Nd-, Sr-, O-isotopic and chemical evidence for a two-stage contamination history of mantle magma in the Central-Alpine Bergell intrusion

Two different contamination processes have been identified as having been operative in the genesis of a plutonic suite: initial contamination of a mantle source, and subsequent crustal contamination of uprising partial melts from the mantle. These processes are indicated by a detailed analyses of Nd, Sr, and oxygen isotopes together with major-and trace-elements of the 32–30 Ma calc-alkaline Bergell intrusion. This intrusion is located at the suture of the Alpine continental collision zone and contains rock types capable of discriminating between mantle and intracrustal processes. A range from basaltic-andesitic dykes in the surrounding country rocks, cumulitic hornblendites, gabbros, tonalite, granodiorite and lamprophyres, to pegmatites and aplites, is exposed in this single intrusion. The results of REE modelling and isotopic compositions of the basic members suggest that the cumulates were fractionated from a picrobasaltic liquid originating by partial melting of enriched subcontinental mantle (_Nd=+4). Increases in ⁸⁷Sr/⁸⁶Sr (0.7055) and ¹⁸O(+6.7) in these samples relative to the mantle array and compositions of other Periadriatic intrusions are most likely the result of an initial contamination of the mantle source by dehydration or partial melting of altered subducted oceanic crust. Slight differentiation of such a picrobasaltic liquid produced the basaltic-andesitic dykes. Simultaneous fractional crystallization and contamination of the uprising magma by continental crust produced crustal isotopic signatures which increase with acidity to values of (_Nd=-7.6), ⁸⁷Sr/⁸⁶Sr=0.716 and ¹⁸O=+10. The crustal imprint and LREE enrichment in the dominating tonalite increase with decreasing crystallization depth which indicates that the tonalites were emplaced in several distinct batches with different degrees of contamination. Shoshonitic lamprophyres, which intruded into the partly solidified granodiorite, were generated in a deep, strongly contaminated mantle source. The posttectonic 26 Ma Novate leucogranite is not cogenetic with the main Bergell body, but rather formed from a predominantly crustal source. If the described features are indeed due to mantle source contamination processes, which are well known for volcanic arcs, it must be concluded that these may also play a significant role in the genesis of calcalkaline plutonic suites.     

Climatic change and design criteria in water resources management a regional case study

As a result of the anthropogenic greenhouse effect there is fear of alterations of the world climate, which also may result in hydrological changes and consequently in water resources management. In a case study it was investigated if such changes could be identified for a regional catchment area. Summarized it may be said that the regional analysis of hydro-meteorological data in the catchment area of the Sieg showed the expected effects of the anthropogenic climate change on the regional water cycle. Rises in annual mean temperature and precipitation could be observed over a period from 1892 until 1993. However, a significant relation between evident changes and greenhouse effect could not be stated. Changes in discharge do not show consistent behavior. Especially apparent contradictions show that additional examinations are necessary in order to make the complex natural inter-relationships between climate and regional water cycle with the impacts of existing anthropogenetic interferences visible and applicable for practical engineering tasks.     

Petrogenesis of contrasting granitoid plutons in western Bohemia (Czech Republic)

Summary Late-Variscan granitoid plutons in western Bohemia (Bor, Waidhaus-Rozvadov) have distinct petrographic, geochemical and isotopic features that suggest different magmatic evolutions. The Bor pluton comprises a suite of metaluminous tonalites and quartz diorites (Bor I), weakly peraluminous (monzo-)granites and granodiorites (Bor II) and medium-aluminous, late vein-forming leucomonzogranites (Bor III). The Waidhaus-Rozvadov pluton is strongly peraluminous, comprising a cordierite-biotite granitoid (CBG), the Rozvadov granite (ROG), the Bärnau granite (BÄG) and the subordinate, highly evolved Kreuzstein (Kíový kámen) granite (KG). Geochemical parameters and initial⁸⁷Sr/⁸⁶Sr ratios straddle the boundary between I- and S-type granites in the Bor pluton and are characteristic of purely S-type granites in the Waidhaus-Rozvadov pluton.The Bor II granitoids have been dated by the Rb-Sr whole-rock method at 341±17 Ma (I_Sr = 0.70724±0.00060). K-Ar biotite and muscovite ages of all units of the Bor pluton are mainly in the range 321-315 Ma. The K-Ar mineral ages are in good agreement with recently published U-Pb zircon data of these rocks. The different units of the Waidhaus-Rozvadov pluton have yielded less well-constrained Rb-Sr whole-rock ages, ranging from 313 to 300 Ma. However, the intrusion sequence is constrained by K-Ar muscovite ages (312-302 Ma), which define a systematic decrease towards the chemically more evolved granite types. Taken as a whole, it seems likely that the new radiometric ages characterize two temporally distinct periods of late-Variscan granitoid intrusion. The regional significance of these periods is emphasized by contemporaneous ages previously found in the adjacent northeastern Bavarian granitoids.The initial Sr and Nd isotope systematics indicate that the Bor and the WaidhausRozvadov plutons were derived from different source rocks. The Bor granitoids reflect the influence of less evolved crustal material which may have been similar to paragneisses of the Teplá-Barrandian region, including the Zone of ErbendorfVohenstrauß (ZEV). The Waidhaus-Rozvadov granitoids probably resulted from anatexis of rocks resembling surrounding Moldanubian paragneisses or metapelites. In addition, the two plutons exhibit poorly defined, opposite trends of Nd_(T) variation which are ascribed to assimilation processes.

---

Petrogenese kontrastierender Granitplutone in Westböhmen (Tschechien)

Zusammenfassung Spätvariscische Granitplutone in Westböhmen (Bor, Waidhaus-Rozvadov) weisen petrographische, geochemische und isotopische Kontraste auf, die unterschiedliche magmatische Entwicklungen nahelegen. Der Bor Pluton umfaßt metalumine Tonalite und Quarzdiorite (Bor I), schwach peralumine (Monzo-)granite und Granodiorite (Bor II) und mäßig alumine, gangbildende Leukomonzogranite (Bor III). Der WaidhausRozvadov Pluton besitzt stark peralumine Zusammensetzung und läßt sich in einen Cordierit-Biotit Granitoid (CBG), den Rozvadov Granit (ROG), den Bärnau Granit (BÄG) und den stofflich hochentwickelten Kreuzstein (Kíový kámen) Granit (KG) untergliedern. Geochemische Parameter und initiale⁸⁷Sr/⁸⁶Sr-Verhältnisse liegen im Falle des Bor Plutons im Übergangsbereich zwischen I- und S-Typ Graniten und im Falle des Waidhaus-Rozvadov Plutons im Bereich reiner S-Typ Granite.Die Bor II Granitoide wurden nach der Rb-Sr Gesamtgesteinsmethode auf 341±17 Ma (I_Sr = 0.70724±0.00060) datiert. K-Ar Biotit- und Muskovitalter der Bor Granitoide liegen zwischen 321 and 315 Ma. Die K-Ar Mineralalter stehen im Einklang mit den kürzlich publizierten U-Pb Zirkondaten dieser Gesteine. Die verschiedenen Teilintrusionen des Waidhaus-Rozvadov Plutons liefern weniger gut definierte Rb-Sr Gesamtgesteinsalter zwischen 313 and 300 Ma. Die Intrusionsabfolge läßt sich dennoch durch K-Ar Muskovitalter festlegen (312-302 Ma), die eine systematische Abnahme von den weniger zu den starker entwickelten Granittypen aufweisen. Als Ganzes betrachtet dokumentieren die neuen radiometrischen Daten zwei zeitlich voneinander getrennte spdtvariscische Intrusionsereignisse. Die regionale Signifikanz dieser Ereignisse wird durch eine analoge Altersverteilung in den benachbarten nordostbayerischen Granitoiden untermauert.Anhand der initialen Sr und Nd Isotopensystematik können für die Bor und Waidhaus-Rozvadov Plutone unterschiedliche Quellen abgeleitet werden. Die Bor Granitoide spiegeln den Einfluß von gering entwickelten krustalen Material wider, das ähnliche stoffliche Eigenschaften besaß, wie Paragneise des Teplá-Barrandiums und der Zone von Erbendorf-Vohenstrauss (ZEV). Die Waidhaus-Rozvadov Granitoide lassen sich als Derivate moldanubischer Paragneise and Metapelite oder vergleichbarer Gesteine auffassen. Die zwei Plutone weisen schwach ausgeprägte gegensätzliche Nd_(T)-Variationen auf, was auf unterschiedliche Assimilationsprozesse zurückgeführt wird.

---

---

With 10 Figures     

Chemical Mechanism Development: Laboratory Studies and Model Applications

Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere.     

Erosion-driven uplift of the modern Central Alps

We present a compilation of data of modern tectono-geomorphic processes in the Central European Alps which suggest that observed rock uplift is a response to climate-driven denudation. This interpretation is predominantly based on the recent quantification of basin-averaged Late Holocene denudation rates that are so similar to the pattern and rates of rock uplift rates as determined by geodetic leveling. Furthermore, a GPS data-based synthesis of Adriatic microplate kinematics suggests that the Central Alps are currently not in a state of active convergence. Finally, we illustrate that the Central Alps have acted as a closed system for Holocene redistribution of sediment in which the peri-Alpine lakes have operated as a sink for the erosional products of the inner Central Alps.While various hypotheses have been put forward to explain Central Alpine rock uplift (e.g. lithospheric forcing by convergence, mantle processes, or ice melting) we show with an elastic model of lithospheric deformation, that the correlation between erosion and rock uplift rates reflects a positive feedback between denudation and the associated isostatic response to unloading. Thus, erosion does not passively respond to advection of crustal material as might be the case in actively converging orogens. Rather, we suggest that the geomorphic response of the Alpine topography to glacial and fluvial erosion and the resulting disequilibrium for modern channelized and associated hillslope processes explains much of the pattern of modern denudation and hence rock uplift. Therefore, in a non-convergent orogen such as the Central European Alps, the observed vertical rock uplift is primarily a consequence of passive unloading due to erosion.     

Interaction between crustal-derived felsic and mantle-derived mafic magmas in the Oberkirch Pluton (European Variscides, Schwarzwald, Germany)

The composite Oberkirch pluton consists of three compositionally different units of peraluminous biotite granite. The northern unit is relatively mafic (SiO₂∼64%) and lacks cordierite. The more felsic central and southern units (SiO₂=67.8 to 70.4%) can only be distinguished from each other by the occurrence of cordierite in the former. Mafic microgranular enclaves of variable composition, texture and size occur in each of these units and are concentrated in their central domains. Most abundant are large (dm to m) hornblende-bearing enclaves with dioritic to tonalitic compositions (SiO₂=50.8 to 56.3 wt%; Mg#=63 to 41) and fine grained doleritic textures that suggest chilling against the host granite magma. Some of these enclaves are mantled by hybrid zones. Less common are microtonalitic enclaves containing biotite as the only primary mafic phase (SiO₂=53.7 to 64.4%) and small hybrid tonalitic to granodioritic enclaves and schlieren. Synplutonic dioritic dikes (up to 6 m thick) with hybrid transition zones to the host granite occur in the southern unit of the pluton. In chemical variation diagrams, samples from unmodified hornblende-bearing mafic enclaves and dikes form continuous trends that are compatible with an origin by fractionation of olivine, clinopyroxene, hornblende and plagioclase. Chemical and initial isotopic signatures (e.g. high Mg#, low Na₂O, ɛ_Nd=−1.2 to −5.1, ⁸⁷Sr/⁸⁶Sr=0.7055 to 0.7080, δ¹⁸O=8.0 to 8.8‰) exclude an origin by partial melting from a mafic meta-igneous source but favour derivation from a heterogeneous enriched lithospheric mantle. Samples from the granitic host rocks do not follow the chemical variation trends defined by the diorites but display large scatter. In addition, their initial isotopic characteristics (ɛ_Nd=−4.5 to −6.8, ⁸⁷Sr/⁸⁶Sr=0.7071 to 0.7115, δ¹⁸O=9.9 to 11.9‰) show little overlap with those of the diorites. Most probably, the granitic magmas were derived from metapelitic sources characterized by variable amounts of garnet and plagioclase. This is suggested by relatively high molar ratios of Al₂O₃/(MgO+FeO_tot) and K₂O/Na₂O, in combination with low ratios of CaO/(MgO+FeO_tot), variable values of Sr/Nd, Eu/Eu*[=Eu_cn/(Sm_cn × Gd_cn)^0.5] and (Tb/Yb)_cn (cn=chondrite-normalized) as well as variable abundances of Sc and Y. Whole-rock initial isotopic signatures of mafic microtonalitic enclaves (ɛ_Nd=−4.6 to −5.2; ⁸⁷Sr/⁸⁶Sr=0.7060 to 0.7073; δ¹⁸O ∼8.1‰) are similar to those of the low ɛ_Nd diorites. Plagioclase concentrates from a granite sample and a mafic microtonalitic enclave are characterized by initial ⁸⁷Sr/⁸⁶Sr ratios that are significantly higher than those of their bulk rock systems suggesting incorporation of high ⁸⁷Sr/⁸⁶Sr crustal material into the magmas. Field relationships and petrographic evidence suggest that the Oberkirch pluton originated by at least three pulses of granitic magma containing mafic magma globules. In-situ hybridization between the different magmas was limited. Late injection of dioritic magma into the almost solidified granitic southern unit resulted in the formation of more or less continuous synplutonic dikes surrounded by relatively thin hybrid zones. Received: 30 April 1999 / Accepted: 6 August 1999     

FerryBox - Application of continuous water quality observations along transects in the North Sea

In 2002, the Helmholtz-Zentrum Geesthacht, Germany, started to use FerryBox-automated monitoring systems on Ships of Opportunity to continuously record standard oceanographic, biological and chemical in situ data in the North Sea. The present study summarises the operational experience gathered since the beginning of this deployment and reflects on the potential and limits of FerryBox systems as a monitoring tool. One part relates to the instrumental performance, constancy of shipping services, and the availability and quality of the recorded in situ data. The other considers integration of the FerryBox observations in scientific applications and routine monitoring campaigns. Examples are presented that highlight the added value of the recorded data for the study of both long- and short-term variability in water mass stability, plankton communities and surface water productivity in the North Sea. Through the assessment of technical and scientific performance, it is evident that FerryBoxes have become a valuable tool in marine research that helps to fill gaps in coastal and open ocean operational observation networks.     

Paleocene alkaline volcanism in the Nares Strait region: evidence from volcanic pebbles

Paleogene sediments in fault-bounded basins on Judge Daly Promontory, northeast Ellesmere Island, Canadian High Arctic, are rich in volcanogenic material. Volcanic pebbles within the Cape Back basin near Nares Strait were studied for their petrography, geochemistry, Sr and Nd isotopes, and geochronology to identify and characterize their parent rock. The pebbles are derived from lava flows and ignimbrites of a continental rift-related, strongly differentiated, highly incompatible element enriched, alkaline volcanic suite, the proposed Nares Strait volcanic suite, which is distinct from other alkaline volcanic suites on the northern coasts of Ellesmere Island and Greenland. ⁴⁰Ar/³⁹Ar amphibole and alkali feldspar ages indicate that volcanism was active around 61–58 Ma and was probably contemporaneous with sedimentation resulting in Middle to Late Paleocene age for deposition within the Cape Back basin and the other Paleogene basins on Judge Daly Promontory.     

Isotopic dating of pre-Alpidic rocks from the island of Ios (Cyclades,Greece)

The lower tectonic unit of Ios provides evidence of an at least four stage metamorphic and intrusive history which well might be generalized for large parts of the internal Pelagonian.Metamorphic country rocks of unknown age were intruded about 500 Ma ago, as concluded from a Rb-Sr whole rock (WR) isochron on relic tonalites to granodiorites which largely escaped the polyphase postmagmatic overprints.A Hercynian amphibolite facies metamorphism, during which the igneous rocks were partly recrystallized to orthogneisses, is dated by a lower intercept age of 300–305 Ma of U-Pb determinations on zircons and by three almost concordant Rb-Sr muscovite-WR ages of 295 to 288 Ma.K-Ar analyses on these muscovites and on biotites, and Rb-Sr tie lines WR-biotite and WR with other relic magmatic minerals yielded various apparent ages between 260 and 60 Ma. They are interpreted as mixed ages between a Hercynian cooling age and the two stage Alpidic overprints.White micas formed during the Eocene high P/T and/or Oligocene/Miocene Barrovian-type overprints yielded K-Ar dates ranging from 82 to 26 Ma, as well as a single Rb-Sr date of 13 Ma. These Alpidic dates resemble the more detailed age patterns of other Cycladic islands. But they are not sufficient for an independent dating of the Tertiary evolution on Ios island.