Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.     

Heat-shock protein 70 expression in shrimp Fenneropenaeus chinensis during thermal and immune-challenged stress

Using western immunoblotting, we obtained heat-shock protein 70 (HSP70) induction data and distribution in different tissues from shrimp Fenneropenaeus chinensis during thermal and immune-challenged stresses. This is probably the first report of the effects of various stressors on the expression of HSP70 in shrimp.HSP70 was prominently induced in hepatopancreas and gills, but not in muscle, eyestalk and hemolymph, when the shrimp were exposed to heat shock and Vibrio anguillavium-challenged stresses. Cold shock and WSSV treatment had no significant effects on the levels of HSP70 expression in all tissues examined. HSP70 induction was greatest after 2 h exposure to heat shock stress, which was elevated after acute heat shock exposure of 10℃ above ambient temperature.     

GPS/LEO掩星观测的变分同化技术

在简单介绍GPS/LEO掩星探测大气的发展历史和科学意义之后,详细阐述了反演的基本原理;分析了标准反演中存在的问题,并说明一维变分同化(1DVAR)在反演方法中的重要性;给出了一维变分同化中价值函数的求解,以及各种同化因子;简单介绍了对当前气象学中普遍使用的四维变分同化(4DVAR);重点讨论了各种同化方法,以及使用各种同化因子的优缺点。最后,通过CHAMP卫星的观测实例分析,验证了GPS数据在数值天气预报(NWP)中的作用,以及相对于标准反演法一维变分对气象要素的改进。     

Petroleum exploration potential of Tamtsag Basin

The Tamtsag Basin is located in the extreme eastern portion of the Mongolia. The Basin and its counterpart in China (the Hailar Basin) are united a whole basin on the structural setting. In recent years, the Tamtsag Basin attracts more and more attention with the important exploration discovered in the 19th block by SOCO and in Hailar Basin of China. This paper discusses the exploration potential of Tamtsag Basin from the viewpoint of petroleum geology.     

The Cenozoic Volcanoes in Northeast China

There are more than 600 Cenozoic volcanic cones and craters with abeut 50 000 km2of lava flows in northeast China, which formed many volcanic clusters and shown the features of the continental rift - type volcanoes. Most volcanic activities in this area, especially in the east part of Songliao graben, were usually controlled by rifts and faults with the main direction of NE / NNE in parallel and become younger from the central graben towards its both sides, especially to the east continental margin. It is revealed that the volcanism occurred in northeast China was as strong as that occurred in Japan during the Miocene and the Quaternary. The Quaternary basalt that is usually distributed along river valley is called "valley basalt"while Neogene basalt usually distributed in the top of mounts is called "high position basalt". These volcanoes and volcanic rocks are usually composed of alkaline basalts with ultramafic inclusions, except Changbaishan volcano that is built by trachyte and pantellerite.     

Fast iterative solution of large undrained soil‐structure interaction problems

In view of rapid developments in iterative solvers, it is timely to re‐examine the merits of using mixed formulation for incompressible problems. This paper presents extensive numerical studies to compare the accuracy of undrained solutions resulting from the standard displacement formulation with a penalty term and the two‐field mixed formulation. The standard displacement and two‐field mixed formulations are solved using both direct and iterative approaches to assess if it is cost‐effective to achieve more accurate solutions. Numerical studies of a simple footing problem show that the mixed formulation is able to solve the incompressible problem ‘exactly’, does not create pressure and stress instabilities, and obviate the need for an ad hoc penalty number. In addition, for large‐scale problems where it is not possible to perform direct solutions entirely within available random access memory, it turns out that the larger system of equations from mixed formulation also can be solved much more efficiently than the smaller system of equations arising from standard formulation by using the symmetric quasi‐minimal residual (SQMR) method with the generalized Jacobi (GJ) preconditioner. Iterative solution by SQMR with GJ preconditioning also is more elegant, faster, and more accurate than the popular Uzawa method. Copyright © 2003 John Wiley & Sons, Ltd.     

高、低煤阶煤层气藏地质特征及控气作用差异性研究

高、低煤阶煤层气地质特征及控气作用差异性是研究煤层气富集成藏的重要组成部分,是煤层气勘探开发理论研究过程中重要的基础性研究领域之一。本文以中国沁水、阜新盆地和美国粉河盆地等典型的含气盆地为例,探讨了高、低煤阶煤层气的储层物性差异,分析了构造控气和水文地质控气作用的差异性。研究表明,高煤阶气藏含气量高,CH4百分含量高,δ13C1值大于-38.75‰,储层渗透率变化小,储层改造难,构造热事件对煤层气的生成、富集贡献大,持续的水动力使气藏遭到破坏,且破坏幅度大,现今地下水格局对气藏的形成具有一定的影响;低煤阶气藏含气量低,CH4百分含量低,δ13C1值大于-49.11‰,储层渗透率变化大,储层易改造,煤热演化史及煤阶影响着煤层气的生成、富集,在煤层气生成过程中活跃的水动力是甲烷生成的主要的水文地质条件之一,但持续的水动力使气藏遭到破坏,且破坏幅度小,而合适的地层水矿化度则是低煤阶煤层气生成的重要条件,地下水格局对气藏的调整和改造起到决定性的影响。     

对松辽盆地钱家店凹陷铀成矿作用的重新认认识

钱家店凹陷中的含矿层位主要为上白垩统姚家组,前人认为其中的红色砂岩为原生成因,但大量的证据证实砂岩原生应以灰色为主,红色砂岩为后生氧化蚀变造成,并控制着钱家店铀矿床铀矿化的产出.在此基础上建立该矿床的后生蚀变分带,依次为红色蚀变带、黄色蚀变带、灰白色蚀变带、过渡带、原生带,红色蚀变带为主要的氧化带,铀矿化主要集中在过渡带.平面上铀矿化主要分布于层间氧化带前锋线附近的位置,并在氧化舌状体的前端和两个氧化舌状体之间存在铀的富集.文章最后还建立了该矿床的成矿模式,并对区域上层间氧化带的展布进行了讨论.     

冀北万全寺银金矿床地质地球化学特征

万全寺银金矿床位于张宣幔枝构造东侧的侏罗纪断陷盆地中,成矿时限晚于133.33Ma～101.82 Ma.通过硫、铅、氢、氧、碳及稀有气体同位素研究认为,成矿物质应源自地球深部,在中生代冀西北幔枝构造演化过程中集中成矿.成矿热液以岩浆水为主并加入了部分天水.