Origins of high pH mineral waters from ultramafic rocks, Central Portugal

This paper reviews the geochemical, isotopic (²H, ¹⁸O, ¹³C, ³H and ¹⁴C) and numerical modelling approaches to evaluate possible geological sources of the high pH (11.5)/Na–Cl/Ca–OH mineral waters from the Cabeço de Vide region (Central-Portugal). Water–rock interaction studies have greatly contributed to a conceptual hydrogeological circulation model of the Cabeço de Vide mineral waters, which was corroborated by numerical modelling approaches. The local shallow groundwaters belong to the Mg–HCO₃ type, and are derived by interaction with the local serpentinized rocks. At depth, these type waters evolve into the high pH/Na–Cl/Ca–OH mineral waters of Cabeço de Vide spas, issuing from the intrusive contact between mafic/ultramafic rocks and an older carbonate sequence. The Cabeço de Vide mineral waters are supersaturated with respect to serpentine indicating that they may cause serpentinization. Magnesium silicate phases (brucite and serpentine) seem to control Mg concentrations in Cabeço de Vide mineral waters. Similar δ²H and δ¹⁸O suggest a common meteoric origin and that the Mg–HCO₃ type waters have evolved towards Cabeço de Vide mineral waters. The reaction path simulations show that the progressive evolution of the Ca–HCO₃ to Mg–HCO₃ waters can be attributed to the interaction of meteoric waters with serpentinites. The sequential dissolution at CO₂ (g) closed system conditions leads to the precipitation of calcite, magnesite, amorphous silica, chrysotile and brucite, indicating that the waters would be responsible for the serpentinization of fresh ultramafic rocks (dunites) present at depth. The apparent age of Cabeço de Vide mineral waters was determined as 2790 ± 40 a BP, on the basis of ¹⁴C and ¹³C values, which is in agreement with the ³H concentrations being below the detection limit.     

Geomorphological evidence for upslope canyon-forming processes on the northern KwaZulu-Natal shelf,SW Indian Ocean,South Africa

A geomorphological and statistical analysis of slope canyons from the northern KwaZulu-Natal continental margin is documented and compared with submarine canyons from the Atlantic margin of the USA. The northern KwaZulu-Natal margin is characterized by increasing upslope relief, concave slope-gradient profiles and features related to upslope growth of the canyon forms. Discounting slope-gradient profile, this morphology is strikingly similar to canyon systems of the New Jersey slope. Several phases of canyon incision indicate that downslope erosion is also an important factor in the evolution of the northern KwaZulu-Natal canyon systems. Despite the strong similarities between the northern KwaZulu-Natal and New Jersey slope-canyon systems, key differences are evident: (1) the concavity of the northern KwaZulu-Natal slope, contrasting with the ∼linear New Jersey slope; (2) the relative isolation of the northern KwaZulu-Natal canyons, rather than the dense clustering of the New Jersey canyons; and (3) the absence of strongly shelf-breaching canyons along the northern KwaZulu-Natal margin. In comparison with the New Jersey margin, we surmise a more youthful stage of canyon evolution, a result of either the canyons themselves being younger or the formative processes being less active. Less complicated patterns of erosion resulting from reduced sediment availability have developed in northern KwaZulu-Natal. The reduction in slope concavity on the New Jersey margin may be the result of grading of the upper slope by intensive headward erosion, a process more subdued—or less evident—on the KwaZulu-Natal margin.     

Application of environmental groundwater tracers at the Sulphur Bank Mercury Mine, California, USA

Boron, chloride, sulfate, δD, δ¹⁸O, and ³H concentrations in surface water and groundwater samples from the Sulphur Bank Mercury Mine (SBMM), California, USA were used to examine geochemical processes and provide constraints on evaporation and groundwater flow. SBMM is an abandoned sulfur and mercury mine with an underlying hydrothermal system, adjacent to Clear Lake, California. Results for non-³H tracers (i.e., boron, chloride, sulfate, δD, and δ¹⁸O) identify contributions from six water types at SBMM. Processes including evaporation, mixing, hydrothermal water input and possible isotopic exchange with hydrothermal gases are also discerned. Tritium data indicate that hydrothermal waters and other deep groundwaters are likely pre-bomb (before ~1952) in age while most other waters were recharged after ~1990. A boron-based steady-state reservoir model of the Herman Impoundment pit lake indicates that 71–79% of its input is from meteoric water with the remainder from hydrothermal contributions. Results for groundwater samples from six shallow wells over a 6–month period for δD and δ¹⁸O suggests that water from Herman Impoundment is diluted another 3% to more than 40% by infiltrating meteoric water, as it leaves the site. Results for this investigation show that environmental tracers are an effective tool to understand the SBMM hydrogeologic regime.

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Résumé Les concentrations en bore, chlorure, sulfate, δD, δ¹⁸O, et ³H d’échantillons d’eaux de surface et souterraine prélevés dans le banc de soufre de la mine de mercure (SBMM en anglais) en Californie, USA, ont été utilisées pour étudier les processus géochimiques et pour fournir des contraintes à l’évaporation et à l’écoulement des eaux souterraines. La SBMM est une mine de soufre et de mercure abandonnée, adjacente au lac Clear en Californie et sous laquelle se trouve un système hydrothermal.Les résultats des traceurs autres que le tritium (bore, chlorure, sulfate, δD, et δ¹⁸O) ont permis d’identifier des contributions de six types d’eaux à SBMM. Des processus tels que l’évaporation, le mélange, l’entrée d’eau hydrothermale et de possibles échanges isotopiques avec des gaz hydrothermaux ont également été identifiés. Les données de tritium montrent que les eaux hydrothermales et d’autres eaux profondes sont probablement d’age antérieure à la bombe (avant ~1952), alors que la plupart des autres eaux sont issues de la recharge après ~1990. Un modèle de réservoir représentant le lac situé dans la partie Herman Impoundment de l’ancienne mine, en régime permanent et basé sur le bore, montre que 71–79% de l’eau provient des précipitations, le reste provenant de contributions hydrothermales. Les résultats de δD et δ¹⁸O pour des échantillons d’eau souterraine de six puits peu profonds sur une période de 6 mois suggèrent que l’eau de Hermann Impoundment est encore diluée entre 3% jusqu’à plus de 40% lorsqu’elle quitte le site du fait de l’infiltration d’eau météorique. Les résultats de cette étude montrent que les traceurs environnementaux constituent un outil efficace pour comprendre le régime hydrogéologique de la SBMM.

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Resumen Se han utilizado datos de concentraciones de boro, cloruros, sulfatos, δD, δ¹⁸O, y ³H en muestras de aguas superficiales y subterráneas procedentes de la Mina de Mercurio Sulphur Bank (SBMM), California, USA, para estudiar los procesos geoquímicos y caracterizar la evaporación y el flujo del agua subterránea. SBMM es una mina abandonada de azufre y mercurio con un sistema hidrotermal subyacente, cercano al Lago Clear, California.Los resultados de los trazadores que no son ³H (por ejemplo, boro, cloruros, sulfatos δD, y δ¹⁸O) identifican las contribuciones de seis tipos de agua en la SBMM. Se han identificado diversos procesos, como evaporación, mezcla, entrada de agua hidrotermal y la posibilidad de intercambios isotópicos con gases hidrotermales. Los datos de tritio indican que las aguas hidrotermales y otras aguas subterráneas profundas son probablemente pre-bombas (previas a ~1952) en edad mientras que la mayoría de las otras aguas se han recargado después de ~1990. Un modelo estacionario basado en el boro de la fosa del lago Herman Impoundment indica que el 71–79% de su entrada procede de agua meteórica con restos de contribución hidrotermal. Los resultados para las muestras de aguas subterráneas procedentes de seis pozos superficiales en un periodo de 6 meses para δD y δ¹⁸O sugieren que el agua procedente de Herman Impoundment se diluye en otro 3% hasta más del 40% debido a la infiltración de agua meteórica., que sale del sitio. Los resultados de esta investigación muestran que los trazadores ambientales son una herramienta efectiva para entender el régimen hidrogeológico de la SBMM.

     

An ephemeral turbidity maximum generated by resuspension of organic-rich matter in a macrotidal estuary, S.W. Wales

An ephemeral estuarine turbidity maximum (ETM) occurs at high water in the macrotidal Taf estuary (SW Wales, United Kingdom). A new mechanism of ETM formation, due to resuspension and advection of material by flood tidal currents, is observed that differs from classical mechanisms of gravitational circulation and tidal pumping. The flood tide advances across intertidal sand flats in the main body of the estuary, progressively entraining material from the rippled sands. Resuspension creates, a turbid front that has suspended sediment concentrations (SSC) of about 4,000 mg I⁻¹ by the time it reaches its landward limit which is also the landward limit of salt penetration. This turbid body constitutes the ETM. Deposition occurs at high slack water but the ETM retains SSC values up to 800 mg I⁻¹, 1–2 orders of magnitude greater than ambient SSC values in the river and estuarine waters on either side. The ETM retreats down the estuary during the ebb; some material is deposited thinly across emergent intertidal flats and some is flushed out of the estuary. A new ETM is generated by the next flood tide. Both location and SSC of the ETM scale on Q/R³ where Q is tidal range and R is river discharge. The greatest expression of the ETM occurs when a spring tide coincides with low river discharge. It does not form during high river discharge conditions and is poorly developed on neap tides. Particles in the ETM have effective densities (120–160 kg m⁻³) that are 3–4 times less than those in the main part of the estuary at high water. High chlorophyll concentrations in the ETM suggest that flocs probably originate from biological production in the estuary, including production on the intertidal sand flats.     

The Elusive AD 1826 Tsunami, South Westland, New Zealand

In AD 1826 sealers reported earthquake and tsunami activity in Fiordland, although, contemporary or near‐contemporary accounts of tsunami inundation at the time are elusive. A detailed analysis of recent sediments from Okarito Lagoon builds on contextual evidence provided by earlier research concerning past tsunami inundation. Sedimentological, geochemical, micropalaeontological and geochronological data are used to determine palaeoenvironments before, during and after what was most probably tsunami inundation in AD 1826. The most compelling chronological control is provided fry a young cohort of trees growing on a raised shoreline bench stranded fry a drop in the lagoon water level following tsunami inundation.     

The origins of marine and non-marine boulder deposits: a brief review

Natural Hazards - We identify 14 mechanisms, marine and non-marine, one man made, that result and could result in the formation of boulder deposits after reviewing issues associated with clast...     

The Eltanin asteroid impact: possible South Pacific palaeomegatsunami footprint and potential implications for the Pliocene–Pleistocene transition

Large asteroid impacts are rare, and those into the deep ocean are rarer still. The Eltanin asteroid impact around 2.51 ± 0.07 Ma occurred at a time of great climatic and geological change associated with the Pliocene–Pleistocene boundary. Numerical models of the event indicate that a megatsunami was generated, although there is debate concerning its magnitude and the region‐wide extent of its influence. We summarise the existing evidence for possible Eltanin megatsunami deposits in Antarctica, Chile and New Zealand, while also examining other potential sites from several locations, mainly around the South Pacific region. In reviewing these data we note that these events were unfolding at the same time as those associated with the Pliocene–Pleistocene boundary and, as such, most of the geological evidence from that time has a climatic interpretation. The potential climatic and geological ramifications of the Eltanin asteroid impact, however, have failed to be considered by most researchers studying this time period. Although we are not advocating that all geological activity at that time is connected with the Eltanin asteroid impact, it raises interesting questions about the role potentially played by such catastrophic events in contributing to or even triggering epochal transitions. Copyright © 2012 John Wiley & Sons, Ltd.     

On the significance of aragonite occurrences in the Western Alps

Aragonite occurrences from two areas of the Western Alps are described. It is shown that aragonite has been formed under blueschist metamorphic conditions in the Western Vanoise, while it has been precipitated under sub-surface conditions in the Queyras region. An uplift (P, T) path of the aragonite-bearing rocks of the Western Vanoise is constructed using two independent methods: (1) temperature estimates using the Sr⁺⁺ content of aragonite in the successive veins and (2) the kinetics of the aragonitecalcite solid-state transition. The uplift (P, T) path has an unusual shape with an important temperature decrease (100° to 150° C for a pressure decrease of 0.2 GPa) following blueschists metamorphism (P=0.7 GPa, T=300° C). Thermal models show that this unusual (P, T) path of the Western Vanoise can be explained if one maintains a low temperature (between 125° and 175° C) at the base of the tectonic unit containing the aragonite-bearing rocks during part of its burial history, followed by the whole of its exhumation. A tectonic scenario is proposed to account for the observed and modelled (P, T) path.     

Gravel transport and morphological change in braided sunwapta river,Alberta, Canada

The relation between morphological change and patterns of variation in bedload transport rate in braided streams was observed by repeated, daily topographic surveys over a 25 day study period in a 60 m reach of the proglacial Sunwapta River, Alberta, Canada. There are two major periods of morphological change, each lasting several days and each involving the complete destruction and reconstruction of bar complexes. Bar complex destruction was caused by redirection of the flow and by downstream extension of the confluence scour zone upstream. Reconstruction involved accretion of unit bars on bar head, flank and tail and in one case was initiated by disection of a large, lobate unit bar. High rates of sediment movement, measured from net scour and fill of the cross-sections, coincided with these morphological changes. Sediment was supplied from both bed and bank erosion, and patterns and distances of transfer were highly variable. Rates of transport estimated by matching upstream erosional volumes with downstream deposition were much greater than those estimated from either a step-length approach or a sediment budget. Measurements of scour and fill and observations of morphological change indicate that step lengths (virtual transport distances) were typically 40–100m during a diurnal discharge cycle. Shorter step lengths occurred when transfer was confined to a single anabranch and longer steps involved channel changes at the scale of the entire reach. Sediment budgeting was used to describe the spatial patterns of sediment transport associated with the morphological changes and to estimate minimum daily reach-averaged transport rates. Mean bedload transport rates correlate with discharge, but with considerable scatter. The largest deviations from the mean relation can be tied to phases of channel incision, bank erosion, scour hole migration, bar deposition and channel filling apparently controlled by changes and fluctuations in sediment supply from upstream, independent of discharge. These are interpreted as field evidence of ‘autopulses’ or ‘macropulses’ in bedload transport, previously observed only in laboratory models of braided streams.     

Geothermobarometry in albite-garnet orthogneisses: A case study from the Gran Paradiso nappe (Western Alps)

The aim of this paper is to estimate syntectonic P-T conditions within albite- and garnet-bearing orthogneisses. These rocks are generally characterized by the assemblage quartz + albite + biotite + phengite + CaFe-garnet + epidote + titanite. Garnet contains up to 55 mole per cent of grossular. K-feldspar is a relict magmatic phase.

P-T conditions are estimated using several independent methods. First, it is shown that exchange reactions based on the Fe---Mg partitioning between garnet and biotite or garnet and phengite cannot be used to estimate temperatures in these rocks, due to the high grossular content of garnet. Second, maximum and minimum pressures are constrained, respectively, by the occurrence of albite instead of jadeite + quartz and by the assemblage phengite + biotite + quartz. Third, phase equilibria in albite- and garnet-bearing metagranites are modelled in the system K₂O---CaO---FeO---Al₂O₃---SiO₂---H₂O. Equilibrium curves are calculated for the observed phase compositions. Uncertainties in P-T estimates mainly result from the choice of appropriate non-ideal solution models for the garnet.

An application is developed for granites from the Gran Paradiso nappe (Western Alps). These granites show an heterogeneous deformation of Alpine age expressed by mylonitic shear zones cutting across weakly deformed domains. Estimated P-T conditions for the synkinematic assemblages are 10–16 kbar at 550±50°C.