Brownish inclusions and dark streaks in Libyan Desert Glass: Evidence for high‐temperature melting of the target rock

Abstract– Dark streaks and different types of inclusions in Libyan Desert Glass (LDG) collected from the LDG strewn field in Egypt were investigated. Rare transparent spherules enclosed in the glassy matrix are characterized by concentric cracks, irregular internal cracks, intense twinning, and considerable amounts of Ti and Al. Raman spectra show that the spherules are α‐cristobalite. Their occurrence together with lechatelierite indicates quick heating of the source rock to at least 1550 °C, followed by rapid quenching leading to crystallization of β‐cristobalite, which upon cooling inverted into α‐cristobalite. Brownish inclusions are irregularly shaped, elongated objects with smooth contacts to the surrounding glass. They contain small roundish to elliptical droplets, and a few larger angular grains, which compositionally and according to their Raman spectra most closely resemble low‐Ca, Al‐rich orthopyroxene. Composition and texture of the orthopyroxene suggest that the brownish inclusions formed by incomplete melting of an Al‐rich orthopyroxene bearing precursor, e.g., mafic phases present in desert surface sands or also of orthopyroxene‐bearing granulite dykes in the LDG target. Experimental data on Ca‐poor enstatite also support that the inclusions were heated to about 1550 °C. Analyses of dark streaks in LDG reveal high abundances of Al, Ti, Mn, Cr, Fe, and Ni and a pronounced correlation between the abundances of Cr, Mn, Fe, and Ni. As the Fe/Ni, Mn/Ni, and Cr/Ni ratios are all clearly nonchondritic, the source of this material is most likely terrestrial and the dark streaks studied here represent a different type of schlieren compared to those which contain a meteoritic component. These findings suggest LDG formation during a short high‐temperature event. Melting of Al‐rich orthopyroxene bearing target material seems to suggest an asteroid impact rather than a near‐surface airburst.     

Low-pressure Granulites of the Lisov Massif, Southern Bohemia: Visean Metamorphism of Late Devonian Plutonic Arc Rocks

The Liov Granulite Massif differs from neighbouring granulitebodies in the Moldanubian Zone of southern Bohemia (Czech Republic)in including a higher proportion of intermediate–maficand orthopyroxene-bearing rocks, associated with spinel peridotitesbut lacking eclogites. In addition to dominantly felsic garnetgranulites, other major rock types include quartz dioritic two-pyroxenegranulites, tonalitic granulites and charnockites. Minor bodiesof high-pressure layered gabbroic garnet granulites and spinelperidotites represent tectonically incorporated foreign elements.The protoliths of the mafic–intermediate granulites (quartz-dioriticand tonalitic) crystallized 360–370 Ma ago, as indicatedby laser ablation inductively coupled plasma mass spectrometryU–Pb ages of abundant zircons with well-preserved magmaticzoning. Strongly metamorphically recrystallized zircons giveages of 330–340 Ma, similar to those of other Moldanubiangranulites. For the overwhelming majority of the Liov granulitespeak metamorphic conditions probably did not exceed 800–900°Cat 4–5 kbar; the equilibration temperature of the pyroxenegranulites was 670–770°C. This is in sharp contrastto conditions of adjacent contemporaneous Moldanubian granulites,which are characterized by a distinct HP–HT signature.The mafic–intermediate Liov granulites are thought tohave originated during Viséan metamorphic overprintingof metaluminous, medium-K calc-alkaline plutonic rocks thatformed the mid-crustal root of a Late Devonian magmatic arc.The protolith resembled contemporaneous calc-alkaline intrusionsin the European Variscan Belt. KEY WORDS: low-pressure granulites; geothermobarometry; laser-ablation ICP-MS zircon dating; whole-rock geochemistry; Sr–Nd isotopes; Moldanubian Zone     

Dendroclimatic studies on conifers from central Europe and Great Britain

Schweingruber, Fritz H., BrÄker, Otto U. & SchÄr, Ernst 1979 1201: Dendroclimatic studies on conifers from central Europe and Great Britain. Boreas, Vol. 8, pp. 427–452. Oslo. ISSN 0300–9483. The use of X-ray densitometry for measuring tree rings makes it possible to consider the relations between climate and tree rings in a new light. Investigations so far have shown that it is the maximum density of the annual rings that provides the most important and best climatological information. Comparisons between density sequences are possible when the tree-ring samples come from ecologically similar sites. Site characteristics are expressed by six different tree-ring parameters. Relations between the maximum densities of various species from different regions are revealed by calculating the percentage of agreement. The growth rate of cell walls in latewood of all coniferous species from cool humid regions is limited mainly by summer temperatures. In Scotland, where the climate is cool-oceanic and relatively stable, the cell walls grow from June to October. In the subalpine zone of the Alps and the Rocky Mountains near the timber line growth takes place mainly in August and September. Maximum density in trees of temperate sites is also primarily influenced by the summer temperature. Minimum density shows the relationship to the xerothermic site characteristics. On dry sites cambial activity and cell wall growth in latewood are mainly limited by precipitation during the growth period. Samples from the subalpine zones (1500–2200 m above sea level) between latitudes 45d? and 50d? North, i.e. those from the Western Carpathians, the Alps, and the Northern Appalachian Mountains, seem to form a unity. Samples from the oceanic region (20–600 m above sea level) between 52d? and 58d?N latitudes show a different and incoherent picture. Only the present low level density during 1950–1975 is evident at all sites investigated for the last 200 years. By cross-dating the annual tree-ring sequences of living trees with samples of timber taken from ancient houses a 700-year-long chronology has been developed for the Northern Prealps in Switzerland. This chronology shows the approximate annual and decennial temperature changes; the sensitivity curve shows the different climatic variability in temperature.     

Comparison of land cover maps using fuzzy agreement

A generic problem associated with different land cover maps that cover the same geographical area is the use of different legend categories. There may be disagreement in many areas when comparing different land cover products even though the legend shows the same or very similar land cover class. To capture the uncertainty associated with both differences in the legend and the difficulty in classification when comparing two land cover maps, expert knowledge and a fuzzy logic framework are used to map the fuzzy agreement. The methodology is illustrated by comparing the Global Land Cover 2000 data set and the MODIS global land cover product. Overall accuracy measures are calculated, and the spatial fuzzy agreement between the two land cover products is provided. This approach can be used to improve the overall confidence in a land cover product, since areas of severe disagreement can be highlighted, and areas can be identified that require further attention and possible re-mapping.     

Shock experiments in support of the Lithopanspermia theory: The influence of host rock composition,temperature, and shock pressure on the survival rate of endolithic and epilithic microorganisms

Abstract– Shock recovery experiments were performed with an explosive set‐up in which three types of microorganisms embedded in various types of host rocks were exposed to strong shock waves with pressure pulse lengths of lower than 0.5 μs: spores of the bacterium Bacillus subtilis, Xanthoria elegans lichens, and cells of the cyanobacterium Chroococcidiopsis sp. 029. In these experiments, three fundamental parameters were systematically varied (1) shock pressures ranging from 5 to 50 GPa, (2) preshock ambient temperature of 293, 233 and 193 K, and (3) the type of host rock, including nonporous igneous rocks (gabbro and dunite as analogs for the Martian shergottites and chassignites, respectively), porous sandstone, rock salt (halite), and a clay‐rich mineral mixture as porous analogs for dry and water‐saturated Martian regolith. The results show that the three parameters have a strong influence on the survival rates of the microorganisms. The most favorable conditions for the impact ejection from Mars for microorganisms would be (1) low porosity host rocks, (2) pressures <10–20 GPa, and (3) low ambient temperature of target rocks during impact. All tested microorganisms were capable of surviving to a certain extent impact ejection in different geological materials under distinct conditions.     

The P–T–X(fluid) evolution of meta‐anorthosites in the Eastern Granulites,Tanzania

Meta‐anorthosite bodies are typical constituents of the Neoproterozoic Eastern Granulites in Tanzania. The mineral assemblage (and accessory components) is made up of clinopyroxene, garnet, amphibole; scapolite, epidote, biotite, rutile, titanite, ilmenite and quartz. Within the feldspar‐rich matrix (70–90% plagioclase), mafic domains with metamorphic corona textures were used for P–T calculations. Central parts of these textures constitute high‐Al clinopyroxene – which is a common magmatic mineral in anorthosites – and is therefore assumed to be a magmatic relict. The clinopyroxene rims have a diopsidic composition and are surrounded by a garnet corona. Locally the pyroxene is surrounded by amphibole and scapolite suggesting that a mixed CO₂–H₂O fluid was present during their formation. Thermobarometric calculations give the following conditions for the metamorphic peak of the individual meta‐anorthosite bodies: Mwega: 11–13 kbar, 850–900 °C; Pare Mountains: 12–14 kbar, 850–900 °C; Uluguru Mountains: 12–14 kbar, 850–900 °C. The P–T evolution of these bodies was modelled using pseudosections. The amount and composition of the metamorphic fluid and <0.5 mol.% fluid in the bulk composition is sufficient to produce fluid‐saturated assemblages at 10 kbar and 800 °C. Pseudosection analysis shows that the corona textures most likely formed under fluid undersaturated conditions or close to the boundary of fluid saturation. The stabilities of garnet and amphibole are dependent on the amount of fluid present during their formation. Mode isopleths of these minerals change their geometry drastically between fluid‐saturated and fluid‐undersaturated assemblages. The garnet coronae developed during isobaric cooling following the metamorphic peak. The cooling segment is followed by decompression as indicated by the growth of amphibole and plagioclase. The estimated of the metamorphic fluid is ～0.3–0.5. Although the meta‐anorthosites have different formation ages (Archean and Proterozoic) they experienced the same Pan‐African metamorphic overprint with a retrograde isobaric cooling path. Similar P–T evolutionary paths are known from the hosting granulites. The presented data are best explained by a tectonic model of hot fold nappes that brought the different aged anorthosites and surrounding rocks together in the deep crust followed by an isobaric cooling history.     

Biosedimentology of the Early Jurassic post-extinction carbonate depositional system, central High Atlas rift basin, Morocco

This study documents a Liassic example of the long‐ranging effects of mass extinction on carbonate systems. Biohistoric constraints inherent in the Liassic carbonate depositional system are deciphered from normal‐marine, sub‐tidal deposits of the central High Atlas rift basin (Morocco) through ?Hettangian/Sinemurian to Early Toarcian times. The integration of results from the analysis of lithofacies, depositional geometries, microfacies, macrobenthos, carbonate build‐ups, carbon and oxygen stable isotopes, and rare earth element + yttrium distribution patterns allows the intrinsic (or biohistoric) control on the central High Atlas deposits to be separated from extrinsic factors, such as basin development and palaeoclimate. The survival interval in the aftermath of the end‐Triassic mass extinction persisted until the Early Sinemurian indicated by a severely depleted carbonate system impoverished in skeletal organisms. A tectonic pulse at the Early to Late Sinemurian boundary interval caused a basin widening with immigration of a marine fauna. However, until the latest Sinemurian (macdonelli Subzone of the raricostatum Zone) the deposits were dominated by filter‐feeding benthic heterotrophs (sponges, brachiopods, polychaetes and crinoids). During this stage, primary production within the enlarged basin must have been largely planktonic and there was a net‐flux of organic matter to the sea floor (oxygen minimum zone). A regional radiation of organic‐walled phytoplankton is inferred to explain the selective success of the filter‐feeding community and the occurrence of sponge mounds. Thus, significant effects of the end‐Triassic mass extinction are still present during the Late Sinemurian. Through almost the entire Pliensbachian a highly productive, shoal‐rimmed carbonate platform existed; it developed subsequent to tectonic reorganization and a marine recirculation event (radiolarian facies, Δδ¹³C ≈ ?1·1, strongly negative Ce‐anomaly). Photosymbiotic sediment producers (mainly large bivalves) now state the success of specialists and environmental equilibrium conditions. In the latest Pliensbachian the climax stage was reached with the development of a coralgal reef‐rimmed carbonate platform. The Liassic carbonate depositional system experienced a terminal, multicausal Early Toarcian drowning event during which most of the large bivalves became extinct.     

Geochemistry and origin of a black mudstone in a volcaniclastic environment, Ordovician Lower Rhyolitic Tuff Formation, North Wales, UK

Black mudstones in marine volcaniclastic environments have been interpreted both as non-volcanic ‘background’sedimentation and as fine grained vitric dust from the waning stages of primary volcanism. Although difficult to distinguish by standard petrographic techniques, differentiation between the two is crucial when attempting to determine sedimentation rates or to infer periods of volcanic quiescence. In the Ordovician Lower Rhyolitic Tuff Formation of North Wales such a fine grained black unit at Cwm Idwal is geochemically similar to an underlying rhyolite ash flow tuff. Its chemical index of alteration (CIA) is identical to that of the tuff. These data suggest that the black mudstone unit is a vitric tuff related to the underlying ash flow tuff. Use of a CIA in addition to trace element geochemistry should, in most cases, serve to distinguish tuffs from silicified mudstones.