Paleoweathering features in the Sergi Formation (Jurassic-Cretaceous), northeastern Brazil,and implications for hydrocarbon exploration

Paleoweathering in the Sergi Formation has been classified and analyzed to ascertain its origin and relationship with stratigraphic evolution. The Sergi Formation belongs to the pre-rift sequence of the Recôncavo Basin (northeastern Brazil) and comprises a complex association of eolian and fluvial sandstones and lacustrine mudstones. This formation can be subdivided into three depositional sequences bounded by regional unconformities. Four paleoweathering types, each one related to a distinct origin, have been described in the Sergi Formation: (1) textural mottling, which is distinguished by alternating rock colors as a result of the iron oxide mobilization within mineral phases that evolved under alternating oxidation (yellowish, brownish and reddish shades) and reduction (grayish or greenish hues) conditions; (2) non-textural mottling, which displays a discoloration pattern that is independent of the original rock texture; (3) carbonate concentrations, usually related to carbonate nodule formation, which display a massive internal structure that reveals their origin through continuous growth or crystallization; and (4) banded carbonates (silicified), associated with the beginning of regular surface formation due to the chemical precipitation of carbonates within lacustrine environments. Both mottling color motifs and carbonate accumulation usually represent groundwater oscillation rather than pedogenesis. Only carbonate intraclasts and banded carbonate (silicified) have their origin ascribed to pedogenesis sensu stricto, although the carbonate intraclasts do not represent soil deposits in situ, but calcretes eroded from areas close to channels, and the banded carbonates (silicified) have strong diagenetic modifications. Therefore, it is reasonable to assume that fluvial and meteoric water have controlled paleoweathering evolution as well as deposition, yet both aspects are ruled by the same mechanisms (relief, sedimentation rate and, above all, climate).     

Reclamation influence and background geochemistry of neutral saline soils in the Po River Delta Plain (Northern Italy)

Reclaimed neutral saline sulphate soils constitute a large part of the eastern part of Po Plain lowlands, where intensive agricultural activities take place. The knowledge of their geochemical features is essential to develop the best management practices capable to preserve this threatened environment. With this aim, three boreholes were drilled in an agricultural field and a typical reclaimed soil profile has been characterized for major and trace element, pH, electrical conductivity, redox conditions and water-soluble anions and ammonium. Statistical analysis (cluster analysis and principal component analysis) has been used to understand the relationship between elements and grain size. The soil profile is characterized by high salinity and high organic matter contents responsible for high chloride, sulphate, and ammonium concentrations. Heavy metal content is naturally high, since Po Plain sediments are the result of ultramafic rocks erosion; in addition, organic matter tends to concentrate heavy metals by adsorption, mainly in peaty horizons. As a consequence of chemical and zootechnical fertilization, high NO₃ ^? contents have been found in the top soil, thus enhancing the risk of nitrate discharge in the water system, especially in relation to extreme climatic events.     

A historical geomorphological approach to flood hazard management along the shore of an alpine lake (northern Italy)

A project to develop a flood hazard management plan along the east shore of Lago Maggiore was carried out. Several municipal territories along a coastal stretch have been analysed, identifying the rate of water rise and the limits of the submerged areas. This study discusses the overall methodological approach and presents the results for Porto Valtravaglia, as a significant case study. The first step was a detailed analysis of historical events to locate the most frequently damaged sites. Thousands of historical documents on past floods were collected, selected and validated, to map the most vulnerable sites. The second step was a morphological analysis of the studied coastal stretch. Multi-temporal aerial snap-shots were used and field surveys were conducted to verify the reliability of the historical data and to identify the critical hydraulic conditions along the shore. The third step was a review of the general urban development plans of the 17 studied municipalities. Aerophotogrammetric and cadastral maps were used to evidence and define the eight classes of land use destinations. In addition, the floodable areas were divided into three vulnerability and exposure categories considering different peculiarities of social and working life. Finally, using GIS spatial analysis tools, these data were compiled into risk maps and wielded as the municipal emergency plans’ baseline scenarios. For each studied municipality was hypothesised the alarm thresholds upon which were activated the flood emergency procedures.

     

Correction to: A historical geomorphological approach to flood hazard management along the shore of an alpine lake (northern Italy)

Natural Hazards - This correction stands to correct mistakes presented in the original article due to a lag in the e-proofing system and the correction handling for this article. The original...     

Slab melt and intraplate metasomatism in Kapfenstein mantle xenoliths (Styrian Basin, Austria)

Anhydrous and amphibole-bearing mantle peridotite xenoliths from Kapfenstein (Styrian Basin) have been studied with the aim of understanding both the processes responsible for amphibole formation and the nature of metasomatizing agents which affected this portion of lithosphere. This area of the Pannonian Basin underwent a subduction event which was followed after about 15 Ma, by alkaline intraplate magmatism. Primary clinopyroxene (cpx1) in four-phase lherzolite xenoliths is characterized by LREE-depleted to slightly LREE-enriched patterns. LREE-depleted cpx1 have low Th and U contents and Zr (and Hf) anomalies varying from slightly negative to positive. LREE-enriched cpx have high Th and U contents and remarkable positive anomalies of Zr and Hf. Primary clinopyroxenes in amphibole-bearing lherzolites present a comparable compositional variation from LREE (and Th, U, Zr, Hf)-depleted type to LREE (and Th, U, Zr, Hf)-enriched type. LREE-depleted cpx1, with strong negative Zr and Ti anomalies, are also recognized in the peridotite matrix of a composite sample cut by a large amphibole vein. Textural and geochemical evidence indicates that amphibole disseminated within the matrix grew at the expense of primary spinel and clinopyroxene, mimicking the trace element patterns of the latter. As a consequence, the geochemical features of amphibole vary in relation to those of clinopyroxene, from enriched to depleted. On the other hand, the composition of vein amphibole in the composite xenolith compares well with amphibole megacrysts and microphenocrysts, suggesting that it represents a fractionation product of alkaline melt that passed through the lithosphere. Two kinds of metasomatism, superimposed on a slightly depleted lithospheric mantle, were identified. A slab-derived melt (proto-adakite?) metasomatic agent was responsible for the first enrichment in Th, U, Zr and Hf observed in clinopyroxene, whereas an alkaline within-plate metasomatic agent caused the formation of the Nb (and Ta)- rich disseminated amphibole. The final process was the alkaline magmatism, which was responsible for the formation of the large amphibole vein and megacrysts. It is proposed that the Nb-poor and Nb-rich amphiboles record the transition between the suprasubduction slab melt-related and the intraplate alkaline metasomatism.

These geochemical features are consistent with a lithospheric portion enriched in slab melt components which was subsequently metasomatized by alkaline melt. Alternatively an asthenospheric uprising could have scavenged a previously slab melt-enriched region of the lithosphere.     

Evolution of an ancient coastal plain: palaeosols, interfluves and alluvial architecture in a sequence stratigraphic framework, Cenomanian Dunvegan Formation, NE British Columbia, Canada

To date, discussion of changes in alluvial style and in the character of palaeosols in relation to changes in accommodation and sediment supply on floodplains has primarily been from a conceptual standpoint: few case studies are available against which to test ideas. One hundred and thirty metres of non-marine strata of the Dunvegan Formation were examined in 14 closely spaced sections in the canyon of the Kiskatinaw River, NE British Columbia, Canada. This site was located about 120 km inland from the transgressive limit of the contemporary marine shoreline and represents almost exclusively freshwater environments. Fluvial channels in the Kiskatinaw River section are of two types. Small, single-storey, very fine- to fine-grained sandstone ribbons with W/T ratios <30, encased in fine-grained floodplain sediments are interpreted as anastomosed channels. Fine- to medium-grained, laterally accreted point-bar deposits forming multistorey sand bodies with individual W/T ratios >30 are interpreted as the deposits of meandering rivers filling incised valleys. Interchannel facies include the deposits of crevasse channels and splays, lakes, floodplains and palaeosols. Floodplain palaeosols consist of laterally heterogeneous, simple palaeosol profiles and pedocomplexes similar to modern Entisols, Inceptisols and hydromorphic soils. Interfluve, sequence-bounding palaeosols adjacent to incised valleys are laterally continuous, up to 3 m thick and can be reliably identified using a combination of (1) stratigraphic position; (2) field observations, such as thickness, structure, colour, degree of rooting; and (3) micromorphological features, such as evidence of bioturbation, clay coatings, ferruginous features and sphaerosiderite. Interfluve palaeosols are similar to modern Alfisols and Ultisols. Correlation of the local stratigraphic succession with the regional sequence stratigraphic framework, based on 2340 well logs and 60 outcrop sections, shows that the vertical changes in coastal plain character (more coals and lakes vs. more pedogenesis) can be related to relatively high-frequency base level cycles (eustatic?) that are expressed as transgressive–regressive marine cycles in downdip areas. Regional isopach maps show that these cycles were progressively overprinted and modified by an increasing rate of tectonic subsidence in the north and west. The character of palaeosols developed on aggrading floodplains primarily reflects local sediment supply and drainage. In contrast, well-developed interfluve palaeosols record pedogenesis during periods of reduced or negative accommodation (base level fall). Vertical changes in floodplain palaeoenvironments and palaeosol types reflect changes in accommodation rate. The detailed micromorphological analysis of interfluve palaeosols represents a powerful application of an under-used technique for the recognition of key surfaces in the geological record. This has broad implications for non-marine sequence stratigraphy.     

Crystal chemistry of amphiboles: implications for oxygen fugacity and water activity in lithospheric mantle beneath Victoria Land,Antarctica

Amphibole is the hydrous metasomatic phase in spinel-bearing mantle xenoliths from Baker Rocks, Northern Victoria Land, Antarctica. It occurs in veins or in disseminated form in spinel lherzolites. Both types derive from reaction between metasomatic melts and the pristine paragenesis of the continental lithospheric mantle beneath Northern Victoria Land. To determine the effective role of water circulation during the metasomatic process and amphibole formation, six amphibole samples were fully characterized. Accurate determination of the site population and the state of dehydrogenation in each of these amphiboles was carried out using single-crystal X-ray diffraction, electron microprobe and secondary ion mass spectroscopy on the same single crystal. The Fe³⁺/ΣFe ratio was determined by X-ray absorption near edge spectroscopy on amphibole powder. The degree of dehydrogenation determined by SIMS is 0.870–0.994 O3(O^2?) a.p.f.u., primary and ascribed to the Ti-oxy component of the amphibole, as indicated by atom site populations; post-crystallization H loss is negligible. Estimates of aH₂O (0.014–0.054) were determined from the dehydration equilibrium among end-member components assuming that amphiboles are in equilibrium with the anhydrous peridotitic phases. A difference up to 58 % in determination of aH₂O can be introduced if the chemical formula of the amphiboles is calculated based on 23 O a.p.f.u. without knowing the effective amount of dehydrogenation. The oxygen fugacity of the Baker Rocks amphibole-bearing mantle xenoliths calculated based upon the dissociation constant of water (by oxy-amphibole equilibrium) is between ?2.52 and ?1.32 log units below the fayalite–magnetite–quartz (FMQ) buffer. These results are systematically lower and in a narrow range of values relative to those obtained from anhydrous olivine–orthopyroxene–spinel equilibria (fO₂ between ?1.98 and ?0.30 log units). A comparative evaluation of the two methods suggests that when amphibole is present in mantle peridotites, the application of oxy-amphibole equilibrium is preferred, because ol–opx–sp oxy-calibrations are not “sensitive” enough in recording the effects (if any) of amphibole in the peridotite matrix. Amphibole acts as the main H acceptor among the peridotite minerals and may prevent fluid circulation and buffer oxygen fugacity. The important conclusion of this study is that amphibole within the lithospheric mantle does not always means high water activity and oxidizing conditions.