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1.
High levels of Cd and Zn in Jamaican soils observed in geochemical surveys are related to the presence of phosphorites of possible Late-Miocene or Pliocene age. The trace element and REE geochemistry of the phosphorites, together with SEM studies, indicate a guano origin for the phosphorites. No specific host minerals for Cd could be identified in the fossiliferous phosphorite which is characterized by uniquely high levels of Cd, Zn, Ag, Be, U and Y. However, in the soil Cd is present in lithiophorite and a complex history of pedological development is preserved in the aluminous–goethite present in the soil. The unique guano signature is preserved in the soil despite the fact that guanos themselves have either not been observed or have been destroyed by continuing karst and soil development. The phosphorite geochemical signature can be traced in the data of a 1988 island-wide soil geochemical survey, identifying areas where the Palaeo-environment that supported bird ‘rookeries’ existed in the Late-Miocene or Pliocene. 相似文献
2.
The turbulent motions responsible for ocean mixing occur on scales much smaller than those resolved in numerical simulations
of oceanic flows. Great progress has been made in understanding the sources of energy for mixing, the mechanisms, and the
rates. On the other hand, we still do not have adequate answers to first order questions such as the extent to which the thermohaline
circulation of the ocean, and hence the earth's climate, is sensitive to the present mixing rates in the ocean interior. Internal
waves, generated by either wind or flow over topography, appear to be the principle cause of mixing. Mean and eddy flows over
topography generate internal lee waves, while tidal flows over topography generate internal tides. The relative importance
of these different internal wave sources is unknown. There are also great uncertainties about the spatial and temporal variation
of mixing. Calculations of internal tide generation are becoming increasingly robust, but we do not know enough about the
subsequent behavior of internal tides and their eventual breakdown into turbulence. It does seem, however, that most internal
tide energy flux is radiated away from generation sites as low modes that propagate over basin scales. The mechanisms of wave-wave
interaction and topographic scattering both act to transfer wave energy from low modes to smaller dissipative scales.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
3.
The mathematical framework for turbulent transport in the ocean is reasonably well established. It may be applied to large-scale fields of scalars in the ocean and to the instantaneous or continuous discharge from a point. The theory and its physical basis can also provide an interpretation of passive scalar spectra. Spatial variations in the rate of turbulent transfer can be related to the movement of the center of mass of a scalar and to a formulation in terms of entrainment. The relative dispersion of a scalar with respect to its center of mass and the streakiness of the concentration field within the relative dispersion domain need to be considered. In many of these problems it is valuable to think in terms of simple models for individual streaks, as well as overall statistical properties. 相似文献
4.
"Debates concerning the origins and development of the late nineteenth- to early twentieth-century declines in marital fertility and infant mortality in England and Wales have been centred largely on the material provided by answers to the ?special' questions in the 1911 census. In their published form these figures have restricted researchers to an examination of large scale geographic and social class differences in the levels and rates of decline of the two phenomena. This paper outlines research conducted on a sample of individual census returns from the 1911 census. From this data it becomes clear that for Victorian and Edwardian England ?where one lived' was rather more important than ?who one was' in determining both family building strategies and the survival of those children born." 相似文献
5.
A least-squares multiple linear regression is performed on orbital decay density data obtained from precise orbital analysis of 22 low-perigee (130–160 km) Air Force satellites. Variations related to solar activity, the semi-annual effect, geomagnetic activity, and the zenith angle of the Sun are in agreement with the model of Jacchia (1971). Density variations in longitude and latitude are also deduced and compared with recent results from other investigations within this altitude regime. 相似文献
6.
Macropores are subsurface connected void spaces caused by processes such as fracture of soils, micro‐erosion, and fauna burrows. They are common near streams (e.g. hyporheic and riparian zones) and may act as preferential flow paths between surface and groundwaters, affecting hydrologic and biogeochemical processes. We tested the hydrologic function of macropores by constructing an artificial macropore within the saturated zone of a meander bend (open macropore, ‘OM’) and later filling its upstream end (partially filled macropore, ‘PFM’). For each treatment, we injected saline tracer at an upgradient monitoring well within the meander and monitored downgradient hydraulics and tracer transport. Pressure transducers in monitoring wells indicated hydraulic gradients within the meander were 32% higher perpendicular to and 6% higher parallel to the macropore for the OM than for the PFM. Additionally, hydraulic conductivities measured via falling head tests were 29 to 550 times higher along the macropore than in nearby sediment. We used electrical conductivity probes in wells and electrical resistivity imaging to track solute transport. Transport velocities through the meander were on average 9 and 21% higher (per temporal moment analysis and observed tracer peak, respectively) for the OM than for the PFM. Furthermore, temporal moments of tracer breakthrough analysis indicated downgradient longitudinal dispersion and breakthrough tracer curve tailing were on average 234% and 182% higher for the OM, respectively. This suggests the OM enabled solute transport at overall shorter timescales than the matrix but also increased tailing. Our results demonstrate the importance of macropores to meander bend hydrology and solute transport. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
7.
This article borrows a statistical method from physical geography—topographical prominence—to suggest a new technique for measuring the relative significance or rank of population centers. Unlike raw population measures, prominence gives consideration to both the spatial intensity of concentrated population areas as well as the spatial dependence or independence of neighboring settlement clusters in relation to one another. We explain how to apply the topographic prominence calculation method to gridded population data and examine its practical utility through case studies of several U.S. states. We then discuss some ways in which parametric choices about point-to-surface transformations can result in considerably different outcomes and offer further suggestions for conceptualizing and measuring population center significance. 相似文献
8.
Chris Garrett 《Dynamics of Atmospheres and Oceans》1996,23(1-4)
Models for the evolution of the surface mixed layer need to be improved to include dominant processes such as Langmuir circulation. It is shown that the wave forcing in Langmuir circulation models is much stronger than that due to a surface buoyancy loss, and studies of the erosion by the cells of a pre-existing stratification are described. Mixed layer models will also need to allow for horizontal inhomogeneity. It is shown, for example, that the horizontal buoyancy gradient that may be left behind after a storm produces restratification that can be significant. The nonlinearity of the equation of state is another real-world factor; it gives rise to an annual average surface buoyancy that is misleading as it is compensated by interior cabbeling. Current work linking the mixed layer to water mass formation is also introduced. 相似文献
9.
Garrett?B.?Hazelton Gary?AxenEmail author Oscar?Lovera 《Contributions to Mineralogy and Petrology》2003,145(1):1-14
Sized aggregates of glasses (47–84 wt% SiO2) were fused from igneous-derived cohesive fault rock and igneous rock, and step-heated from ~400 to >1,200 °C to obtain their 39Ar diffusion properties (average E=33,400 cal mol?1; D o=4.63×10?3 cm2 s?1). At T<~1,000 °C, glasses containing <~69 wt% SiO2 and abundant network-forming cations (Ca, Fe, Mg) reveal moderate to strong non-linear increases in D and E, reflecting structural modifications as the solid transitions to melt. Extrapolation of these Arrhenius properties down to typical geologic T-t conditions could result in a 1.5 log10 unit underestimation in the diffusion rate of Ar in similar materials. Numerical simulations based upon the diffusion results caution that some common geologic glasses will likely yield 40Ar/39Ar cooling ages rather than formation ages. However, if cooling rates are sufficiently high, ambient temperatures are sufficiently low (e.g., <65–175 °C), and coarse particles (e.g., radius (r) >~1 mm) are analyzed, glasses with compositions similar to ours may preserve their formation ages. 相似文献
10.
Garrett W Brass 《Geochimica et cosmochimica acta》1975,39(12):1647-1653
The strontium isotope ratio in sea water has varied through geologic time owing to the input of strontium from rock weathering. To evaluate the possibility that ratios might be altered during weathering, seven weathering profiles developed on Mesozoic arkoses located along the length of New Zealand were investigated. The rubidium-strontium-strontium isotope relations in these profiles give ‘isochron’ ages less than the ages of deposition of the arkoses. These ages appear to result from the weathering of a homogeneous source rock. The age calculated from the rubidium-strontium system (t′) is related to the original age (t) by the equation t′/t = (n ? 1)/n, where n is the ratio of the amounts of common and radiogenic strontium leached from the rock. Shales formed by the accumulation of these residual solids may inherit misleading isochron relationships which may not be erased during deposition or early diagenesis. The strontium which goes into solution and is transported to the sea is slightly less radiogenic than the strontium in the unweathered rock, while the residual clays may be much more radiogenic. 相似文献