A Laboratory and Theoretical Study on the Uptake of SO2 Gas by Large and Small Water Drops Containing Heavy Metal Ions

Laboratory experiments have been carried out to investigate the uptake of sulfur dioxide by water drops containing heavy metal ions where the metal ions serve as catalysts to oxidise the taken up S(IV) into S(VI). During the gas uptake the drops were freely suspended at their terminal velocity in the airstream of the Mainz vertical wind tunnel. Two series of experiments were carried out, one with large millimeter size water drops containing manganese or iron ions, and the other with small water drops containing manganese ions and having radii in hundreds of micron size range. The experimental results were compared against model computations using the Kronig–Brink model and the fully mixed model, modified for the case that heavy metal ions present in the liquid phase act as catalysts for the oxidising process. The results of the model calculations show that there are only small differences between the predicted gas uptake according to the two models. In addition it was found that the experimental obtained results from the uptake of SO₂ by water drops containing heavy metal ions for both, large and small water drops did agree with the model results.     

http://www.sciencedirect.com/science/article/pii/S1674987114000437

The Pranhita-Godavari Basin in central eastern India is one of the Proterozoic "Purana" basins of cratonic India.New geochronology demonstrates that it has a vast depositional history of repeated basin reactivation from the Palaeoproterozoic to the Mesozoic.U-Pb laser ablation inductively coupled plasma mass spectrometry dating of detrital zircons from two samples of the Somanpalli Group—a member of the oldest sedimentary cycle in the valley-constrains its depositional age to ~1620 Ma and demonstrates a tripartite age provenance with peaks at ~3500 Ma,~2480 Ma and ~1620 Ma,with minor age peaks in the Eoarchaean(~3.8 Ga) and at ~2750 Ma.These ages are consistent with palaeocurrent data suggesting a southerly source from the Krishna Province and Enderby Land in East Antarctica.The similarity in the maximum depositional age with previously published authigenic glauconite ages suggest that the origin of the Pranhita-Godvari Graben originated as a rift that formed at a high angle to the coeval evolving late Meosproterozoic Krishna Province as Enderby Land collided with the Dharwar craton of India.In contrast,detrital zircons from the Cycle III Sullavai Group red sandstones yielded a maximum depositional age of 970±20 Ma and had age peaks of ~2550 Ma,~1600 Ma and then a number of Mesoproterozoic detrital zircons terminating in three analyses at ~970 Ma.The provenance of these is again consistent with a southerly source from the Eastern Ghats Orogen and Antarctica.Later cycles of deposition include the overlying Albaka/Usur Formations and finally the late Palaeozoic to Mesozoic Gondwana Supergroup.     

Spatial-Correlation Based Persistent Scatterer Interferometric Study for Ground Deformation

Interferometric Synthetic Aperture Radar (InSAR), nowadays, is a precise technique for monitoring and detecting ground deformation at a millimetric level over large areas using multi-temporal SAR images. Persistent Scatterer Interferometric SAR (PSInSAR), an advanced version of InSAR, is an effective tool for measuring ground deformation using temporally stable reference points or persistent scatterers. We have applied both PSInSAR and Small Baseline Subset (SBAS) methods, based on the spatial correlation of interferometric phase, to estimate the ground deformation and time-series analysis. In this study, we select Las Vegas, Nevada, USA as our test area to detect the ground deformation along satellite line-of-sight (LOS) during November 1992–September 2000 using 44 C-band SAR images of the European Remote Sensing (ERS-1 and ERS-2) satellites. We observe the ground displacement rate of Las Vegas is in the range of ?19 to 8 mm/year in the same period. We also cross-compare PSInSAR and SBAS using mean LOS velocity and time-series. The comparison shows a correlation coefficient of 0.9467 in the case of mean LOS velocity. Along this study, we validate the ground deformation results from the satellite with the ground water depth of Las Vegas using time-series analysis, and the InSAR measurements show similar patterns with ground water data.     

Shallow lithosphere-asthenosphere boundary beneath Cambay Rift Zone of India: Inferred presence of carbonated partial melt

A vast area between Phalodi in Jodhpur and Pokaran in Jaisalmer district of western Rajasthan, is occupied distinctly by rocky, shallow gravelly surfaces and occasional hills. These surfaces exhibit quartz and quartzite pebbles, angular, sub-angular and few rounded sandstone gravels, have slightly convex outline and can be best described as desert pavements. Such land features assume significance because of their extent and variability under a dominantly dry aeolian environment. Morphology and distributional pattern of such formations indicate that sediments are either of in situ origin or may have been transported to a short distance. The present study is based on field level assessment of such surfaces in the above two desert districts. Over much of the area, the profile shows a surficial concentration of gravels followed by thick sand and silt mixed with gravels and then the parent material. There are also occasional rock outcrops of very low relief exhibiting vertical, horizontal and conchoidal pattern of fractures over these surfaces near Pokaran and north of Jaisalmer which indicate disintegration of rocks under extreme diurnal fluctuation of temperature. Such manifestations in the morphology indicate impact of both thermal as well as aeolian processes. In the east of Jaisalmer town near Basanpir and Bhojka, the pavement surfaces are found covered with abundant sub-rounded to rounded pebbles and cobbles. This type of condition would indicate a profound action by fluvial activities followed by wind sorting. Our study found significant spatial variability in the distribution of pavement surfaces, which carried imprints of climatic fluctuations and environment of deposition during Holocene.     

Drought analysis in the Tons River Basin,India during 1969-2008

The primary focus of this study is the analysis of droughts in the Tons River Basin during the period 1969–2008. Precipitation data observed at four gauging stations are used to identify drought over the study area. The event of drought is derived from the standardized precipitation index (SPI) on a 3-month scale. Our results indicated that severe drought occurred in the Allahabad, Rewa, and Satna stations in the years 1973 and 1979. The droughts in this region had occurred mainly due to erratic behavior in monsoons, especially due to long breaks between monsoons. During the drought years, the deficiency of the annual rainfall in the analysis of annual rainfall departure had varied from ?26% in 1976 to ?60% in 1973 at Allahabad station in the basin. The maximum deficiency of annual and seasonal rainfall recorded in the basin is 60%. The maximum seasonal rainfall departure observed in the basin is in the order of ?60% at Allahabad station in 1973, while maximum annual rainfall departure had been recorded as ?60% during 1979 at the Satna station. Extreme dry events (z score <?2) were detected during July, August, and September. Moreover, severe dry events were observed in August, September, and October. The drought conditions in the Tons River Basin are dominantly driven by total rainfall throughout the period between June and November.     

Mixed boundary value problem in an elastic quarter-space

Summary The stress and displacement throughout a homogeneous, isotropic, elastic quarterspace have been evaluated when the stress is prescribed on one of the plane boundaries and the displacement on the other. The variations of the displacement and stress on the boundaries with time and distance from the origin have been shown graphically.     

Reliability Analysis of Earth Slopes Considering Spatial Variability

The paper presents a computational procedure for reliability analysis of earth slopes considering spatial variability of soils under the framework of the Limit Equilibrium Method. In the reliability analysis of earth slopes, the effect of spatial variability of soil properties is generally included indirectly by assuming that the probabilistic critical slip surface is the same as that determined without considering spatial variability. In contrast to this indirect approach, in the direct approach, the effect of spatial variability is included in the process of determination of the probabilistic critical surface itself. While the indirect approach requires much less computational effort, the direct approach is definitely more rigorous. In this context this paper attempts to investigate, with the help of numerical examples, how far away are the results obtained from the indirect approach from that obtained from the direct approach. In both the approaches, it is required to use a model of discretization of random fields into finite random variables. A few such models are available in the literature for one-dimensional (1D) as well as two-dimensional (2D) spatial variability. The developed computational scheme is based on the First Order Reliability Method (FORM) coupled with the Spencer Method of Slices valid for limit equilibrium analysis of general slip surfaces. The study includes bringing out the computational advantages and disadvantages of the three commonly used discretization models. The sensitivity of the reliability index to the magnitudes of the scales of fluctuation has also been studied.