Long-term moored array measurements of currents and hydrography over Georges Bank: 1994–1999

In conjunction with the GLOBEC (Global Ocean Ecosystems Dynamics) program, measurements of moored currents, temperature and salinity were made during 1994–1999 at locations in 76 m of water along the southern flank of Georges Bank and at the Northeastern Peak. The measurements concentrate on the biologically crucial winter and spring periods, and coverage during the fall is usually poorer.Current time series were completely dominated by the semidiurnal M₂ tidal component, while other tidal species (including the diurnal K₁ component) were also important. There was a substantial wind-driven component of the flow, which was linked, especially during the summer, to regional–scale response patterns. The current response at the Northeast Peak was especially strong in the 3–4 days period band, and this response is shown to be related to an amplifying topographic wave propagating eastward along the northern flank. Monthly mean flows on the southern flank are southwestward throughout the year, but strongest in the summertime. The observed tendency for summertime maximum along-bank flow to occur at depth is rationalized in terms of density gradients associated with a near-surface freshwater tongue wrapping around the Bank.Temperature and salinity time series demonstrate the presence, altogether about 25% of the time, of a number of intruding water masses. These intrusions could last anywhere from a couple days up to about a month. The sources of these intrusions can be broadly classified as the Scotian Shelf (especially during the winter), the Western Gulf of Maine (especially during the summer), and the deeper ocean south of Georges Bank (throughout the year). On longer time scales, the temperature variability is dominated by seasonal temperature changes. During the spring and summer, these changes are balanced by local heating or cooling, but wintertime cooling involves advective lateral transports as well. Salinity variations have weak, if any, seasonal variability, but are dominated by interannual changes that are related to regional- or basin-scale changes.All considered, Georges Bank temperature and salinity characteristics are found to be highly dependent on the surrounding waters, but many questions remain, especially in terms of whether intrusive events leave a sustained impact on Bank waters.     

Mantle plumes and the metamorphism of the lower crust and their influence on basin evolution

Since the stretching model appears to be not applicable to the subsidence of accretionary crust, basins located on this crust type may have an alternative origin. Examples of such basins are the West Siberia Basin and the North German Basin. Both basins showed intensive volcanism and magmatism during the initial phase of their development. Remarkably, the West Siberia Basin is closely located to the (hotspot related) Siberian flood basalts with a similar Permo-Triassic age, and the location of the North German Basin in Permian times is identical with the present day position of the Tibesti hotspot in Northern Africa. These two basins may have specific relations to hotspot heat sources of the Earth's underlying mantle. Due to these heat sources, thermal metamorphism within the lower layers of the (accretionary) crust may occur, resulting in rock density increase and subsequent shrinkage of the affected rock volumes. These shrinkage processes will lead to the development of topographic lows, their filling with sediments, and the subsequent start of an exponentially declining isostatic/metamorphic basin subsidence. In addition to the analyses of metamorphic processes, potential field anomalies, temperature fields, and histories of subsidence have been integrated into one single model that can explain the development of the North German Basin. Similarly, the East African Rift and Eifel Hotspots affected parts of the overriding continental plates. The East African Rift Hotspot can be traced back to the Afar flood basalts and the Dniepr–Donets Basin, whereas the Eifel Hotspot can be linked to the North Sea Basin. Continental drift templates, present day hotspot locations, flood basalt areas, metamorphic facies as function of temperature, and crust categories are taken as published in recent literature.     

PCB concentrations and metabolism patterns in common terns (Sterna hirundo) from different breeding colonies in The Netherlands

PCB levels in blood of common terns (Sterna hirundo) from Terneuzen, a breeding colony in The Netherlands with relatively low breeding success, were significantly higher than in birds from two Dutch reference colonies, one nearby (Oesterdam) and one further away (the Isle of Griend). However, a detailed analysis of the patterns of PCB congeners in birds from the different colonies indicated that birds from Terneuzen and to a lesser extent birds from the Oesterdam showed Ah-receptor mediated activity of P450 iso-enzymes. It is concluded that the induction of this enzyme activity in Terneuzen may be related to PCBs as well as other non-identified compounds. In contrast to this, it is likely that at the Oesterdam non-identified compounds are mainly responsible for the enzyme activity, resulting in a shift of PCB congener patterns.     

The Cloud Ice Mountain Experiment (CIME) 1998: experiment overview and modelling of the microphysical processes during the seeding by isentropic gas expansion

The second field campaign of the Cloud Ice Mountain Experiment (CIME) project took place in February 1998 on the mountain Puy de Dôme in the centre of France. The content of residual aerosol particles, of H₂O₂ and NH₃ in cloud droplets was evaluated by evaporating the drops larger than 5 μm in a Counterflow Virtual Impactor (CVI) and by measuring the residual particle concentration and the released gas content. The same trace species were studied behind a round jet impactor for the complementary interstitial aerosol particles smaller than 5 μm diameter. In a second step of experiments, the ambient supercooled cloud was converted to a mixed phase cloud by seeding the cloud with ice particles by the gas release from pressurised gas bottles. A comparison between the physical and chemical characteristics of liquid drops and ice particles allows a study of the fate of the trace constituents during the presence of ice crystals in the cloud.In the present paper, an overview is given of the CIME 98 experiment and the instrumentation deployed. The meteorological situation during the experiment was analysed with the help of a cloud scale model. The microphysics processes and the behaviour of the scavenged aerosol particles before and during seeding are analysed with the detailed microphysical model ExMix. The simulation results agreed well with the observations and confirmed the assumption that the Bergeron–Findeisen process was dominating during seeding and was influencing the partitioning of aerosol particles between drops and ice crystals. The results of the CIME 98 experiment give an insight on microphysical changes, redistribution of aerosol particles and cloud chemistry during the Bergeron–Findeisen process when acting also in natural clouds.     

Behaviour of H2O2, NH3, and black carbon in mixed-phase clouds during CIME

We investigated the partitioning of trace substances during the phase transition from supercooled to mixed-phase cloud induced by artificial seeding. Simultaneous determination of the concentrations of H₂O₂, NH₃ and black carbon (BC) in both condensed and interstitial phases with high time resolution showed that the three species undergo different behaviour in the presence of a mixture of ice crystals and supercooled droplets. Both H₂O₂ and NH₃ are efficiently scavenged by growing ice crystals, whereas BC stayed predominantly in the interstitial phase. In addition, the scavenging of H₂O₂ is driven by co-condensation with water vapour onto ice crystals while NH₃ uptake into the ice phase is more efficient than co-condensation alone. The high solubility of NH₄⁺ in the ice could explain this result. Finally, it appears that the H₂O₂–SO₂ reaction is very slow in the ice phase with respect to the liquid phase. Our results are directly applicable for clouds undergoing limited riming.     

δ objects as a gauge for stress sensitivity of strain rate in mylonites

Our understanding of the flow properties of deforming rocks in the Earth's lithosphere is mainly based on theoretical work and on the extrapolation of high-strain-rate experimental data to the low strain rates of rock deformation in nature. The geometry of structures in naturally deformed rocks can be an additional source of information on the rheology of the lithosphere. Flow experiments show that the geometry of a mantle of recrystallised material around a rigid object can be used to distinguish between a linear or power-law relation of differential stress and strain rate in strongly deformed rocks such as mylonites. This means that it is possible to use geometrical patterns in deformed rocks to constrain aspects of the rheology and to check the applicability of theoretical models and the extrapolation of laboratory data on creep in rocks to nature.     

Shelfbreak circulation and thermohaline structure in the northern south China Sea-contrasting spring conditions in 2000 and 2001

Two intensive, high-resolution hydrographic surveys during April 2000 and May 2001 are used to characterize the thermohaline and current structure at the shelfbreak in the South China Sea. In 2000, a strong anticyclonic circulation was present in the northern portion of the South China Sea with strong onshore currents east of Dongsha Island. The flow became polarized along isobaths as it encountered shallow water, with northeastward flows of over 0.9 m/s along steep topography. The flow was driven by strong density contrasts between waters of the outer shelf and upper slope. Shelf water was both cooler and more fresh than the water offshore, which had salinities close to that of Kuroshio water. In contrast, the mean flow in the northern South China Sea was predominantly cyclonic in 2001. Flow over the slope was to the southwest at up to 0.2 m/s. The water mass properties of the outer shelf and upper slope were similar, so that there were not the strong cross-shelf density gradients present as in 2000. A potential difference between the water mass structure of the two years was the difference in cooling during the preceding winters. In December, 1999, unusually strong cooling may have resulted in cooler shelf waters relative to the following year. The ASIAEX study area may be a particularly sensitive region to both seasonal and interannual variability, as it is near a bifurcation point associated with the Kuroshio Intrusion into the South China Sea.     

High temperature gas–solid reactions in calc–silicate Cu–Au skarn formation; Ertsberg,Papua Province,Indonesia

The 2.7–3 Ma Ertsberg East Skarn System (Indonesia), adjacent to the giant Grasberg Porphyry Copper deposit, is part of the world’s largest system of Cu–Au skarn deposits. Published fluid inclusion and stable isotope data show that it formed through the flux of magma-derived fluid through contact metamorphosed carbonate rock sequences at temperatures well above 600° C and pressures of less than 50 MPa. Under these conditions, the fluid has very low density and the properties of a gas. Combining a range of micro-analytical techniques, high-resolution QEMSCAN mineral mapping and computer-assisted X-ray micro-tomography, an array of coupled gas–solid reactions may be identified that controlled reactive mass transfer through the ~ 1 km³ hydrothermal skarn system. Vacancy-driven mineral chemisorption reactions are identified as a new type of reactive transport process for high-temperature skarn alteration. These gas–solid reactions are maintained by the interaction of unsatisfied bonds on mineral surfaces and dipolar gas-phase reactants such as SO₂ and HCl that are continuously supplied through open fractures and intergranular diffusion. Principal reactions are (a) incongruent dissolution of almandine-grossular to andradite and anorthite (an alteration mineral not previously recognized at Ertsberg), and (b) sulfation of anorthite to anhydrite. These sulfation reactions also generate reduced sulfur with consequent co-deposition of metal sulfides. Diopside undergoes similar reactions with deposition of Fe-enriched pyroxene in crypto-veins and vein selvedges. The loss of calcium from contact metamorphic garnet to form vein anhydrite necessarily results in Fe-enrichment of wallrock, and does not require Fe-addition from a vein fluid as is commonly assumed.     

UML‐Based Approach to Developing a CityGML Application Domain Extension

Recently a national 3D standard was established in the Netherlands as a CityGML Application Domain Extension (called IMGeo). In line with the Dutch practice of modeling geo‐information, the ADE is developed using a model driven approach. The classes are designed in UML and automatically mapped to GML schema. The current OGC CityGML specification does not provide rules or guidance on correctly modeling an ADE in UML. This article fills this gap by studying how CityGML can be extended for specific applications starting from the UML diagrams. Six alternatives for modeling ADEs in UML are introduced and compared. The optimal alternative is selected and applied to obtain the national 3D standard. The approach was extensively discussed with international experts, who were members of both SIG3D and other working groups. As a consequence the approach was adopted by the SIG3D, the Special Interest Group 3D which, among other things, work on the 3D standard CityGML in cooperation with OGC. Therefore the approach contains many issues that can be generalized and reused by future domain extensions of CityGML. To further support this, the article formulates a model‐driven framework to model CityGML ADEs. Open issues are described in the conclusions.