Phase Equilibrium Constraints on Intensive Crystallization Parameters of the Ilimaussaq Complex, South Greenland

The 1·13 Ga Ilímaussaq intrusive complex, SouthGreenland, is composed of various types of alkali granite andsilica-undersaturated alkaline to agpaitic nepheline syenitesrelated to three subsequently intruded magma batches. Mineralchemistry indicates continuous fractionation trends within eachrock type, but with distinct differences among them. The last,peralkaline magma batch is the most fractionated in terms ofX_Fe^{mafic mineral}, feldspar composition and mineral assemblage.This indicates that an evolving magma chamber at depth discontinuouslyreleased more highly fractionated alkaline melts. Fluid inclusionsin some sodalites record a pressure drop from 3·5 to1 kbar indicating that crystallization started during magmaascent and continued in the high-level magma chamber. On thebasis of phase equilibria and preliminary fluid inclusion data,crystallization temperature drops from >1000°C (augitesyenite liquidus) to <500°C (lujavrite solidus) and silicaactivity decreases from     

Post‐Glacial immigration of the harbour porpoise (Phocoena phocoena) into the Baltic Sea*

At the end of the Pleistocene, environmental conditions in the Baltic Basin were affected by the melting glaciers and the resultant freshwater bodies. In contrast to various seal species, there is no subfossil evidence of the harbour porpoise (Phocoena phocoena) from the early Holocene stages of the Baltic Basin. This article is an attempt to clarify the colonization of the harbour porpoise into the Baltic Sea and to reveal the ecological background of this process. All published Holocene subfossil records from the porpoise in the Baltic region were sought and supplemented with those from museums and zoological collections; 148 records document the porpoise's occurrence. The earliest records of the harbour porpoise date from the time between 9600 and 7000 cal. yr BP and originate from the early and middle Mesolithic coastal settlements of the Maglemose and Kongemose culture during the early Littorina stage. Around 7500–5700 cal. yr BP, the porpoise is recorded frequently at many localities from late Mesolithic (Ertebølle culture) and Neolithic in the coastal areas of the western Baltic Sea, as well as for the first time in the Gulfs of Bothnia and Finland. Since 4000 cal. yr BP, P. phocoena has only been recorded in the western Baltic. We suggest that immigration and dispersion of P. phocoena into the Baltic Sea was connected with the Littorina transgression beginning around 9000 cal. yr BP. The continuous influx of seawater and the associated ecological changes led to a new, very species‐rich, fish community and adequate living conditions for the harbour porpoise.     

Structure and evolution of a Messinian mixed carbonate‐siliciclastic platform: the role of evaporites (Sorbas Basin,South‐east Spain)

The Sorbas Member is a late Messinian complex sedimentary system that formed immediately following deposition of the Messinian evaporites in the Sorbas Basin (South‐east Spain). This work describes the sequence architecture and facies organization of a continuous kilometre long, alluvial fan to open platform transect near the village of Cariatiz in the north‐east of the basin. The post‐evaporitic Cariatiz platform was a mixed carbonate‐siliciclastic system composed of four intermediate‐frequency, fifth‐order depositional sequences (Depositional Sequences 1 to 4) arranged in an overall prograding trend. The intense fracturing and brecciation of these deposits is attributed to the deformation and dissolution of an evaporite body measuring several tens of metres in thickness. The four sequences display significant spatial–temporal variability in both architecture and facies distribution, with two main phases: (i) Depositional Sequences 1 and 2 are ooid and oobioclastic dominated, and show normal marine faunas; and (ii) Depositional Sequences 3 and 4 show a higher siliciclastic contribution and are microbialite dominated. These important changes are interpreted as modifications of the primary controlling factors. Following an initial 70 m drowning, possibly linked to increased oceanic input, Depositional Sequences 1 to 3 were controlled mainly by eustatic variations and inherited topography; their progradation destabilized the evaporite body near the end of the Depositional Sequence 2 period. During the second phase, Depositional Sequences 3 and 4 recorded a progressive restriction of the Sorbas Basin related to a 30 to 40 m fall in water level that was driven mainly by regional factors. These regional factors were dissolution and gravity‐induced deformation of the evaporites and correlative evaporative fluid circulation associated with the contrasted arid/humid regional climate that, respectively, controlled sequence geometry and fluctuating water salinity which caused a microbialite bloom.     

TEMPERATURE EFFECT ON PRECIPITATION OF CALCIUM CARBONATE FROM CALCIUM BICARBONATE SOLUTIONS AND ITS APPLICATION TO CAVERN ENVIRONMENTS

Solutions of calcium bicarbonate were allowed to lose carbon dioxide and evaporate to dryness under controlled temperature conditions. With filtered solutions prepared from spar calcite, precipitates were 100% calcite in the 2° to 100°C temperature range. When, in analogous experiments, coralline aragonite was the starting material, the precipitates were 100% calcite. Essentially the same was true when carbonate rocks from karst areas were used to prepare the experimental solutions. An artificially prepared mixture (maximum crystal size of about 7 u) of 70% aragonite and 30% calcite was also used in the study. The precipitates from this starting material were apparently affected by seed nuclei which passed through the filter. The stability of calcium carbonate seed nuclei appears to vary with temperature. Natural calcium bicarbonate solutions from caves yielded only calcite at 25°C. Calcite should be the dominant or only polymorph of CaCO₃ formed by the loss of carbon dioxide and evaporation of natural calcium bicarbonate solutions if temperature is the controlling factor. Since appreciable amounts of aragonite are found in many cave deposits, factors other than temperature must influence the polymorphs formed. POBEGUIN (1955) proposed that rapid evaporation and slow diffusion of solutions favor aragonite. If so, layers of aragonite and calcite in speleothems may reprsent alternate wet and dry paleoclimates. During these periods, rate of introduction of solution and rate of evaporation would change markedly.     

Mid-crustal Metasomatic Reaction Veins ina Spinel Peridotite

In Central Dronning Maud Land, East Antarctica, rare metre-sizedlenses of spinel peridotite are enclosed in high-grade metamorphicrocks. The rocks experienced a medium-P granulite-facies metamorphismat 575 Ma and a low-P amphibolite-facies overprint at 530 Ma.The latter is probably related to extensive granitoid magmatismbetween 530 and 500 Ma, which produced large volumes (abouthalf of the outcrops today) of granitic to syenitic rocks aswell as abundant K-feldspar–quartz pegmatites. One ofthe spinel peridotite lenses in the Schirmacher Oasis of CentralDronning Maud Land is crosscut by several small (up to 10 cmwide) veins with a characteristic zoned sequence of mineralassemblages, which was formed by reaction of a hydrous, SiO₂-saturatedfluid or pegmatitic melt with the peridotite. The zoned sequenceconsists of the following mineral assemblages (from the centreof the vein towards the outer margin): zone 0, plagioclase +quartz; zone 1, green biotite intergrown with zircon + clinoamphibole;zone 2, cummingtonite + dark brown biotite intergrown with rutile+ clinoamphibole; zone 3, cummingtonite + light brown biotite+ spinel; zone 4, olivine + orthopyroxene + spinel ±clinopyroxene (unaltered peridotite). This sequence was investigatedwith respect to its conditions of formation, modal mineralogy,mineral chemistry, fluid inclusions, and oxygen and hydrogenisotope compositions of selected minerals. Based on the stabilityof cummingtonite and on equilibrium calculations in the MgO–SiO₂–H₂Osystem and on quartz–biotite oxygen isotope thermometry,the reaction vein formed at 650°C, which is in accord withtypical pegmatite crystallization temperatures. The pegmatiteof zone 0 is interpreted to have formed in an open fissure whereas,on textural grounds, zone 3 replaces former peridotite. On thebasis of mass balance constraints, the boundary between zones1 and 2 is interpreted to approximately represent the formerboundary between peridotite and the open fissure before reaction.Oxygen isotope systematics show that the infiltrating fluidhad an isotopic composition of 9–10 SMOW. All mineralsof the reaction vein with the exception of the inherited spineland olivine in the adjacent peridotite are in equilibrium withsuch a fluid. Spinel in the peridotite is depleted in ¹⁸O comparedwith coexisting olivine, which suggests isotopic disequilibrium.Spinel in zone 3 has a distinctly different isotopic compositioncompared with that in the peridotite, apparently approachingbut not reaching equilibrium. The combination of mineral chemistryand mass balance constraints of the modal mineralogy constrainsthe volume change during metasomatism and the direction of elementaldiffusion. It is indicated that Mg, Cr and Ni always diffusedtowards the vein, whereas Si, Al, K, Na, H₂O and possibly Fediffused into the peridotite. KEY WORDS: peridotite; metasomatism; pegmatite; diffusion; reaction     

Deep-water resedimentation of anhydrite and gypsum deposits in the Middle Miocene (Belayim Formation) of the Red Sea, Egypt

The Middle Miocene evaporites in the Red Sea rift were deposited within a complex system of fault-bounded basins that were episodically active during sedimentation. Such a tectonic framework is known to be highly favourable to resedimentation processes. An offshore petroleum well in the north-western Red Sea has cored, below a massive salt unit, an anhydrite-bearing succession which provides an excellent opportunity to study the processes of gravity induced redeposition of Ca-sulphates in a deep basin. Anhydrite deposits, interbedded with siliciclastic layers and thin halite layers, are composed of resedimented facies ranging from fine-grained laminated sediments to coarse-grained breccias. The components derive from the reworking of shelf sediments deposited initially in shallow water to supratidal settings on the surface and edges of structural highs bordering depressions: proximal siliciclastic deposits with interstitial anhydrite (cement patches, nodules) or gypsum and dolostones with early diagenetic anhydrite facies (nodular, chicken-wire) formed in sabkha conditions, interstitially grown gypsum crystals and subaqueous gypsum crusts precipitated in hypersaline ponds, and diatom-rich oozes formed in marine, shallow-water conditions. The homogeneity of the stable isotope composition and petrography of sulphates argue for the initial crystallization of Ca-sulphates within brines of the same origin and in closely interconnected sedimentary settings. The unconsolidated sediments redeposited as slope-foot accumulations were carried both as anhydrite (nodules, soft masses, various fragments, individual grains or crystals released by disintegration of large masses) and gypsum (crystalline aggregates or single crystals) later converted to anhydrite during burial. Layers of chaotic breccia are interpreted as the result of seismic events, whereas the fine-grained deposits could be related to redistribution by nepheloid layers of suspensions of finer grains released by disintegration of the soft anhydrite masses during downslope transport, or of in situ deposits removed by the turbiditic flows.     

Long‐term summer (AD751–2008) temperature fluctuation in the French Alps based on tree‐ring data

Corona, C., Edouard, J.‐L., Guibal, F., Guiot, J., Bernard, S., Thomas, A. & Denelle, N. 2010: Long‐term summer (AD751–2008) temperature fluctuation in the French Alps based on tree‐ring data. Boreas, 10.1111/j.1502‐3885.2010.00185.x. ISSN 0300‐9843. On the basis of a dense tree‐ring width network (34 unpublished multi‐centennial larch chronologies), this paper attempts to reconstruct, for the first time, the summer temperatures in the French Alps (44°–45.30°N, 6.30°–7.45°E) during the last millennium. The adaptative Regional Growth Curve standardization method is applied to preserve interannual to multi‐centennial variations in this high‐elevation proxy data set. The proxies are calibrated using the June to August mean temperatures from the last revised version of the HISTALP database spanning the period AD1760–2003 and adjusted to take into account the warm bias before 1850. About 45% of the temperature variance is reconstructed. Despite the use of the newly updated meteorological data set, the reconstruction still shows colder temperatures than early instrumental measurements between 1760 and 1840. The proxy record evidences a prolonged Medieval Warm Period persisting until 1500, with warm periods that resemble 20th century conditions but also cold phases before 1000 synchronous with Swiss glacier advances. The Little Ice Age is rather mild until 1660 if compared with other Alpine reconstructions. Thereafter, summers are 0.7 °C cooler than the 1961–1990 mean until 1920. The maximum temperature amplitude over the past 1250 years is estimated to be 3 °C between the warmest (810s, 1990s) and coldest (1810s) decades. Most of the 20th century is comparable with the Medieval Warm Period.