Hostrocks to the stratabound iron-formation-hosted Starra gold-copper deposit,Australia

This paper documents the timing, geochemistry and possible origin of sodium enrichment associated with Proterozoic iron formation-hosted copper-gold ore lenses at the Starra deposit, Australia. The ore lenses are immediately underlain by variably sheared albitemagnetite-hematite-pyrite-bearing rocks, and overlain by mainly unaltered, less-sheared, meta-sediments. Evidence indicating that albite was abundant prior to deformation, and also prior to the main hydrothermal addition of Fe, S, Cu and Au, includes (1) regional albite development at this stratigraphic level; (2) alteration of albite by ore-related sericite; and (3) inclusion of unfoliated inclusions of albite and hematite in ore-related pyrite. Nevertheless, albite also developed around dolerites and within hangingwall shears during metamorphism and deformation. Least altered albite footwall rocks have SiO₂ (67.31–73.13 wt.%), Al₂O₃(9.89–12.51 wt.%), total alkali elements (6.40–9.43 wt.%) and HFS elements (e.g., Zr = 179–275 ppm; Ti/Zr = 7.6–14.1) comparable with felsic volcanics, but have high relative Na₂O contents (5.08–5.81 wt. %), and variable to high Na₂O/K₂O ratios (0.05–68.37). An episode of alkali alteration by high-Na fluids prior to the ore-related alteration is postulated to account for sodic compositions, after chemical consideration of the alternatives (1) arkosic sediments; (2) trondhjemitic volcaniclastics; and (3) Na-metasomatism of Staveley Formation sediments. During the most intense ore-alteration, isocon analysis indicates a density increase of 23% compared to the least altered albitised hostrocks. Cu, Fe, Au, Sn, W, Zn, K, Ba and Rb were enriched during the mineralising process, whereas Mn, Ca, Si, Nb and Zr were lost, and Al, Ti and Y were not changed (and were used to define the isocon). The loss of some high field strength elements during this alteration indicates that igneous rock classification diagrams based on immobile element ratios should be used with caution for albitemuscovite magnetite-pyrite assemblages associated with iron formation-hosted copper-gold deposits. Zircon was partially soluble, whereas titanium oxides were probably stable in the saline, high temperature (260°–380 °C), acid (pH = 3.9–6.0) fluids envisaged for ore-related alteration.     

The role of moisture cycling in the weathering of a quartz chlorite schist in a tropical environment: findings of a laboratory simulation

Long‐term weathering of a quartz chlorite schist via wetting and drying was studied under a simulated tropical climate. Cubic rock samples (15 mm × 15 mm × 15 mm) were cut from larger rocks and subjected to time‐compressed climatic conditions simulating the tropical wet season climate at the Ranger Uranium Mine in the Northern Territory, Australia. Fragmentation, moisture content and moisture uptake rate were monitored over 5000 cycles of wetting and drying. To determine the impact of climatic variables, five climatic regimes were simulated, varying water application, temperature and drying. One of the climatic regimes reproduced observed temperature and moisture variability at the Ranger Uranium Mine, but over a compressed time scale. It is shown that wetting and drying is capable of weathering quartz chlorite schist with changes expected over a real time period of decades. While wetting and drying alone does produce changes to rock morphology, the incorporation of temperature variation further enhances weathering rates. Although little fragmentation occurred in experiments, significant changes to internal pore structure were observed, which could potentially enhance other weathering mechanisms. Moisture variability is shown to lead to higher weathering rates than are observed when samples are subjected only to leaching. Finally, experiments were conducted on two rock samples from the same source having only subtle differences in mineralogy. The samples exhibited quite different weathering rates leading to the conclusion that our knowledge of the role of rock type and composition in weathering is insufficient for the accurate determination of weathering rates. Copyright © 2005 John Wiley & Sons, Ltd.     

Archaeological geology of the Rustad Quarry site (32RI775): An early archaic site in Southeastern North Dakota

At The Rustad Quarry Site (32RI775), in southeastern North Dakota, Early Archaic artifacts, bison bone, and hearth features were found in the lowest of three Boroll-like buried soils formed in alluvial fan sediments. Alluvial fan sediments were deposited from 8000 to 4925 B.P., and were then buried by eolian sand. The alluvial fan sediments (mudflows) bury lacustrine sediments (Sherack Formation deposited from 9900 to 9500 B.P. in Glacial Lake Agassiz II), both of which overlie a Moorhead Phase fluvial terrace deposited from 10,900 to 9,900 B.P. Cultural remains were associated with five radiocarbon ages, three on archaeological charcoal (7180 B.P., 7240 B.P., and 7550 B.P.) and two on organic carbon from two welded A-horizons containing the cultural remains (7370 B.P. and 7675 B.P.). A well-developed Aquoll-like soil formed in the lacustrine sediments from 9500 to 8000 B.P. Soil morphology and chemistry of the Boroll-like fan soils, the Aquoll-like lacustrine soil, and other Boroll-like soils formed in eolian and deltaic sediments nearby suggest a subhumid, cool continental climate with riparian woodland and mixed prairie vegetation at the site and surrounding area from 11,400 B.P. to the present. This partially contradicts paleoenvironmental reconstruction from pollen sites nearby that suggest the area was covered by a closed canopy spruce forest from terminal late-Pleistocene to 10,000 B.P. Alluvial fan formation and eolian activity on the adjacent Sheyenne Delta occurred from 8000 to 5000 B.P., which indicates greater landscape instability and drier conditions during the mid-Holocene (Altithermal).     

Pyroxene-melt equilibria: an updated model

An updated model for pyroxene-melt equilibria at 1 atm has been developed and calibrated using new and existing experimental data in order to refine calculations of liquid lines of descent, which simulate the effect of igneous differentiation processes. We combine the Davidson and Lindsley (1985) model for activities of components in clinopyroxene and orthopyroxene solid solutions, a _i ^p , where i represents a quadrilateral endmember, with the Nielsen and Drake (1979) expressions for component activities in the melt, a _i ^L (two-lattice melt model). The chemical potential differences for pyroxene-melt equilibria are expressed in the form: $$\Delta \mu _{\iota } = 0 = In \left( {{{a_i^p } \mathord{\left/{\vphantom {{a_i^p } {a_i^L }}} \right.\kern-\nulldelimiterspace} {a_i^L }}} \right) + A_i + {{B_i } \mathord{\left/{\vphantom {{B_i } T}} \right.\kern-\nulldelimiterspace} T}$$ Pyroxene compositions were projected to quadrilateral compositions with the method of Lindsley and Anderson (1983). The regression constants A _i and B _i were calculated from experimental data that consists of 282 pyroxene-melt pairs, including 83 orthopyroxene-melt pairs. These experiments were all performed at 1 atm and represent compositions ranging from basalts (alkali to lunar) to dacites (42–66 wt% SiO₂). The model is calibrated for 1000相似文献   

Coal resources,production, and quality in the Eastern kentucky coal field: Perspectives on the future of steam coal production

The Eastern Kentucky coal field, along with adjacent portions of Virginia and southern West Virginia, is part of the greatest production concentration of high-heating-value, low-sulfur coal in the United States, accounting for over 27% of the 1993 U.S. production of coal of all ranks. Eastern Kentucky's production is spread among many coal beds but is particularly concentrated in a limited number of highquality coals, notably the Pond Creek coal bed and its correlatives, and the Fire Clay coal bed and its correlatives. Both coals are relatively low ash and low sulfur through the areas of the heaviest concentration of mining activity. We discuss production trends, resources, and the quality of in-place and clean coal for those and other major coals in the region.     

Results from a new model of river basin evolution

This paper briefly describes a model of the erosional development of catchments and their channel networks. The model differentiates between the dominant transport processes in hillslope and channels. The development of channels and hillslopes occurs in an integrated manner as a function of physically observable mechanisms. The growth of a river basin is qualitatively described. The model concepts are used to study the basin during periods of growth (transient periods), as well as during dynamic equilibrium. This leads to hypotheses about the relationship between slopes, relief, tectonic uplift, erodability, runoff, and catchment area. It is shown that the model leads to very reasonable and desirable behaviour of hillslopes during retreat and degradation.     

Spatial variability in soil moisture as predicted from airborne thematic mapper (ATM) data

In the first part of this project, the extent to which moisture content of alluvial soils could be predicted from imagery derived from an airborne thematic mapper (ATM) was investigated. From sampling done on the same day as the flight, it was found that digital numbers derived from the thermal channel (waveband 11) were strongly correlated with gravimetric moisture content. From sampling three fields of contrasting land cover, the relationship between waveband 11 values and moisture content was found to be independent of land cover type. Spatial variation in waveband 11 values and thus moisture content were related to palaeochannel patterns on the alluvial land. This was investigated by deriving variograms for long transects from each of the three investigated fields. The range and sills of the variograms are shown to express the nature and pattern of palaeochannels. By the application of such geostatistical techniques, high resolution imagery can thus be used to quantify palaeochannel characteristics on alluvial land.     

Laboratory simulation of the salt weathering of schist: II. Fragmentation of fine schist particles

Recent developments in long term landform evolution modelling have created a new demand for quantitative salt weathering data, and in particular data describing the size distribution of the weathered rock fragments. To enable future development of rock breakdown models for use in landscape evolution and soil production models, laboratory work was undertaken to extend existing schist/salt weathering fragmentation studies to include an examination of the breakdown of sub‐millimetre quartz chlorite schist particles in a seasonally wet tropical climate. Laser particle sizing was used to assess the impact of different experimental procedures on the resulting particle size distribution. The results reveal that salt weathering under a range of realistic simulated tropical wet season conditions produces a significant degree of schist particle breakdown. The fragmentation of the schist is characterized by splitting of the larger fragments into mid‐sized product with finer material produced, possibly from the breakdown of mid‐sized fragments when weathering is more advanced. Salinity, the salt addition method and temperature were all found to affect weathering rates. Subtle differences in mineralogy also produce variations in weathering patterns and rates. It is also shown that an increase in drying temperature leads to accelerated weathering rates, however, the geometry of the fracture process is not significantly affected. Copyright © 2006 John Wiley & Sons, Ltd.     

The opacity of some local Martian dust storms observed by the Viking IRTM

In this paper we analyze some Viking infrared thermal mapping (IRTM) measurements of local Martian dust storms observed in the southern tropical region of the planet between L_s=225 and 262°. The derived opacities of these storms show that in the most opaque regions of the cloud, the optical thickness may be ≈6. Away from the individual clouds, the opacity is ≈2, which is still about four times the background level of dustiness in the Martian atmosphere. We find considerable structure in the derived opacity which will create corresponding variations in the atmospheric heating, which in turn may have an important feedback upon the local winds.