there are legally feasible options that could mitigate emissions in addition to the EU ETS and CORSIA. Distance-based air passenger taxes are common among EU Member States and through increased ticket prices these taxes can reduce demand for air travel and thus reduce emissions. Tax on jet fuel is an option for domestic aviation and for international aviation if bilateral agreements are concluded. A quota obligation for biofuels is a third option.

Key policy insights

• Existing international climate policies for aviation will not deliver any major emission reductions.

• Policymakers who want to significantly push the aviation sector to contribute to meeting the 2°C target need to work towards putting in place tougher international policy instruments in the long term, and simultaneously implement temporary national policy instruments in the near-term.

• Distance-based air passenger taxes, carbon taxes on jet fuel and quota obligations for biofuels are available national policy options; if they are gradually increased, and harmonized with other countries, they can help to significantly reduce emissions.

     

The aperiodic broad-band X-ray variability of Cygnus X-3

We study the soft X-ray variability of Cygnus X-3. By combining data from the All-Sky Monitor and Proportional Counter Array instruments on the RXTE satellite with EXOSAT /Medium Energy (ME) detector observations, we are able to analyse the power density spectrum (PDS) of the source from 10⁻⁹ to 0.1 Hz, thus covering time-scales from seconds to years. As the data on the longer time-scales are unevenly sampled, we combine traditional power spectral techniques with simulations to analyse the variability in this range. The PDS at higher frequencies  (≳10⁻³ Hz)  are for the first time compared for all states of this source. We find that it is for all states well described by a power law, with index  ∼−2  in the soft states and a tendency for a less steep power law in the hard state. At longer time-scales, we study the effect of the state transitions on the PDS, and find that the variability below  ∼10⁻⁷ Hz  is dominated by the transitions. Furthermore, we find no correlation between the length of a high/soft-state episode and the time since the previous high/soft state. On intermediate time-scales, we find evidence for a break in the PDS at time-scales of the order of the orbital period. This may be interpreted as evidence for the existence of a tidal resonance in the accretion disc around the compact object, and constraining the mass ratio to   M ₂/ M ₁≲ 0.3  .     

The POC / Th ratio of settling particles isolated using split flow-thin cell fractionation (SPLITT)

The common assumption that the ratio between particulate organic carbon (POC) and particulate ²³⁴Th obtained from shallow sediment traps and filterable particles are representative of the ratio in the total particle settling flux should be treated with caution in view of well-known biases associated with tethered shallow sediment traps and the decoupling between size and settling velocity of many natural particle regimes. To make progress toward reliably constraining the POC / ²³⁴Th ratio on truly settling particles, we have tested here a settling collection technique designed to remove any hydrodynamic bias; split flow-thin cell fractionation (SPLITT). These first results from a North Sea fjord and an open Baltic Sea time-series station indicates that the POC / ²³⁴Th ratio on the more complete particle-settling spectrum, isolated with SPLITT, was higher than the POC / ²³⁴Th ratio obtained simultaneously from tethered shallow sediment traps in seven out of seven parallel deployments with an average factor of 210%. The POC / ²³⁴Th ratio from the SPLITT was either in the same range or higher than that obtained on filtered “bulk” particles. To explain this novel data we hypothesize that the slowest settling fraction is organic-matter rich and does not strongly complex ²³⁴Th (i.e., high POC / ²³⁴Th). We suggest that this ultra-slow sinking fraction is better collected by SPLITT than with tethered sediment traps because of minimized hydrodynamic bias.This was tested using the ratio of POC / Al as a tracer of detrital mineral-ballast influenced settling velocity. The higher POC / Al ratios in SPLITT samples relative to in traps is consistent with the hypothesis that SPLITT is better suited for collecting also the slow-settling component of sinking particles. This important slow-settling component appears to here consist primarily of non-APS/TEP components of plankton exudates or other less-strongly ²³⁴Th-complexing organic matter. Further applications of the SPLITT technique are likely to return increasingly new insights on the composition (including “truly settling” POC / ²³⁴Th) of the total spectrum of particles settling out of the upper ocean.     

Environmental records of carbonaceous fly-ash particles from fossil-fuel combustion

Analysis of fly-ash particles in lake sediments has become increasingly important in studies of environmental pollution and lake acidification history. Most fly-ash studies have concerned black spheroidal carbonaceous particles (SCP)(>5 m) produced from oil and coal combustion. This review paper provides a summary of this technique and its application, and focusses on our investigations in Sweden between 1979 and 1993. It consists of five parts: i) preparation and analysis methods, ii) historical trends in atmospheric deposition, iii) geographical surveys of atmospheric deposition, iv) sediment dating, and v) studies of sedimentation processes in lakes. Methods for preparation and analyses of SCP have been developed and applied to investigations using sediment, soil and snow samples. Stratigraphic trends of SCP concentrations in lake-sediment cores reflect the consumption history of fossil fuels. A characteristic temporal SCP pattern, with a marked concentration increase beginning after the 1940's and a peak in the early 1970's, has been recognized in most Swedish lakes and elsewhere in Europe. A survey of SCP concentrations in surface sediments of >100 lakes covering Sweden demonstrated that polluted areas in southern Sweden had >100 times higher SCP concentrations than clean areas in the north. The spatial distribution of SCP over Sweden is similar to the deposition pattern of long-range transported airborne pollutants, such as excess sulphate monitored by network stations. SCP also accumulate in soils, and soil analyses can be used for determining the integrated historical deposition of SCP at the local or regional scale. Finally, SCP have been used for indirect dating of sediment cores and as a marker to assess sediment distribution patterns within lake basins.     

The accuracy of methods used to estimate the whole-lake accumulation rate of organic carbon, major cations, phosphorus and heavy metals in sediment

The accuracy of three methods used to estimate the whole-lake accumulation rate of chemicals in sediment, the simple mean accumulation rate, regression against water depth and the mean accumulation rate in sedimentation zones, was assessed. The concentrations and accumulation rates of organic carbon, four major cations, phosphorus and four heavy metals in the 1902 to 1988 sediment layer at 43 sites in Kassjön were used and the three methods gave identical results. The accuracy of the simple mean accumulation rate method using 5 or 10 sites was investigated using Monte Carlo simulation and both versions gave accurate results. If the method used the dry sediment accumulation rate at 5 or 10 sites, along with chemical concentration at one central site, then the errors were less than ±10% for five of the chemicals and larger for the others (?20 or 20–40%), although the direction of the bias was predictable. If chemical accumulation rate at the central site only was used to estimate the whole-lake value, the bias increased to 25% for the major cations, 50% for the heavy metals and P, and 85% for organic carbon. Having 43 sites in Kassjön meant that the true whole-lake chemical accumulation rate was known and so the accuracy of the methods and their variants could be assessed for the first time. These findings allow the particulars of the simple mean accumulation rate method to be chosen to suit the accuracy needed for a palaeolimnological investigation.     

Uncertainties in Grout Penetrability Measurements; Evaluation and Comparison of Filter pump,Penetrability Meter and Short Slot

To measure grout penetrability in fractured hard rock, various measuring instruments have been developed over the years. Penetrability meter and Filter pump have been designed to use in both the lab and the field. Short slot has been applicable mainly in the lab due to its complexity. The fact, that these instruments have been built based on different assumptions, limitations, and test conditions, makes their results occasionally in contradict. Deficiency in design of the instruments as well as the methods of evaluating grout penetrability is additionally a basis for uncertainty in results. This study is an experimental effort to determine and thoroughly perceive the nature of the most governing uncertainties in grout penetrability measurements. The test apparatus, procedure, and method used to evaluate the grout penetrability in both Penetrability meter and Filter pump were thus modified. The aim was to control the corresponding uncertainties and make their limitations and test conditions as similar as possible with the ones in Short slot. The results suggested that to obtain a more realistic evaluation of the grout penetrability, measurement should be accomplished at both the high and the low pressures with sufficient grout volume using Short slot. Moreover, application of both Filter pump and Penetrability meter is no longer recommended due to the revealed uncertainties.