Water soluble components of PM10 Chongqing, China

The concentrations of water soluble ions (Na⁺, NH₄ ⁺, K⁺, Mg²⁺, Ca²⁺, NO₃ ^-, Cl^-, and SO ₄ ^2- ) in PM₁₀ samples collected on cellulose filters by a medium-volume cascade impactor were determined, which were obtained from three kinds of areas in Chongqing: industrial area (Jiulongpo district), commercial and residential area (Jiangbei district) and background area (Jinyun Mountain in the Beibei district). The results showed that except for the background site, the annual average values of PM₁₀ are 23% – 61% higher than the national air quality standard (GradeII) (0.1 mg/m³), even that the value of the control site is still 20% higher than American standard (0.05 mg/m³). This implied that serious pollution of fine particles occurred in Chongqing. Nine kinds of soluble ions in water of PM₁₀ were analyzed by ion chromatography (IC) and the annual average concentrations follow the order of [SO ₄ ^2- ] > [NO³ _-] > [Cl^-] > [F^-], and [Ca²⁺] > [NH₄ ⁺] > [K⁺] > [Na⁺] > [Mg²⁺]. Their values were different in these areas: the industrial area > the commercial and living area > the control area. As for NH_{4 +}, K⁺, Ca²⁺, NO₃ ^- and SO ₄ ^2- , their seasonal average concentrations show a similar variation trend: the values in spring and fall were higher than those in summer and winter. The seasonal average concentrations of [Cl^-], [F^-], [Na⁺] and [Mg²⁺] are much lower than those of other ions. However, the concentrations of [Na⁺] changed more greatly in different seasons than those of the other three ions. Correlation coefficients showed that the three areas have been polluted by coal smoke and dust to different extents, while some local resources of pollution should be taken into consideration as well.     

Impact of water environmental characteristics in Dry-Hot valley of Jinsha river on soil desertification

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Health risk assessment for typical and abandoned chromium-contaminated sites

Chromium pollution were investigated by sampling the abandoned chromium contaminated sites in Chongqing. Its health risk was assessed following the procedures made by USEPA. The results showed that the most seriously polluted land was found at the former production area （G4） with average Cr（VI） concentration of 3369.2 mg kg-1 on the surface soil. The assessment indicated that there was high risk of non-carcinogens for children. The assessed risk of the first layer of office area （G1） for children, chromium slag transition （G2）, drainage pipeline chromium slag transition （G3） and production area （G4） for both children and adults were not acceptable （〉1.00× 106）. It was strongly suggested that the accessible measures of remediation should be taken for a portion of contaminated sites before the reuse of abandoned lands.     

Mercury indicating inflow zones and ruptures along the Wenchuan Ms 8.0 earthquake fault

Acta Geochimica - During the Wenchuan Fault Scientific Drilling Project, we determined the values of total mercury (HgT) and gaseous elemental mercury (GEM) from drilled cores and drilling mud,...     

元谋干热河谷近50 a降水量时间序列的DFA分析

干热河谷是一类特殊的退化生态系统区域,降水对河谷景观格局的变化起着十分重要的作用.基于消除趋势波动分析法(DFA)分析了元谋地区近50 a降雨量变化趋势,同时也对1978～2006年进行了滑移分析.结果表明,元谋地区年均降水量序列至少在50 a的时间尺度上具有微弱的Hurst效应,即具有较弱的长期持续性及较强的随机性.区域植被覆盖率的变化能对该区域降雨量的动力学变化趋势做出有效的解释.     

Characteristics of surface runoff and throughflow in a purple soil of Southwestern China under various rainfall events

In order to harvest runoff to palliate water disaster as well as effectively manage irrigation and fertilizer application in the studied region, it is necessary to better understand the runoff processes. A newly designed runoff collection system for a plot scale was used to partition runoff under contrasting rainfall events into surface flow and subsurface flow to obtain characteristics of surface runoff and throughflow in a purple soil (Regosols in FAO taxonomy, Entisol in USDA taxonomy) of Sichuan, China. Under small rainfall (shower and drizzle), only surface runoff was observed. It is noted that, under shower, particularly with antecedent dry soil conditions, the highest peak surface runoff significantly lagged behind that of rainfall, because air‐locked soil pores of the top layer appeared temporally. Under rainstorm and downpour, surface runoff and throughflow both commenced and showed hysteresis. The hydrograph of surface runoff better resembled that of rainfall than throughflow did. The durations of throughflow discharge of post‐rainfall‐end were near the same (within 24 h) under various rainfalls and rather dependent upon the soil properties than the rainfall characteristics. Throughflow is about 60–90% of total runoff, and especially significant in a ploughed layer under downpour. The chloride concentration of throughflow was over twice that of surface runoff and rainfall, implying that throughflow contains more nutrients than surface runoff. Presumably, surface runoff was primarily governed by an infiltration‐excess or saturated excess‐infiltration mechanism under unsaturated or saturated soil conditions. Therefore, the management of water and fertilizer, and the harvesting of water flow in the ploughed soil layer, should be emphasized in this region. Copyright © 2005 John Wiley & Sons, Ltd.     

Spatial and temporal dynamics of soil moisture after rainfall events along a slope in Regosols of southwest China

High frequency seasonal drought in purple soils (Regosols in FAO taxonomy) of the hilly upland areas of Sichuan basin, China, is one of the key restrictive factors for crop production. In order to manage irrigation and fertilizer application in these soils effectively, the soil water content in a sloped plot with 60 cm soil depth was measured by neutron probe devices to investigate the soil moisture regime during the 1998 rainy season after various amounts of rainfall events. The results showed that variation of soil moisture along the slope positions was highest in the top soil layer during the period of sporadic rainfall that did not induce any runoff. The coefficients of variation of soil moisture at various slope positions (upper, middle, and lower) are 17·36%, 8·95%, 10·25%, 8·58%, 8·05% and 9·21% at the 10 cm, 20 cm, 30 cm, 40 cm, 50 cm and 60 cm soil depths respectively. When surface runoff occurred, the soil moisture dynamics at various positions on the plot were then very different. Soil water content decreased more rapidly on the upper slope than on the middle and lower slope positions. When both surface runoff and throughflow occurred, the soil moisture dynamics in the various layers showed a stable period (soil water content is near constant as time elapses) that lasted about 1 week. Also, the pattern of moisture dynamics is ‘decreasing–stabilization–decreasing’. Thus, irrigation and fertilization management according to the spatial and temporal features of soil moisture dynamics on sloped land can increase the water and fertilizer utilization efficacy by reducing their losses during the stable period. Copyright © 2006 John Wiley & Sons, Ltd.     

Distribution of heavy metals in an incineration system of solid wastes in the Three-Gorges region of the Yangtze River

On the basis of investigations on the composition and contents of heavy metals in the domestic refuse in the Three-Gorges region of the Yangtze River, in combination with the experimental results, this paper deals with the distribution rule of heavy metals in the various compartments of an incineration system： leachate pool, fly ash and residue. It is concluded that in the leachate pool heavy metals should not be neglectable since about 30% of Pb and 10% of Cr are leached here; in the incineration system, above 74% of Cr, As and Pb exists in residue; above 96% of Hg exists in fly ash and the contents of Cd in fly ash are close to those of residue. It is also concluded that the physical conditions of incineration have a significant influence on the distribution of heavy metals in the incineration system.     

紫色土丘陵区小流域综合治理对水土保持的作用

小流域综合治理是各地区水土保持的基本途径之一。根据对四川紫色土丘陵区综合治理小流域(四川南部县鹤鸣观小流域)水土流失多年(1985~2001年)监测,结果表明:①紫色土丘陵区小流域无论是以工程措施还是以生物措施为主进行综合治理,其水土保持效果都是十分有效的,而且是稳定的;②以工程措施为主的综合治理,其水土保持较以生物措施为主的见效快;③这两种综合治理模式,经过一定时期后,其水土保持效果接近。因此,综合治理水土流失,应因地制宜采取治理模式。     

A quantification of the effects of erosion on the productivity of purple soils

Research on the effects of soil erosion on soil productivity has attracted increasing attention.Purple soil is one of the main soil types in China and plays an important role in the national economy.However,the relationship between erosion and the productivity of purple soils has not been well studied.The purpose of this research was to determine if soil depth,which is dependent on the rate of erosion,has an influence on crop yield and growth.Plot and pot experiments at different soil depths were performed.Results indicate that soils from different parental materials had different growth features and crop yields due to the differential fertility of the derived soils.The yield reduction rate increases exponentially with the depth of eroded soil(level of erosion).The yield reduction rate per unit eroded soil horizon(10 cm) is approximately 10.5% for maize and wheat.