Site effects of the Roio basin, L��Aquila

During the microzonation studies of the April 6th, 2009 L??Aquila earthquake, we observed local seismic amplifications in the Roio area??a plane separated from L??Aquila city center by mount Luco. Six portable, digital instruments were deployed across the plain from 15 April to mid-May 2009. This array recorded 152 aftershocks. We analyzed the ground motion from these events to determine relative site amplification within the plain and on surrounding ridges. Horizontal over vertical spectral ratio on noise data (HVSRN), aftershock recordings (HVEQ) and standard spectral ratio (SSR) showed amplifications at 1.3 and 4.0?Hz on quaternary deposits. Seismic amplifications in the frequency range of 4 and 6?Hz were also observed on a carbonate ridge of Colle di Roio, on the northwestern border of the plateau. A small amplification was noticed near the top of mount Luco, another rocky site. Large discrepancies in the amplification levels between methods have been observed for these sites, but the HVSRN, HVEQ and SSR gave similar results at the stations located in the Roio plain. On the rocky sites, the SSR was more reliable than the HVSRN at estimating the transfer function of the site, even if the resonance frequency seemed to be well detected by the latter method.     

Seismic response of L��Aquila downtown from comparison between 2D synthetics spectral ratios of SH, P-SV and Rayleigh waves and observations of the 2009 earthquake sequence

This is the first part of a study on the seismic response of the L’Aquila city using 2D simulation and experimental data. We have studied two velocity-depth models with the aim of outlining the behavior of a velocity reversal in the top layer, which is associated with the stiff Brecce de L’Aquila unit (BrA). In this setting, the SMTH model is topped by a layer with about 2:1 impedance contrast with the underlying layer while the NORV model has no velocity reversal. We have simulated the propagation of SH and P-SV wavefields in the range 0–10 Hz for incidence 0°–90°. Earthquake spectral ratios of the horizontal and vertical components at six sites in L’Aquila downtown are compared to corresponding synthetics spectral ratios. The vertical component of P-SV synthetics enables us to investigate a remarkable amplification effect seen in the vertical component of the recorded strong motion. Sites AQ04 and AQ05 are best matched by synthetics from the NORV model while FAQ5 and AQ06 have a better match with synthetics spectral ratios from the SMTH model. All simulations show this behavior systematically, with horizontal and near-horizontal incident waves predicting the overall pattern of matches more clearly than vertical and near-vertical incidence. The model inferences are in agreement with new geological data reporting lateral passages in the top layer from the stiff BrA to softer sediments. Matches are good in terms of frequency of the first amplification peak and of spectral amplitude: the horizontal components have spectral ratio peaks predominantly at 0.5 Hz in the simulations and at 0.7 Hz in the data, both with amplitudes of 4, while the vertical component spectral ratios reach values of 6 at frequencies of about 1 Hz in both data and simulations. The vertical component spectral ratios are very well matched using Rayleigh waves with incidence at 90°. The NORV model without the velocity reversal predicts spectral ratio peaks for the horizontal components at frequencies up to 6 Hz. The reversal of velocity acts as a low-pass frequency filter on the horizontal components reducing the amplification effect of the sediment filled valley.     

Some chemical characteristics of the brines in Bannock and Tyro Basins: salinity, sulphur compounds, Ca, F, pH, At, PO4, SiO2, NH3

Results of the chemical investigation on the Bannock and Tyro Basins are reported.Both basins were found to be hypersaline ( 10 times higher than salinity of normal seawater) and anoxic. In all investigated basins a region of transition, a few meters thick, was identified at depths > 3327 dbar. It is characterized by a sharp gradient of salinity, and all concentrations of analysed species increase strongly except for dissolved oxygen and nitrate, which immediately drop to zero. This region appears as a sharp boundary that prevents mixing. As a result, in the presence of organic matter, an anoxic condition developed with the complete depletion of dissolved oxygen. At the same time, hydrogen sulphide and ammonium accumulated within the brine. Between the Bannock and the Tyro brines differences occur in the measured concentrations of H₂S, SO²⁻₄, Ca²⁺ and NH₃. There are some differences also within the Bannock area sub-basins.The Libeccio sub-basin, in the Bannock area, contains a double-layered brine: the upper layer is 140 dbar thick and the lower layer is 300 dbar thick. A second interface between upper and lower brines develops at a depth of 3500 dbar. Nearly all of the measured concentrations vs. depth show the double layer, with the exception of ammonium, the concentration of which remains nearly constant throughout the anoxic column. Profiles of the other species analyzed show remarkable differences on passing from the upper to the lower brine. Hydrogen sulphide, sulphate and fluoride concentrations appear constant and then increase at the second interface. The calcium concentration is also constant in the upper brine, but decreases at the second interface. Total alkalinity and phosphate concentrations show a maximum peak just below the first interface. However, after passing through the second interface all the chemical parameters exhibit an almost constant behaviour down to the bottom.Hypersaline conditions are attributed to the dissolution of Messinian evaporite, and anoxia is suggested to originate from the oxidation of organic matter present in sediments and from the absence of bottom water circulation in such a deep and enclosed environment.The chemical conditions can be summarized as follows: in the Libeccio Basin the values for the species analysed have the ranges: 39–321 psu for ‘salinity’, 8.2−6.5 for pH, 2.7–4.0 mM for total alkalinity, 0.2-0 mM for dissolved oxygen, 0–1669 μM for hydrogen sulphide, 0–198 μM for thiol, 31–99 mM for sulphate, 11–21 mM for calcium, 7–100 μM for fluoride, 0.2–3080 μM for ammonium, 5.8-0 μM for nitrite, 0.2–12 μM for phosphate and 8–130 μM for silicate.     

Oxidative stress in two populations of killifish (Fundulus heteroclitus) with differing contaminant exposure histories

A population of killifish (Fundulus heteroclitus) inhabiting a creosote-polluted inlet of the Elizabeth River demonstrates tolerance to the acute toxic effects exerted by contaminated sediments on reference site killifish. Previous data have suggested that upregulated antioxidant defenses contribute to short-term tolerance in killifish exposed to Elizabeth River sediments. This study investigated population differences in antioxidant defenses from wild caught Elizabeth River and reference population killifish in different seasons, and after being held in the laboratory. Parameters measured in the killifish were total glutathione concentrations (GSH(T)), activities of glutathione reductase (GR), glutathione peroxidase (GPx), and lipid peroxidation (LPO), all in adult hepatic tissues. The Elizabeth River population exhibited greater GSH(T), higher GPx activities, and increased LPO as compared to the reference population. Sex specific population differences were also observed in GSH(T) and GPx. Both populations displayed decreased GSH(T) and increased GR from early to late summer, as well as after being held in the laboratory. This study indicates that there are many factors that may contribute to differences in levels of antioxidant defenses in addition to exposure to contaminants, including reproductive status and environmental conditions.     

BIFoR FACE: Water–soil–vegetation–atmosphere data from a temperate deciduous forest catchment,including under elevated CO2

The ecosystem services provided by forests modulate runoff generation processes, nutrient cycling and water and energy exchange between soils, vegetation and atmosphere. Increasing atmospheric CO₂ affects many linked aspects of forest and catchment function in ways we do not adequately understand. Global levels of atmospheric CO₂ will be around 40% higher in 2050 than current levels, yet estimates of how water and solute fluxes in forested catchments will respond to increased CO₂ are highly uncertain. The Free Air CO₂ Enrichment (FACE) facility of the University of Birmingham's Institute of Forest Research (BIFoR) is the only FACE in mature deciduous forest. The site specializes in fundamental studies of the response of whole ecosystem patches of mature, deciduous, temperate woodland to elevated CO₂ (eCO₂). Here, we describe a dataset of hydrological parameters – seven weather parameters at each of three heights and four locations, shallow soil moisture and temperature, stream hydrology and CO₂ enrichment – retrieved at high frequency from the BIFoR FACE catchment.     

Geochronological constraints on the evolution of the Periadriatic Fault System (Alps)

Fault rocks from various segments of the Periadriatic fault system (PAF; Alps) have been directly dated using texturally controlled Rb-Sr microsampling dating applied to mylonites, and both stepwise-heating and laser-ablation ⁴⁰Ar/³⁹Ar dating applied to pseudotachylytes. The new fault ages place better constraints on tectonic models proposed for the PAF, particularly in its central sector. Along the North Giudicarie fault, Oligocene (E)SE-directed thrusting (29-32 Ma) is currently best explained as accommodation across a cogenetic restraining bend within the Oligocene dextral Tonale-Pustertal fault system. In this case, the limited jump in metamorphic grade observed across the North Giudicarie fault restricts the dextral displacement along the kinematically linked Tonale fault to ~30 km. Dextral displacement between the Tonale and Pustertal faults cannot be transferred via the Peio fault because of both Late Cretaceous fault ages (74-67 Ma) and sinistral transtensive fault kinematics. In combination with other pseudotachylyte ages (62-58 Ma), widespread Late Cretaceous-Paleocene extension is established within the Austroalpine unit, coeval with sedimentation of Gosau Group sediments. Early Miocene pseudotachylyte ages (22-16 Ma) from the Tonale, Pustertal, Jaufen and Passeier faults argue for a period of enhanced fault activity contemporaneous with lateral extrusion of the Eastern Alps. This event coincides with exhumation of the Penninic units and contemporaneous sedimentation within fault-bound basins.     

The DAV and Periadriatic fault systems in the Eastern Alps south of the Tauern window

Alpine deformation of Austroalpine units south of the Tauern window is dominated by two kinematic regimes. Prior to intrusion of the main Periadriatic plutons at ~30 Ma, the shear sense was sinistral in the current orientation, with a minor north-side-up component. Sinistral shearing locally overprints contact metamorphic porphyroblasts and early Periadriatic dykes. Direct Rb-Sr dating of microsampled synkinematic muscovite gave ages in the range 33-30 Ma, whereas pseudotachylyte locally crosscutting the mylonitic foliation gave an interpreted ⁴⁰Ar-³⁹Ar age of ~46 Ma. The transition from sinistral to dextral (transpressive) kinematics related to the Periadriatic fault occurred rapidly, between solidification of the earlier dykes and of the main plutons. Subsequent brittle-ductile to brittle faults are compatible with N-S to NNW-SSE shortening and orogen-parallel extension. Antithetic Riedel shears are distinguished from the previous sinistral fabric by their fine-grained quartz microstructures, with local pseudotachylyte formation. One such pseudotachylyte from Speikboden gave a ⁴⁰Ar-³⁹Ar age of 20 Ma, consistent with pseudotachylyte ages related to the Periadriatic fault. The magnitude of dextral offset on the Periadriatic fault cannot be directly estimated. However, the jump in zircon and apatite fission-track ages establishes that the relative vertical displacement was ~4-5 km since 24 Ma, and that movement continued until at least 13 Ma.     

Mineralisation of amethyst-bearing geodes in Ametista do Sul (Brazil) from low-temperature sedimentary brines: evidence from monophase liquid inclusions and stable isotopes

Fluid inclusion studies in combination with hydrogen, oxygen and sulphur isotope data provide novel insights into the genesis of giant amethyst-bearing geodes in Early Cretaceous Paraná continental flood basalts at Amestita do Sul, Brazil. Monophase liquid inclusions in colourless quartz, amethyst, calcite, barite and gypsum were analysed by microthermometry after stimulating bubble nucleation using single femtosecond laser pulses. The salinity of the fluid inclusions was determined from ice-melting temperatures and a combination of prograde and retrograde homogenisation temperatures via the density maximum of the aqueous solutions. Four mineralisation stages are distinguished. In stage I, celadonite, chalcedony and pyrite formed under reducing conditions in a thermally stable environment. Low δ³⁴S_V-CDT values of pyrite (?25 to ?32?‰) suggest biogenic sulphate reduction by organotrophic bacteria. During the subsequent stages II (amethyst, goethite and anhydrite), III (early subhedral calcite) and IV (barite, late subhedral calcite and gypsum), the oxidation state of the fluid changed towards more oxidising conditions and microbial sulphate reduction ceased. Three distinct modes of fluid salinities around 5.3, 3.4 and 0.3 wt% NaCl-equivalent characterise the mineralisation stages II, III and IV, respectively. The salinity of the stage I fluid is unknown due to lack of fluid inclusions. Variation in homogenisation temperatures and in δ¹⁸O values of amethyst show evidence of repeated pulses of ascending hydrothermal fluids of up to 80–90 °C infiltrating a basaltic host rock of less than 45 °C. Colourless quartz and amethyst formed at temperatures between 40 and 80 °C, while the different calcite generations and late gypsum precipitated at temperatures below 45 °C. Calculated oxygen isotope composition of the amethyst-precipitating fluid in combination with δD values of amethyst-hosted fluid inclusions (?59 to ?51?‰) show a significant ¹⁸O-shift from the meteoric water line. This ¹⁸O-shift, high salinities of the fluid inclusions with chloride-sulphate composition, and high δ³⁴S values of anhydrite and barite (7.5 to 9.9?‰) suggest that sedimentary brines from deeper parts of the Guaraní aquifer system must have been responsible for the amethyst mineralisation.     

1D velocity structure of the Po River plain (Northern Italy) assessed by combining strong motion and ambient noise data

Strong ground motions recorded on the sedimentary deposits of the Po River alluvial plain during the Emilia (Northern Italy) Mw 5.7 earthquake of May 29, 2012 are used to assess the vertical profile of shear-wave velocity above the limestone basement. Data were collected by a linear array installed for site effect studies after the Mw 5.9 mainshock of May 20, 2012. The array stations, equipped with both strong and weak motion sensors, are aligned in the South–North direction, at distances ranging from 1 to 26 km from the epicenter. The vertical components of ground motion show very distinctive, large-amplitude, low-frequency dispersive wave trains. Wavelet analysis yields group-velocity dispersion curve in the 0.2–0.7 Hz frequency band. The availability of a long ambient noise record allows estimates of the site resonance frequency along with its stability among stations. The joint inversion of dispersion of surface waves and ellipticity curves derived from ambient noise H/V allows extending investigations down to the sediment-limestone interface, at a depth of about 5,000 m. Our results add new information about the velocity structure at a scale that is intermediate between the local scale already investigated by other authors with small-aperture arrays using ambient noise and the regional scale inferred from modeling of seismogram waveforms recorded at hundreds of kilometers from the source.