Punctuated,long-lived emplacement history of the Renard 2 kimberlite,Canada, revealed by new high precision U-Pb groundmass perovskite dating

Kimberlites are rare volatile-rich ultramafic magmas thought to erupt in short periods of time (<1 Myr) but there is a growing body of evidence that the emplacement history of a kimberlite can be significantly more protracted. In this study we report a detailed geochronology investigation of a single kimberlite pipe from the Renard cluster in north-central Québec. Ten new high precision ID-TIMS (isotope dilution – thermal ionization mass spectrometry) U-Pb groundmass perovskite dates from the main pipe-infilling kimberlites and several small hypabyssal kimberlites from the Renard 2 pipe indicate kimberlite magmatism lasted at least ~20 Myr. Two samples of the main pipe-infilling kimberlites yield identical weighted mean ²⁰⁶Pb/²³⁸U perovskite dates with a composite date of 643.8 ± 1.0 Myr, interpreted to be the best estimate for main pipe emplacement. In contrast, six hypabyssal kimberlite samples yielded a range of weighted mean ²⁰⁶Pb/²³⁸U perovskite dates between ~652-632 Myr. Multiple dates determined from these early-, syn- and late-stage small hypabyssal kimberlites in the Renard 2 pipe demonstrate this rock type (commonly used to date kimberlites) help to constrain the duration of kimberlite intrusion history within a pipe but do not necessarily reliably record the emplacement age of the main diatreme in the Renard cluster. Our results provide the first robust geochronological data on a single kimberlite that confirms the field relationships initially observed by Wagner (1914) and Clement (1982); the presence of antecedent (diatreme precursor) intrusions, contemporaneous (syn-diatreme) intrusions, and consequent (post-diatreme) cross-cutting intrusions. The results of this detailed U-Pb geochronology study indicate a single kimberlite pipe can record millions of years of magmatism, much longer than previously thought from the classical viewpoint of a rapid and short-duration emplacement history.

     

Winter severity and snowiness and their multiannual variability in the Karkonosze Mountains and Jizera Mountains

This paper analyses winter severity and snow conditions in the Karkonosze Mountains and Jizera Mountains and examines their long-term trends. The analysis used modified comprehensive winter snowiness (WSW) and winter severity (WOW) indices as defined by Paczos (1982). An attempt was also made to determine the relationship between the WSW and WOW indices. Measurement data were obtained from eight stations operated by the Institute of Meteorology and Water Management – National Research Institute (IMGW–PIB), from eight stations operated by the Czech Hydrological and Meteorological Institute (CHMI) and also from the Meteorological Observatory of the University of Wroc?aw (UWr) on Mount Szrenica. Essentially, the study covered the period from 1961 to 2015. In some cases, however, the period analysed was shorter due to the limited availability of data, which was conditioned, inter alia, by the period of operation of the station in question, and its type.Viewed on a macroscale, snow conditions in the Karkonosze Mountains and Jizera Mountains (in similar altitude zones) are clearly more favourable on southern slopes than on northern ones. In the study area, negative trends have been observed with respect to both the WSW and WOW indices—winters have become less snowy and warmer. The correlation between the WOW and WSW indices is positive. At stations with northern macroexposure, WOW and WSW show greater correlation than at ones with southern macroexposure. This relationship is the weakest for stations that are situated in the upper ranges (Mount ?nie?ka and Mount Szrenica).     

The smoke is rising but where is the fire? Exploring effective online map design for wildfire warnings

The current study sought to offer guidance for developing effective web-based mapping tools for wildfire warnings by identifying (1) the important content for facilitating individuals’ decision-making, and (2) the optimal interface design for ensuring usability and ease of information access. A map-based warning tool was prototyped in the Australian context, followed by a usability and effectiveness evaluation through individual interviews and verbal protocol analysis to assess participants’ interaction with the mapping interface and information in response to the simulated warning scenario. The results demonstrated variations in participants’ approaches to wildfire warning response, revealing varied information needs. Specifically, most participants relied on their own assessment of the prospective threat, requiring specific wildfire-related information before eliciting a response. In contrast, the decision of a minority of the participants was motivated by response guidance from agencies, and accurate wildfire information was less important for their response. Imperative information for both types of residents therefore needs to be highlighted in a map-based warning tool to cater to a wide audience. Furthermore, a number of heuristics were identified for designing effective interactive functions to facilitate the control of, and access to, the various maps and textual information presented on the map-based warning interface.     

Domestic and industrial water uses of the past 60 years as a mirror of socio-economic development: A global simulation study

To enhance global water use assessment, the WaterGAP3 model was improved for back-calculating domestic, manufacturing and thermoelectric water uses until 1950 for 177 countries. Model simulations were carried-out on a national scale to estimate water withdrawals and consumption as well as cooling water required for industrial processes and electricity production. Additionally, the amount of treated and untreated wastewater as generated by the domestic and manufacturing sectors was modeled. In the view of data availability, model simulations are based on key socio-economic driving forces and thermal electricity production. Technological change rates were derived from statistical records in order to consider developments in water use efficiency, which turned out to have a crucial role in water use dynamics. Simulated domestic and industrial water uses increased from ca. 300 km³ in 1950 to 1345 km³ in 2010, 12% of which were consumed and 88% of which were discharged back into freshwater bodies. The amount of domestic and manufacturing wastewater increased considerably over the last decade, but only half of it was untreated. The downscaling of the untreated wastewater volume to river basin scale indicates a matter of concern in East and Southeast Asia, Northern Africa, and Eastern and Southern Europe. In order to reach the Millennium Development Goals, securing water supply and the reduction of untreated wastewater discharges should be amongst the priority actions to be undertaken. Population growth and increased prosperity have led to increasing water demands. However, societal and political transformation processes as well as policy regulations resulting in new water-saving technologies and improvements counteract this development by slowing down and even reducing global domestic and industrial water uses.     

Holocene environmental history in high‐Arctic North Greenland revealed by a combined biomarker and macrofossil approach

In this study, we use a combined biomarker and macrofossil approach to reconstruct the Holocene climate history recorded in Trifna Sø, Skallingen area, eastern North Greenland. Chronological information is derived from comparison of lithological, biogeochemical and macrofossil characteristics with a well‐dated record from nearby Lille Sneha Sø. Following local deglaciation around c. 8 cal. ka BP, the local peak warmth occurred between c. 7.4 and 6.2 cal. ka BP as indicated by maximum macrofossil abundances of warmth‐demanding plants (Salix arctica and Dryas integrifolia) and invertebrates (Daphnia pulex and Chironomidae). Warm conditions were dominated by terrestrial organic matter (OM) sedimentation as implied by the alkane‐based P_aq ratio, but increased aquatic productivity is indicated when temperature was highest around 6.5 cal. ka BP. The n‐C₂₉/n‐C₃₁ alkane ratio shows that vegetation in the catchment was dominated by shrubs after deglaciation, but shifted towards relatively more grassy/herbaceous vegetation during peak warmth. After 5.4 cal. ka BP, the disappearance of warmth‐demanding plant and invertebrate macrofossils indicates cooling in the Skallingen area. This cooling was characterized by a significant shift towards dominance of aquatic OM sedimentation in Trifna Sø as implied by high P_aq ratios. Cooling was also associated with a shift in vegetation type from dwarf‐shrub heaths towards relatively more herbaceous vegetation in the catchment, stronger erosion and more oligotrophic conditions in the lake. Our data show that mean air temperatures inferred using branched glycerol dialkyl glycerol tetraethers (brGDGTs) do not seem to accurately reflect the local climatic history. Irrespective of calibration, methylation of branched tetraethers (MBT) palaeothermometry cannot be reconciled with the macrofossil evidence and seems to be biased by either changing brGDGT sources (in situ vs. soil‐derived) or changing species assemblages and/or an unknown physiological response to changing environmental conditions at high latitude.     

Enhancement and inhibition of iron photoreduction by individual ligands in open ocean seawater

In laboratory experiments, we investigated the effect of five individual Fe-binding ligands: phaeophytin, ferrichrome, desferrioxamine B (DFOB), inositol hexaphosphate (phytic acid), and protoporphyrin IX (PPIX) on the Fe(II) photoproduction using seawater of the open Southern Ocean. Addition of 10-100 nM Fe(III) to open Southern Ocean seawater without the model ligands and containing; 1.1 nM dissolved Fe(III), 1.75 ± 0.28 equivalents of nM Fe of natural ligands with a conditional stability constant (log K′) of 21.75 ± 0.34 and a concentration DOC of 86.8 ± 1.13 μM C leads to the formation of amorphous Fe(III) hydroxides. These amorphous Fe(III) hydroxides are the major source for the photoproduction of Fe(II). The addition of the model ligands changed the Fe(II) photoproduction considerably and in various ways. Phaeophytin showed higher Fe(II) photoproduction than ferrichrome and the control, i.e., amorphous Fe(III) hydroxides. Additions of phytic acid between 65 and 105 nM increased the concentration of photoproduced Fe(II) with 0.16 nM Fe(II) per nM phytic acid, presumably due to the co-aggregation of Fe(III) and phytic acid leading via an increasing colloidal surface to an increasing photoreducible Fe(III) fraction. DFOB and PPIX strongly decreased the photoproduced Fe(II) concentration. The low Fe(II) photoproduction with DFOB confirmed reported observations that Fe(III) complexed to DFOB is photo-stable. The PPIX hardly binds Fe(III) in the open Southern Ocean seawater but decreased the photoproduced Fe(II) concentration by complexing the Fe(II) with a binding rate constant of k_Fe(II)PPIX = 1.04 × 10⁻⁴ ± 1.53 × 10⁻⁵ s⁻¹ nM⁻¹ PPIX. Subsequently, PPIX is suggested to act as a photosensitizing producer of superoxide, thus increasing the dark reduction of Fe(III) to Fe(II). Our research shows that the photochemistry of Fe(III) and the resulting photoproduced Fe(II) concentration is strongly depending on the identity of the Fe-binding organic ligands and that a translation to natural conditions is not possible without further characterization of the natural occurring ligands.     

Effect of modelling scale on the assessment of climate change impact on river runoff

Abstract

The effect of using two distributed hydrological models with different degrees of spatial aggregation on the assessment of climate change impact on river runoff was investigated. Analyses were conducted in the Narew River basin situated in northeast Poland using a global hydrological model (WaterGAP) and a catchment-scale hydrological model (SWAT). Climate change was represented in both models by projected changes in monthly temperature and precipitation between the period 2040–2069 and the baseline period, resulting from two general circulation models: IPSL-CM4 and MIROC3.2, both coupled with the SRES A2 emissions scenario. The degree of consistency between the global and the catchment model was very high for mean annual runoff, and medium for indicators of high and low runoff. It was observed that SWAT generally suggests changes of larger magnitude than WaterGAP for both climate models, but SWAT and WaterGAP were consistent as regards the direction of change in monthly runoff. The results indicate that a global model can be used in Central and Eastern European lowlands to identify hot-spots where a catchment-scale model should be applied to evaluate, e.g. the effectiveness of management options.

Editor D. Koutsoyiannis; Associate editor F.F. Hattermann

Citation Piniewski, M., Voss, F., Bärlund, I., Okruszko, T., and Kundzewicz. Z.W., 2013. Effect of modelling scale on the assessment of climate change impact on river runoff. Hydrological Sciences Journal, 58 (4), 737–754.     

Dichotomy in host environments and signs of recycled active galactic nuclei

We analyse the relation between active galactic nuclei (AGN) host properties and large-scale environment for a representative red and blue AGN host galaxy sample selected from the Data Release 4 Sloan Digital Sky Survey. A comparison is made with two carefully constructed control samples of non-active galaxies, covering the same redshift range and colour baseline. The cross-correlation functions show that the density distribution of neighbours is almost identical for blue galaxies, either active or non-active. Although active red galaxies inhabit environments less dense compared to non-active red galaxies, both reside in environments considerably denser than those of blue hosts. Moreover, the radial density profile of AGN relative to galaxy group centres is less concentrated than galaxies. This is particularly evident when comparing red AGN and non-active galaxies.
The properties of the neighbouring galaxies of blue and red AGN and non active galaxies reflect this effect. While the neighbourhood of the blue samples is indistinguishable, the red AGN environs show an excess of blue-star-forming galaxies with respect to their non-active counterpart. On the other hand, the active and non-active blue systems have similar environments but markedly different morphological distributions, showing an excess of blue early-type AGN, which are argued to be late-stage mergers. This comparison reveals that the observable differences between active red and blue host galaxy properties including star formation history and AGN activity depends on the environment within which the galaxies form and evolve.     

Sorption of Cu and Pb to kaolinite-fulvic acid colloids: Assessment of sorbent interactions

The sorption of Cu(II) and Pb(II) to kaolinite-fulvic acid colloids was investigated by potentiometric titrations. To assess the possible interactions between kaolinite and fulvic acid during metal sorption, experimental sorption isotherms were compared with predictions based on a linear additivity model (LAM). Suspensions of 5 g L⁻¹ kaolinite and 0.03 g L⁻¹ fulvic acid in 0.01 M NaNO₃ were titrated with Cu and Pb solutions, respectively. The suspension pH was kept constant at pH 4, 6, or 8. The free ion activities of Cu²⁺ and Pb²⁺ were monitored in the titration vessel using ion selective electrodes. Total dissolved concentrations of metals (by ICP-MS) and fulvic acid (by UV-absorption) were determined in samples taken after each titration step. The amounts of metals sorbed to the solid phase, comprised of kaolinite plus surface-bound fulvic acid, were calculated by difference. Compared to pure kaolinite, addition of fulvic acid to the clay strongly increased metal sorption to the solid phase. This effect was more pronounced at pH 4 and 6 than at pH 8, because more fulvic acid was sorbed to the kaolinite surface under acidic conditions. Addition of Pb enhanced the sorption of fulvic acid onto kaolinite at pH 6 and 8, but not at pH 4. Addition of Cu had no effect on the sorption of fulvic acid onto kaolinite. In the LAM, metal sorption to the kaolinite surface was predicted by a two-site, 1-pK basic Stern model and metal sorption to the fulvic acid was calculated with the NICA-Donnan model, respectively. The LAM provided good predictions of Cu sorption to the kaolinite-fulvic acid colloids over the entire range in pH and free Cu²⁺ ion activity (10⁻¹² to 10⁻⁵). The sorption of Pb was slightly underestimated by the LAM under most conditions. A fractionation of the fulvic acid during sorption to kaolinite was observed, but this could not explain the observed deviations of the LAM predictions from the experimental Pb sorption isotherms.