Astrometric investigation with the Tautenburg Schmidt telescope

The observations and the plate reduction technique for the determination of positions and absolute proper motions which is used in Potsdam are described. Recent results have shown that an accuracy of about 0 _. 1 for positions and 0 _. ⁷ cent _. ^–1 for proper motions can be achieved both for bright (8^m–12^m) and faint (16^m–18^m) stars. Three astrometric programmes using the Tautenburg plates are presented.     

Calcium isotope (δCa) fractionation along hydrothermal pathways, Logatchev field (Mid-Atlantic Ridge, 14°45′N)

We investigate the Logatchev Hydrothermal Field at the Mid-Atlantic Ridge, 14°45′N to constrain the calcium isotope hydrothermal flux into the ocean. During the transformation of seawater to a hydrothermal solution, the Ca concentration of pristine seawater ([Ca]_SW) increases from about 10 mM to about 32 mM in the hydrothermal fluid endmember ([Ca]_HydEnd) and thereby adopts a δ^44/40Ca_HydEnd of −0.95 ± 0.07‰ relative to seawater (SW) and a ⁸⁷Sr/⁸⁶Sr isotope ratio of 0.7034(4). We demonstrate that δ^44/40Ca_HydEnd is higher than that of the bedrock at the Logatchev field. From mass balance calculations, we deduce a δ^44/40Ca of −1.17 ± 0.04‰ (SW) for the host-rocks in the reaction zone and −1.45 ± 0.05‰ (SW) for the isotopic composition of the entire hydrothermal cell of the Logatchev field. The values are isotopically lighter than the currently assumed δ^44/40Ca for Bulk Earth of −0.92 ± 0.18‰ (SW) [Skulan J., DePaolo D. J. and Owens T. L. (1997) Biological control of calcium isotopic abundances in the global calcium cycle. Geochim. Cosmochim. Acta61,(12) 2505-2510] and challenge previous assumptions of no Ca isotope fractionation between hydrothermal fluid and the oceanic crust [Zhu P. and Macdougall J. D. (1998) Calcium isotopes in the marine environment and the oceanic calcium cycle. Geochim. Cosmochim. Acta62,(10) 1691-1698; Schmitt A. -D., Chabeaux F. and Stille P. (2003) The calcium riverine and hydrothermal isotopic fluxes and the oceanic calcium mass balance. Earth Planet. Sci. Lett. 6731, 1-16]. Here we propose that Ca isotope fractionation along the fluid flow pathway of the Logatchev field occurs during the precipitation of anhydrite. Two anhydrite samples from the Logatchev Hydrothermal Field show an average fractionation of about Δ^44/40Ca = −0.5‰ relative to their assumed parental solutions. Ca isotope ratios in aragonites from carbonate veins from ODP drill cores indicate aragonite precipitation directly from seawater at low temperatures with an average δ^44/40Ca of −1.54 ± 0.08‰ (SW). The relatively large fractionation between the aragonite precipitates and seawater in combination with their frequent abundance in weathered mafic and ultramafic rocks suggest a reconsideration of the marine Ca isotope budget, in particular with regard to ocean crust alteration.     

Investigation of the stable isotope fractionation in speleothems with laboratory experiments

Many speleothems show evidence for calcite precipitation under disequilibrium conditions. To improve the understanding of these kinetic processes, several laboratory experiments were performed to study the fractionation of stable oxygen and carbon isotopes during the precipitation of calcite. Carbonate was precipitated under controlled conditions from both a body of standing water (beaker experiments) and a solution flowing along a channel (channel experiments) at a relative humidity of 100%. Slow degassing of CO₂, simulated by the beaker experiments, results in δ¹⁸O values in equilibrium with the solution. In contrast, the δ¹³C values show a significant enrichment, inversely proportional to the height of the solution in the beakers. Fast degassing of CO₂, simulated by the channel experiments, showed an enrichment of both δ¹³C and δ¹⁸O and a slope of Δδ¹³C/Δδ¹⁸O of 1.4±0.6. These results represent experimental evidence for the Hendy effect, which is manifested in (i) a progressive increase in δ¹⁸O and δ¹³C away from the growth axis and (ii) a positive correlation between δ¹⁸O and δ¹³C along a single growth layer of a stalagmite.     

Crustal structure of the Eastern Alps along the TRANSALP profile from wide-angle seismic tomography

The objective of the TRANSALP project is an investigation of the Eastern Alps with regard to their deep structure and dynamic evolution. The core of the project is a 340-km-long seismic profile at 12°E between Munich and Venice. This paper deals with the P-wave velocity distribution as derived from active source travel time tomography. Our database consists of Vibroseis and explosion seismic travel times recorded at up to 100 seismological stations distributed in a 30-km-wide corridor along the profile. In order to derive a velocity and reflector model, we simultaneously inverted refractions and reflections using a derivative of a damped least squares approach for local earthquake tomography. 8000 travel time picks from dense Vibroseis recordings provide the basis for high resolution in the upper crust. Explosion seismic wide-angle reflection travel times constrain both deeper crustal velocities and structure of the crust–mantle boundary with low resolution. In the resulting model, the Adriatic crust shows significantly higher P-wave velocities than the European crust. The European Moho is dipping south at an angle of 7°. The Adriatic Moho dips north with a gentle inclination at shallower depths. This geometry suggests S-directed subduction. Azimuthal variations of the first-break velocities as well as observations of shear wave splitting reveal strong anisotropy in the Tauern Window. We explain this finding by foliations and laminations generated by lateral extrusion. Based on the P-wave model we also localized almost 100 local earthquakes recorded during the 2-month acquisition campaign in 1999. Seismicity patterns in the North seem related to the Inn valley shear zone, and to thrusting of Austroalpine units over European basement. The alignment of deep seismicity in the Trento-Vicenza region with the top of the Adriatic lower crust corroborates the suggestion of a deep thrust fault in the Southern Alps.     

Permanent Scatterers for landslide investigations: outcomes from the ESA-SLAM project

Within the SLAM project (Service for Landslide Monitoring), launched in 2003 by the European Space Agency (ESA) the Permanent Scatterers (PS) technique, a multi-image interferometric approach, coupled with the interpretation of aerial-photos and optical satellite images, was carried out for landslide investigations. The PS analysis was applied at a regional scale as support for landslide inventory mapping and at local scale for the monitoring of single well-known slope movements. For the integration of the PS measurements within a landslide inventory the Arno river basin (Italy) was chosen as test site for the presence of a high number of mass movements (to date about 300 areas at high landslide risk and more than 27,000 individual landslides mapped by the institutional authorities). About 350 SAR images have been interferometrically processed by means of the PS technique, with the detection of about 600,000 PS. The use of optical images contributed spatial meaning to the point-wise information provided by the PS, making it easier to identify terrain features related to slope instability and the landslide boundaries. Here we describe the employed methodology and its impact in the updating of a preexisting landslide inventory. 6.8% of the total number of landslides were characterized by ground displacement measurements from the PS: 6.1% of already mapped landslides and 0.8% of new unstable areas detected through the PS analysis. Moreover, most of the PS are located in urban areas, showing that the proposed methodology is suitable for landslide mapping in areas with a quite high density of urbanization, but that over vegetated areas it still suffers from the limitations induced by the current space-borne SAR missions (e.g. temporal de-correlation). On the other hand, the use of InSAR for the monitoring of single slow landslides threatening built-up areas has provided satisfactory results, allowing the measurement of superficial deformations with high accuracy on the landslide sectors characterized by a good radar reflectivity and coherence.     

Redetermination of the transformation enthalpies of the xanthoconite–proustite, pyrostilpnite–pyrargyrite and trechmannite–smithite phase transitions

 We report here refined values of the transformation enthalpy for xanthoconite to proustite (54.81 kJ/mol) and pyrostilpnite to pyrargyrite (40.32 kJ/mol). Additionally, the enthalpy for the transformation of trechmannite to smithite (5.82 kJ/mol) has been determined. The refinement was possible by taking into account a previously unknown dependence of electrochemical signals on the amount of substance undergoing the reduction process. Received December 21, 1995/Revised, accepted June 29, 1996     

Regional and temporal changes in epizoobiontic bryozoan-communities of Flustra foliacea (Linnaeus, 1758) and implications for North Sea ecology

Until recently, bryozoans have not been used as indicators for changes in bottom communities or climate control in the North Sea Basin, despite a 200-year history of bryozoan collecting. The epizoobiontic bryozoan fauna of Flustra foliacea (Linnaeus, 1758) was analysed on 51 sample stations kept in four German museums. The samples cover the entire North Sea and different time periods (1776–2008, mainly the period of 1904/1905 compared to 1980–87). Cluster analysis shows a differentiation into a northern and a southern North Sea assemblage. The northern assemblage is characterized by Amphiblestrum flemingii (Busk, 1854), Callopora dumerilii (Audouin, 1826) and Tricellaria ternata (Ellis & Solander, 1786), while the southern North Sea is characterized by Electra pilosa (Linnaeus, 1767), Crisia eburnea (Linnaeus, 1758) and Plagioecia patina (Lamarck, 1816). Spatial separation approximately follows the 50 m depth contour. The temporal distribution patterns of bryozoans are discussed in terms of NAO (North Atlantic Oscillation) and temperature variations.