A laboratory test of the soil chemical submodels of two models of catchment acidification

Parameters for ion exchange selectivity and aluminium hydroxide dissolution in the soil chemical submodels used in applications of the Birkenes model and of MAGIC are compared and several discrepancies identified for organic soils. A laboratory column simulation of the soil chemical submodels is proposed and applied to soils from the Loch Dee area in Galloway. Experimental results were well predicted by a simplified version of MAGIC, with ion exchange selectivity parameters similar to those used in a previous simulation of one subcatchment of Loch Dee. The aluminium hydroxide dissolution parameter used previously was found to be too low for the organic soil materials, where a value of 106 predicted the experimental results more closely. The model developed also included a simple silicate weathering reaction to release base cations into the system. It is concluded that such simple laboratory simulations are useful for independent calibration of the soil chemical submodel of catchment models.     

Dissolved organic carbon dynamics in two streams draining forested catchments at loch ard,Scotland

Dissolved organic carbon (DOC) was measured at four or eight hour intervals between mid-1989 and mid-1991 in two catchments in west central Scotland. The experimental catchment had been recently clear-felled and the control remained under forest. The amount of DOC varied during individual storm events following the stream hydro-graph. Maximum variations were found in the summer half-year and in the clear-felled catchment. There was also evidence of the exhaustion of DOC in the later events of a sequence. Differences between the catchments were related to catchment characteristics and to land-use change. The reduced magnitude of variation in DOC with discharge in the control stream was due to the influence of a wetland area through which the stream flowed. The mean DOC concentrations were similar in the two streams and annual exports were 15 g m^?2 from the control and 16g m^?2 from the felled catchment. The stream draining the clear-felled catchment had greater high flow DOC concentrations in the summer half-year, probably due to the effect of greater mean summer temperatures on DOC release and of the greater supply of organic debris in the stream channel.     

The terrestrial cratering record: I. Current status of observations

The location, size, and principal characteristics of the currently known proven and probable terrestrial impact structures are tabulated. Of the 78 known probable structures, only 3 are Precambrian and the majority are <300 my in age. A survey of the variation in preservation with size and age indicates that, unless protected by sedimentary cover, a structure <20 km in diameter has a recognizable life of <600 my. The depth-diameter relationships of terrestrial structures are similar to lunar craters; however, it is believed that terrestrial craters were always shallower than their lunar counterparts. Complex structures formed in sedimentary targets are shallower than those in crystalline targets, and the transition from simple to complex crater morphology occurs in sedimentary strata at approximately one-half the diameter of the morphology transition in crystalline rocks. This is a reflection of target strength. Although observations indicate that crater size, target strength, and surface gravity are variables in the formation of complex craters, they do not permit an unequivocal choice between collapse and rebound processes for the formation of complex structures. It may be that both processes act together in the modification of crater morphology during the later stages of excavation. The major emphasis of recent shock metamorphic studies has been toward the development of models of cratering processes. An important contribution has been the identification, through meteoritic contamination in the melt rocks, of the type of bolide at a number of probable impact structures. This has served to strengthen the link between the occurrence of shock metamorphic effects and their origin by hypervelocity meteorite impact.     

Transitional impact craters on the Moon: Insight into the effect of target lithology on the impact cratering process

We studied a data set of 28 well‐preserved lunar craters in the transitional (simple‐to‐complex) regime with the aim of investigating the underlying cause(s) for morphological differences of these craters in mare versus highland terrains. These transitional craters range from 15 to 42 km in diameter, demonstrating that the transition from simple to complex craters is not abrupt and occurs over a broad diameter range. We examined and measured the following crater attributes: depth (d), diameter (D), floor diameter (D_f), rim height (h), and wall width (w), as well as the number and onset of terraces and rock slides. The number of terraces increases with increasing crater size and, in general, mare craters possess more terraces than highland craters of the same diameter. There are also clear differences in the d/D ratio of mare versus highland craters, with transitional craters in mare targets being noticeably shallower than similarly sized highland craters. We propose that layering in mare targets is a major driver for these differences. Layering provides pre‐existing planes of weakness that facilitate crater collapse, thus explaining the overall shallower depths of mare craters and the onset of crater collapse (i.e., the transition from simple to complex crater morphology) at smaller diameters as compared to highland craters. This suggests that layering and its interplay with target strength and porosity may play a more significant role than previously considered.     

Complex crater formation: Insights from combining observations of shock pressure distribution with numerical models at the West Clearwater Lake impact structure

Large impact structures have complex morphologies, with zones of structural uplift that can be expressed topographically as central peaks and/or peak rings internal to the crater rim. The formation of these structures requires transient strength reduction in the target material and one of the proposed mechanisms to explain this behavior is acoustic fluidization. Here, samples of shock‐metamorphosed quartz‐bearing lithologies at the West Clearwater Lake impact structure, Canada, are used to estimate the maximum recorded shock pressures in three dimensions across the crater. These measurements demonstrate that the currently observed distribution of shock metamorphism is strongly controlled by the formation of the structural uplift. The distribution of peak shock pressures, together with apparent crater morphology and geological observations, is compared with numerical impact simulations to constrain parameters used in the block‐model implementation of acoustic fluidization. The numerical simulations produce craters that are consistent with morphological and geological observations. The results show that the regeneration of acoustic energy must be an important feature of acoustic fluidization in crater collapse, and should be included in future implementations. Based on the comparison between observational data and impact simulations, we conclude that the West Clearwater Lake structure had an original rim (final crater) diameter of 35–40 km and has since experienced up to ~2 km of differential erosion.     

Chemical variations and genetic relationships between the Hess and Foy offset dikes at the Sudbury impact structure

Offset dikes are found concentrically around—and extending radially outward from—the Sudbury Igneous Complex (SIC), which represents an ~3 km thick differentiated impact melt sheet. The dikes are typically composed of an inclusion‐rich, so‐called quartz diorite (IQD) in the center of the dike, and an inclusion‐poor quartz diorite (QD) along the margins of the dike. New exposures of the intersection between the concentric Hess and radial Foy offset dikes provide an excellent opportunity to understand the relationship between the radial and concentric offset dikes and their internal phases. The goal was to constrain the timing of the dike emplacements relative to the impact and formation of the SIC. Results herein suggest that (1) the timing between the emplacement of the QD and IQD melts was geologically short, (2) the Hess and Foy dikes coexisted as melts at the same time and the intersection between them represents a mixture of the two, (3) the Foy dike has a slightly more evolved chemical composition than the Hess dike, and (4) the IQD melt from the Foy dike underwent some degree of chemical fractionation after its initial emplacement.     

Relationships among dissolved organic matter,iron, and discharge in a moorland stream

Dissolved organic matter (DOM) and iron in a moorland stream were determined at 8-hour intervals over a 6-month period to examine relationships with streamflow. Regression of both solutes on discharge were positive and explained 50–70 per cent of the variance in the solute data, but better predictions were obtained in both cases when a covariate reflecting temporal variation in the relationships was introduced (explained variance 80–90 per cent). Variations in the regression of Fe on DOM were also identified, indicating differences in the complexing power of DOM for Fe and possible variations in the chemical composition of the DOM.     

The Sudbury Structure (Ontario,Canada): a tectonically deformed multi-ring impact basin

The occurrence of shock metamorphic features substantiates an impact origin for the 1.85 Ga old Sudbury Structure, but this has not been universally accepted. Recent improvements in knowledge of large-scale impact processes, combined with new petrographic, geochemical, geophysical (LITHOPROBE) and structural data, allow the Sudbury Structure to be interpreted as a multi-ring impact structure. The structure consists of the following lithologies: Sudbury Breccia —dike breccias occurring up to 80 km from the Sudbury Igneous Complex (SIC); Footwall rocks and Footwall Breccia — brecciated, shocked crater floor materials, in part thermally metamorphosed by the overlying SIC; Sublayer and Offset Dikes, Main Mass of the SIC and Basal Member of the Onaping Formation (OF) — geochemically heterogeneous coherent impact melt complex ranging from inclusion-rich basal unit through a dominantly inclusion-free to a capping inclusion-rich impact melt rock; Grey Member of OF — melt-rich impact breccia (suevite); Green Member of OF — thin layer of fall back ejecta; Black Member of OF — reworked and redeposited breccia material; Onwatin and Chelmsford Formations — post-impact sediments. Observational and analytical data support an integrated step-by-step impact model for the genesis of these units. Analysis of the present spatial distribution of various impact-related lithologies and shock metamorphic effects result in an estimated original rim-to-rim diameter of the final crater of 200 or even 280 km for the Sudbury Structure, prior to tectonic thrusting and deformation during the Penokean orogeny.     

Lunar polymict breccia 14321: a petrographic study

Seven petrographic thin sections of lunar rock sample 14321, ‘Big Bertha’, have been examined. It is a complex rock incorporating diverse lithic and single crystal fragments and represents a sampling of the heterogeneous Fra Mauro formation, considered by the writers to be lithified debris from the Imbrium impact event. Electron probe microanalysis and microscopic study of textures reveal the assembly history of this breccia which in turn allows some interpretation of the nature of the pre-Imbrium crust and the effect of the Imbrium impact and the subsequent transportation to the Apollo 14 site. The present-day polymict breccia 14321 is composed of basaltic clasts originating from the fragmentation of a single or closely related set of lava cooling units, a set of fragmental clasts designated as microbreccia 3 (themselves polymict microbreccias), and a light colored matrix which formed rock 14321 by cementing the two major groups of clasts. The light colored matrix material is derived from the fragmentation and mutual abrasion of the basalt and microbreccia 3. On the basis of consistent textural relations two older sets of microbreccias have been identified within microbreccia 3. Microbreccia 1 clasts are well-rounded, relatively light colored, and noritic. They are always completely enclosed within microbreccia 3, most often forming the central cores of rounded accretionary lapilli structures which we have designated as microbreccia 2. Microbreccias 1, 2, 3, and macrobreccia 14321 represent a chronological series of fragmentation and lithification events. Each of these events involved some thermal and/or shock metamorphism as evidenced by mineralogical and textural criteria, and the chronological order of formation of the breccias also corresponds to a decreasing intensity of associated thermal effects. The petrology and mineralogy of 14321 are described in detail in this paper. A more general interpretation of the combined petrographic and chemical data is given in Duncanet al. (1975a).     

Meteoritic material at four Canadian impact craters

Eleven impact melt and 6 basement rock samples from 4 craters were analyzed by neutron activation for Au, Co, Cr, Fe, Ge, Ir, Ni, Os, Pd, Re and Se. Wanapitei Lake, Ontario: the impact melts show uniform enrichments corresponding to 1–2% C1-chondrite material. Interelement ratios ($\text{Co}\text{Cr}$, $\text{Ni}\text{Cr}$, $\text{Ni}\text{Ir}$) suggest that the impacting body was a Cl-, C2-, or LL-chondrite. Nicholson Lake, North West Territory: Ni, Cr and Co are distinctly more enriched than Ir and Au which tentatively suggests an olivine-rich achondrite (nakhlite or ureilite). Gow Lake, Saskatchewan and Mistastin, Labrador: small enrichments in Ir and Ni; both the low $\text{Ir}\text{Ni}$ ratios and low Cr content suggest iron meteorites, but the signals are too weak for conclusive identification.A tentative comparison of meteoritic signatures at 10 large, ≥4km craters and their presumed celestial counterparts (13 Apollo and Amor asteroids) shows more irons and achondrites among known projectile types, and a preponderance of S-type objects, having no known meteoritic equivalent, among asteroids. It is not yet clear that these differences are significant, in view of the tentative nature of the crater identifications (achondrites in particular), and the limited statistics.