Isotopic age and metamorphic history of the banded gneiss at Danmarkshavn,East Greenland

Along the northern part of the East Greenland coast the Caledonian structures are superimposed on an older fold system called the Carolinidian. Traces of this Carolinidian belt are preserved in a few isolated fragments within the Caledonian fold belt. According to Haller (1970) one of these fragments exhibiting the typical Carolinidian NNW to NW-trending infrastructural folds is the peninsula of Germania Land which is accessible near the Danish weather station Danmarkshavn. The rock sampled there is a banded gneiss of granodioritic composition with steeply inclined, NNW-trending layers. Isotopic age determinations yielded essentially two groups of ages: 1) 3,000±150 m.y. (zircon suite and Rb/Sr whole rock analyses of layers) and 2) 320–380 m.y. (Rb/Sr mineral isochrons, U-Th-Pb on sphene, K/Ar on hornblende and biotite). The egg-shaped zircons support a sedimentary origin of the banded gneiss and in conjunction with the Rb/Sr whole rock ages determine the age of formation of the banded gneiss (or its last high grade metamorphism) some 3,000 m.y. ago. No other Precambrian metamorphism or orogeny is recorded in the rock. The ages between 320–380 m.y. date a thermal event of lower amphibolite facies grade related to a late Caledonian spasm.The new isotopic data reveal the existence of very old rocks in the hinterland — away from the direction of thrusting—of the East Greenland Caledonian belt. With respect to the age of the Carolinidian fold system three geological interpretations are compatible with the results of this study:

Uranium and lead gain of detrital zircon studied by isotopic analyses and fission-track mapping

Besides Pb and U loss and mixing of crystals of different age, U gain is considered a possible cause of discordant U-Pb ages of zircons. However, whether U gain without new zircon growth occurs in nature had not been proven, so far. In order to test this possibility, two detrital zircon populations were studied for which the absence of later zircon overgrowth after deposition could be demonstrated. The samples were separated from a metaquartzite near a large pegmatite body and from metaquartzite inclusions found in the pegmatite (Martell Valley, Italian Alps). The distribution of neutron-induced fission tracks reveals distinct accumulation of U in the rims of more than 90% of the zircon grains of the inclusions (total U in the crystals: 540–850 ppm), whereas in the country rock only some of the grains show similar but weaker patterns (total U: 155–320 ppm). From the isotopic data and from additional U-Pb and Rb-Sr analyses of minerals and whole-rock samples of the pegmatite, the marginal accumulation and the higher concentration of U in the zircon grains of the inclusions are interpreted as the result of episodic U gain during the intrusion of the pegmatite and/or during a later metamorphism. From the concentration levels of common Pb, an addition of Pb - and possibly other elements - to the zircon grains is inferred.     

Order-disorder relations in natural and heated rhomb porphyry plagioclases

Several plagioclase samples from core and rim of rhomb porphyry phenocrysts of the Oslo region were heated under dry conditions at 1050° C for 1, 10, 97, and 811 hours. X-ray powder photographs show that the structurally disordered to intermediate core and rim plagioclases crystallized under similar conditions. Between the slope of the [(2 ₁₃₁–2 _1¯31) vs. heating time]-curve and the potassium content in solid solution of these plagioclases exists the relation: the lower the K content, the steeper is the slope.Dr. Gorica Harnik-optrajanova, EMPA, Swiss Federal Laboratory for Testing Materials and Research, Überlandstraße 129, CH-8600 Dübendori, Switzerland.     

Paleozoic migmatites affected by high-grade tertiary metamorphism in the central Alps (Valle Bodengo,Italy)

The Lepontine Gneiss Complex of southern Switzerland and northern Italy is characterized by high-grade metamorphism and intensive deformation of Alpine age with migmatites prevalent in the area with the highest metamorphic grade. Petrological and structural observations are generally inconclusive but indicate in some places an Alpine age for the migmatite formation. To determine the time of migmatite formation a geochronologic study was undertaken in one of the best exposed areas, the Valle Bodengo, Italy. Rb-Sr whole-rock errorchrons of intrusive migmatite phases and of two rather homogeneous granitoid gneiss bodies yield apparent ages between 280 and 350 m.y. They suggest a Hercynian or older igneous history for these rocks. The U-Pb ages of the euhedral zircons are highly discordant, but they do point to the presence of zircon components more than 450 m.y. old. The concordia-intercept ages are incompatible with the Rb-Sr data and the low initial ⁸⁷Sr/⁸⁶Sr ratios of about 0.706. These low initial ratios suggest that either the bulk of the granitoid material is not much older than Hercynian, or older crustal material was isotopically homogenized on a regional scale with rocks that had low Rb/Sr and ⁸⁷Sr/⁸⁶Sr ratios (e.g. the lower crust or upper mantle) during a Hercynian metamorphism. Rb-Sr small-scale whole-rock isochrons and tie lines of adjacent, lithologically different rock phases give Alpine ages, the best isochron yielding 22 m.y. This coincides with concordant U-Pb ages of monazites of 23 to 24 m.y. Rb-Sr mineral isoohrons (muscovite, biotite, feldspars, apatite) give ages of 18–21 m.y. Our interpretation is that this age pattern resulted due to rapid cooling after the climax of the last phase of the Alpine metamorphism and we conclude that high-grade metamorphic conditions existed during the upper Oligocene or early Miocene. Other investigators have suggested that the Alpine metamorphism had a climax 35–40 m.y. ago and that the younger mineral ages are a result of simple continuous cooling due to uplift. Based on this study and other recent geochronological studies in the Lepotine Gneiss Complex we suggest that there had to be a thermal maximum at about 20–25 m.y. The example of Valle Bodengo demonstrates that the areal coincidence of the zone of highest-grade metamorphism with the occurrence of migmatites does not necessarily mean that metamorphism and migmatite formation were coeval and related to each other.     

Geochronology of a polymetamorphic and anatectic gneiss region: The moldanubicum of the area Lam-Deggendorf,eastern Bavaria,Germany

Rb-Sr isotopic analyses of whole-rocks and biotite and U-Th-Pb analyses of zircon and monazite reveal regional metamorphic events for the Ordovician (Caledonian metamorphism) and the Carboniferous (Variscan=Hercynian orogeny), both accompanied by anatexis. The extent of the Caledonian and Variscan anatexis, however, cannot be evaluated, so far, because the field petrographic criteria are not sufficient to distinguish clearly between early and late Paleozoic anatexites. Evidence for a Precambrian metamorphism has not been found. Rb-Sr whole-rock isochrons obtained on leucosomes and melanosomes of partially molten paragneisses are interpreted as a minimum age of the second, early Variscan anatexis. The alternative explanation of the isochrons as a result of local Sr isotopic redistribution without a melt involved is considered less likely. Concordant and nearly concordant zircon ages (318–335 m.y.) of a coarse-grained granite and of diatexites are regarded as evidence for an intensive early Variscan granitization and palingenesis. Concordant zircon ages of diorite dykes, crosscutting the anatexites, establish a lower time limit of 309–312 m.y. for the Variscan anatexis. Rb-Sr ages of biotite (310-290 m.y.) indicate the end of the Variscan metamorphism. Estimates of the time of sedimentation or diagenesis based on Rb-Sr whole-rock analyses for some metasediment series in the north of the area yield maximum ages of 550 m.y., provided that Rb and Sr migration did not exceed substantially the extent of the outcrops (30–500 m) between the time of diagenesis and the Ordovician metamorphism. Otherwise, an upper limit of 2000–2300 m.y., which is the primary age of detrital zircon populations, can be established. Zircon populations of paragneisses and their anatectic derivatives were separated into size and shape fractions. From morphologic studies and U-Pb isotopic analyses, they were found to be composites of young concordant (318–325 m.y.) and old, highly discordant zircon components, with more than fifty per cent of young crystals in some anatexites. The apparent ages of the composites are 320–750 m.y. The U concentrations of the newly formed crystals can be higher, equal, or lower than those of the inherited zircon component. Some peculiarities in the concordia plot of the zircon data of paragneisses and migmatites (curved pattern; inversion of the generally observed systematics with respect to U concentration, grain size, degree of discordance) are interpreted as the result of polyepisodic disturbances of the inherited crystals in connection with new zircon growth. In the concordia diagram, the data points of the individual zircon grains containing inherited components appear to plot in band or wedgelike areas, and not on lines as the patterns of size fractions of the same zircon populations could pretend. Consequently, ages obtained by extrapolation of the regression curves to the concordia are not necessarily meaningful and require verification by other methods.     

Age and origin of detrital zircons from the pre-Permian basements of the Bohemian Massif and the Alps

U-Pb isotopic analyses were made on detrital zircon populations from sandstones and quartzites of the pre-Permian basement in an attempt to shed light on the presedimentary history of the zircons and the age of their primary source rocks. Eight rock samples were collected from the Saxothuringian and Moldanubian parts of the Bohemian Massif, the western part of the Upper Austroalpine Nappes, and the Southern Alps. The heterogeneous populations were separated into fractions of different size, magnetic susceptibility, color, and shape. Because of their typically pitted surface all zircon grains from the sandstones and quartzites appear to be detrital. Only in three samples from the Alps—one from a contact metamorphic aureole—the zircons show surface recrystallization and minor new growth. With the exception of some euhedral crystals in the Saxothuringian quartzites all zircon fractions have highly discordant U-Pb ages. On a concordia diagram their data points scatter slightly around best-fit lines with upper intersections between 2000 and 2300 m.y. From this pattern the following conclusions are reached:

1. A large proportion of the material of the metasedimentary basement rocks in the Bohemian Massif as well as in the Alps derives from one or more sources, about 2000 to 2300 m.y. old.
2. The estimated proportion of detrital zircons with primary ages of 700 to 1500 m.y. is less than 10%.
3. The existence of a regional high-grade metamorphism in the Bohemian Massif as well as in the Alps during 700 to 1500 m.y. can be excluded. From Rb-Sr isotopic data, a metamorphism for the time prior to 1500 m.y. is very unlikely.

The lower intersections of the best-fit lines with the concordia curve cannot be clearly correlated with an episodic disturbance of the U-Pb systems during weathering and sedimentation and/or during regional metamorphism. For the zircons of the Bohemian Massif a disturbing event, about 550 to 600 m.y. ago, is likely. Clear, euhedral, but nevertheless detrital zircons found among the zircon populations of two Saxothuringian quartzites (“Plattenquarzit” of the pre-Ordovician “Arzberger Serie” and Lower Ordovician “FrauenbachQuarzit”) crystallized most probably during the Upper Proterozoic and/or the Assyntian petrogenesis. The highly discordant age pattern of the detrital zircons from the Alps is likely to be the result of the Caledonian and/or Hercynian (=Variscan) metamorphism. Differences in concentration levels of common lead in detrital zircons and the problem of red zircons as indicators of Precambrian origin are discussed.