Chemical and mechanical processes during burial diagenesis of chalk: an interpretation based on specific surface data of deep-sea sediments

Burial diagenesis of chalk is a combination of mechanical compaction and chemical recrystallization as well as cementation. We have predicted the characteristic trends in specific surface resulting from these processes. The specific surface is normally measured by nitrogen adsorption but is here measured by image analysis of scanning electron micrographs. This method concentrates on the micritic matrix alone. Deep-sea sediments are ideally suited to the study of burial diagenesis because they accumulate in a relatively conservative tectonic setting. We used material from the Ontong Java Plateau in the Pacific, where a > 1 km thick package of chalk facies sediments accumulated from the Cretaceous to the present. In the upper 200–300 m the sediment is unconsolidated carbonate ooze, throughout this depth interval compaction is the principal porosity reducing agent, but recrystallization has an equal or larger influence on the textural development. In the chalk interval below, compaction is not the only porosity reducing agent but it has a larger influence on texture than concurrent recrystallization. Below 850 m grain-bridging cementation becomes important resulting in a lithified limestone below 1100 m. This interpretation is based on specific surface data alone, and modifies current diagenetic models.     

Process length variation in cysts of the dinoflagellate Protoceratium reticulatum,from surface sediments of the Baltic–Kattegat–Skagerrak estuarine system: a regional salinity proxy

Mertens, K. N., Dale, B., Ellegaard, M., Jansson, I.‐M., Godhe, A., Kremp, A. & Louwye, S. 2010: Process length variation in cysts of the dinoflagellate Protoceratium reticulatum, from surface sediments of the Baltic–Kattegat–Skagerrak estuarine system: a regional salinity proxy. Boreas, 10.1111/j.1502‐3885.2010.00193.x. ISSN 0300‐9483. Results are presented from a regional comparison of average process length variation in cysts of Protoceratium reticulatum and Lingulodinium polyedrum, extracted from surface sediments in the Skagerrak–Kattegat–Baltic estuarine system, with the environmental variables of seawater temperature and salinity. Although too few cysts of Lingulodinium polyedrum were recovered from the sediments to make reliable correlations, cysts of Protoceratium reticulatum were well represented, and average process length was correlated significantly with both salinity and temperature. Owing to dominant summer surface production, and regional covariation between salinity and density, we propose the use of the significant correlation with summer sea surface salinity (SSS_summer) by the equation SSS_summer=3.16 × average process length ?0.84 (R²=0.8). Application of this equation down‐core in Limfjord (northern Denmark) shows its usefulness as a regional palaeosalinity proxy.     

Stylolites, porosity, depositional texture, and silicates in chalk facies sediments. Ontong Java Plateau – Gorm and Tyra fields, North Sea

Comparison of chalk on the Ontong Java Plateau and chalk in the Central North Sea indicates that, whereas pressure dissolution is controlled by effective burial stress, pore-filling cementation is controlled by temperature. Effective burial stress is caused by the weight of all overlying water and sediments as counteracted by the pressure in the pore fluid, so the regional overpressure in the Central North Sea is one reason why the two localities have different relationships between temperature and effective burial stress. In the chalk of the Ontong Java Plateau the onset of calcite-silicate pressure dissolution around 490 m below sea floor (bsf) corresponds to an interval of waning porosity-decline, and even the occurrence of proper stylolites from 830 m bsf is accompanied by only minor porosity reduction. Because opal is present, the pore-water is relatively rich in Si which through the formation of Ca–silica complexes causes an apparent super-saturation of Ca and retards cementation. The onset of massive pore-filling cementation at 1100 m bsf may be controlled by the temperature-dependent transition from opal-CT to quartz. In the stylolite-bearing chalk of two wells in the Gorm and Tyra fields, the nannofossil matrix shows recrystallization but only minor pore-filling cement, whereas microfossils are cemented. Cementation in Gorm and Tyra is thus partial and has apparently not been retarded by opal-controlled pore-water. A possible explanation is that, due to the relatively high temperature, silica has equilibrated to quartz before the onset of pressure dissolution and thus, in this case, dissolution and precipitation of calcite have no lag. This temperature versus effective burial stress induced difference in diagenetic history is of particular relevance when exploring for hydrocarbons in normally pressured chalk, while most experience has been accumulated in the over-pressured chalk of the central North Sea.     

An Early or Middle Weichselian sequence of proglacial, shallow marine sediments on western Svalbard

A 20 m thick shallow marine sequence, capped by a Late Weichselian lodgement till, is exposed for 200111 along the river in Linnedalen on the west coast of Svalbard. Five formations are recognized: Formation A, the oldest, consists of a shallow marine, proglacial fan, of channelized sandy turbidites, possibly fed from an ice-contact deposit. Formation B, a sequence of proglacial channels and ice-rafted debris, was formed during a small oscillation of the glacier. Formation C, a prograding, storm-dominated shoreline sequence, was formed during a sea level fall, assumed to be a result of glacio-isostatic uplift.
Formation D, a lodgement till formed during the last glacier advance in Linnedalen and formation E, a coarsening upwards sequence, were formed during the post-glacial sea level fall. The subtill sequence (fm. A, B and C) is dated to between 40,000BP (radiocarbon dates) and 120,000BP (thermoluminescence and amino acid D/L ratios). The glacier front was 10 km downvalley during deposition of formations A and B, relative to the present glacier terminus, and more than 12km during the late Weichselian maximum.     

The Kregnes moraine in Gauldalen, west-central Norway: anatomy of a Younger Dryas proglacial delta in a palaeofjord basin*

The Kregnes “moraine” ridge in Gauldalen, a north-trending valley south of Trondheim, is a Gilbert-type delta formed at a Younger Dryas glacier terminus. The gravelly delta consists of a north-dipping foreset, 150 m thick, comprised of turbidites, debrisflow beds and debrisfall deposits. The bottomset consists of turbiditic sand and mud layers. The topset, 2-3 m thick, is a braided-river alluvium with local beach deposits, matching the marine limit of 175 m a.s.l. The fjord-wide delta front had an extent of 3 km and prograded over a distance of 1.5 km, in probably less than 100 years, with the delta toe climbing by 50 m against the basin's rapidly aggrading muddy floor. The delta advanced through the alternating episodes of its toe aggradation and progradation, related to the increases and decreases of the delta-slope gradient. Slope steepening led to intense sediment sloughing by chutes and occasional large-scale failures. The fjord's wave fetch was low and the wave base no deeper than 1.5-2 m, but strong storm waves occasionally reworked the delta front to a depth of 6 m. Glacitectonic deformation was limited to the system's upfjord end. Allostratigraphic analysis suggests that the proglacial system commenced its development as an ice-contact submarine fan that was deformed, quickly aggraded to the sea surface and turned into an ice-contact delta, which further evolved into the large glaciofluvial delta. The Kregnes ridge represents an episode of the ice-front re-advance due to climatic deterioration and is tentatively correlated with the Hoklingen substage.     

Formation and disintegration of a high-arctic ice-cored moraine complex, Scott Turnerbreen, Svalbard

Englacial debris structures, morphology and sediment distribution at the frontal part and at the proglacial area of the Scott Turnerbreen glacier have been studied through fieldwork and aerial photograph interpretation. The main emphasis has been on processes controlling the morphological development of the proglacial area. Three types of supraglacial ridges have been related to different types of englacial debris bands. We suggest that the sediments were transported in thrusts, along flow lines and in englacial meltwater channels prior to, and during a surge in, the 1930s, before the glacier turned cold. Melting-out of englacial debris and debris that flows down the glacier front has formed an isolating debris cover on the glacier surface, preventing further melting. As the glacier wasted, the stagnant, debris-covered front became separated from the glacier and formed icecored moraine ridges. Three moraine ridges were formed outside the present ice-front. The further glacier wastage formed a low-relief proglacial area with debris-flow deposits resting directly on glacier ice. Melting of this buried ice initiated a second phase of slides and debris flows with a flow direction independent of the present glacier surface. The rapid disintegration of the proglacial morphology is mainly caused by slides and stream erosion that uncover buried ice and often cause sediments to be transported into the main river and out of the proglacial area. Inactive stream channels are probably one of the morphological elements that have the best potential for preservation in a wasting ice-cored moraine complex and may indicate former ice-front positions.     

Comparison of Quaternary interglacial periods in the Iceland Sea

Five Quaternary interglacial periods are represented in core 57-7 from the Iceland Sea. Analysis of coccolith and planktonic foraminiferal assemblages from the interglacial periods (Oxygen Isotope Stages 1, 5, 7, 9 and 11) shows both similarities and differences in the assemblages. The differences indicate that the palaeoenvironment was not identical in the five interglacial periods. Oxygen Isotope Substage 5e reflects the warmest period, with the greatest inflow of warm Atlantic water. During this interval the Arctic Front apparently had a more westerly position than it has today. Substages 5a and 5c were periods when Arctic water masses dominated, as at the present day. In Oxygen Isotope Stages 7 and 9 inflow of Atlantic water was limited. Oxygen Isotope Stage 11 reflects a period of great productivity, but the region was still dominated by Arctic water masses. The position of the Arctic Front was possibly close to that of today, but not at the extreme western position it had in Oxygen Isotope Substage 5e.     

Experimental Crystallization of a High-K Arc Basalt: the Golden Pumice, Stromboli Volcano (Italy)

The near-liquidus crystallization of a high-K basalt (PST-9golden pumice, 49·4 wt % SiO₂, 1·85 wt % K₂O,7·96 wt % MgO) from the present-day activity of Stromboli(Aeolian Islands, Italy) has been experimentally investigatedbetween 1050 and 1175°C, at pressures from 50 to 400 MPa,for melt H₂O concentrations between 1·2 and 5·5wt % and NNO ranging from –0·07 to +2·32.A drop-quench device was systematically used. AuPd alloys wereused as containers in most cases, resulting in an average Feloss of 13% for the 34 charges studied. Major crystallizingphases include clinopyroxene, olivine and plagioclase. Fe–Tioxide was encountered in a few charges. Clinopyroxene is theliquidus phase at 400 MPa down to at least 200 MPa, followedby olivine and plagioclase. The compositions of all major phasesand glass vary systematically with the proportion of crystals.Ca in clinopyroxene sensitively depends on the H₂O concentrationof the coexisting melt, and clinopyroxene Mg-number shows aweak negative correlation with NNO. The experimental data allowthe liquidus surface of PST-9 to be defined. When used in combinationwith melt inclusion data, a consistent set of pre-eruptive pressures(100–270 MPa), temperatures (1140–1160°C) andmelt H₂O concentrations is obtained. Near-liquidus phase equilibriaand clinopyroxene Ca contents require melt H₂O concentrations<2·7–3·6 and 3 ± 1 wt %, respectively,overlapping with the maximum frequency of glass inclusion data(2·5–2·7 wt % H₂O). For olivine to crystallizeclose to the liquidus, pressures close to 200 MPa are needed.Redox conditions around NNO = +0·5 are inferred fromclinopyroxene compositions. The determined pre-eruptive parametersrefer to the storage region of golden pumice melts, which islocated at a depth of around 7·5 km, within the metamorphicarc crust. Golden pumice melts ascending from their storagezone along an adiabat will not experience crystallization ontheir way to the surface. KEY WORDS: basalt; pumice; experiment; phase equilibria; Stromboli     

Physical signatures of ice advance in a Younger Dryas ice-contact delta, Troms, northern Norway: implications for glacier-terminus history

The depositional history of an ice-contact delta in Sørfjorden has been reconstructed, based on two sections, 100 and 900 m long. Five major sedimentary facies have been distinguished within the delta's foreset, and their geometry and spatial organization have been mapped in the outcrops through the use of photographs. Facies 1 comprises chaotically bedded coarse clastics; facies 2 comprises sets of high-angle clinoforms; facies 3 comprises sets of low-angle sandy clinoforms; facies 4 comprises sets of hummocky sandy clinoforms and facies 5 comprises sets of low-angle to subhorizontal sandy and muddy clinoforms. The glacier advanced at least 500 m during the formation of the foreset sequence. Six minor halts during this advance are indicated. The study puts new constraints on the history of the Younger Dryas ice advance in the region, including local palaeogeography, ice-front dynamics and fjord-fill sediment stratigraphy.