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The phenomenon of volcanic fallout ash from Mt. Etna in Sicily (Italy) is well known and frequent in recent years, as in the period 2001–2004. As a consequence, significant problems for the population, road, rail and air traffic and production activities have occurred. The industrial areas of Catania and Augusta-Priolo, located in south eastern Sicily, might be involved during particular weather conditions. This paper aims at determining the potential scenarios of damage to industrial facilities caused by volcanic ash fallout. The work has been focused on the study of both fixed and floating roof storage tanks, containing flammable liquids, and examines extreme failures damage causing the greatest loss of containment for these facilities. To include scenarios arising from natural phenomena (Na-Tech events) in the standard risk assessment procedure, the estimation of the vulnerability of these facilities is necessary. The study has been applied to the area surrounding Mt. Etna, and the procedure can also be extended to other case studies.  相似文献   
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