Distribution of trace metals in the Odra River system: Water–suspended matter–sediments

Extensive investigations of trace metals concentrations in water, suspended particulate matter (SPM) and bottom sediments of the whole Odra River system were carried out over the years 1997–2000. The vertical distribution of selected metals and their mobility were also studied in the sediment cores from upper and middle river sections. Significant levels of metal contamination were found. Median concentrations (Cd, Pb, Cu, Zn and As) in the SPM and sediments were (mg kg⁻¹) 7.1 and 8.9 Cd, 128 and 146 Pb, 81 and 119 Cu, 1198 and 1204 Zn, 48 and 54 As, respectively. The highest metal pollution of the Odra River solids was found with cadmium, zinc, lead and arsenic, showing high similarity in their frequency distributions in both SPM and sediments. Cd, Zn and As appear to be of particular concern because of the high levels, that appear to be bioavailable, and their high mobility. The exchangeable and carbonate chemical forms of Cd and Zn reached up to 50% of their total amount. Besides the determination of total metal concentration, the metal chemical forms in river solids were investigated. The results of very wide studies of the Odra River system through 4 years suggest that metal pollution decreased, especially for Zn, Pb and Cu. Among all metals studied in the Odra River sediments, substantial reductions of Cd contamination were observed neither in the period after ’97 flood, nor if compared with the earlier results obtained before ’97. No essential differences of the metal contents were observed among the samples for the same river compartment, from the same locality, taken within the five sampling campaigns. The pattern of spatial and vertical metal distributions in the river solids indicates that a variety of sources might be responsible for the contamination; very intensive, historical and current mining and smelting activities probably are the most important ones.     

Origin of minerals with intermediate chlorite-vermiculite structure (Szklary, Poland)

The vermiculite-like minerals show varied relative intensities of basal reflections and do not collapse fully when saturated with K and heated up to 700°C.

Transmission oblique texture X-ray diffraction patterns were used to determine a continuous series of the vermiculite-chlorite intermediate structures. Relative diffraction intensities in the region (060) were correlated with the amount of water released at 500–700°C to show that the investigated samples belong to two structurally distinctive series: vermiculitic and chloritic types. The structural premises indicate that the parent mineral for the chloritic intergrades should be chlorite and that for the vermiculitic series phlogopite.     

Types of sedimentary environment in alluvial sediments distinguished on the basis of its chemical constitution: the example of the lower course of the Obra river (Western Poland)

Research concerning chemical constitution of alluvial sediments was done in the lower course of the Obra river (Western Poland). The fragment of vertical profile, which consisted of various alluvial sediments (fine sands, peats, and sandy silts) was chosen for detailed analysis. The main research problem was to determine if lithology and chemical constitution of alluvial deposits are interconnected in a distinct way within studied section of the Obra river valley, and, if changes of chemical elements’ concentration could be used to illustrate depositional processes, which take place in riverbed and floodplain. Concentrations of Fe, Mn, Cu, Zn, Ca, Mg, and K were determined in collected sediment samples. Next, geochemical groups of alluvial sediments were distinguished using cluster analysis. Investigated changes of chemical elements’ concentration show that there is a distinct border between the environment of organic sediments, which marks the place of former functioning of the Obra riverbed, and sandy silts, which were deposited within floodplain during floods. Besides, floodplain sediments, riverbed sediments, and reductive environment within peat deposits were singled out on the basis of the analysis.     

Natural Radioactivity at the Sin Quyen Iron-Oxide-Copper-Gold Deposit in North Vietnam

The field radiometric and laboratory measurements were performed at the Sin Quyen copper deposit in North Vietnam. The field gamma-ray spectrometry indicated the concentration of uranium ranging from 5.5 to 87 ppm, thorium from 5.6 to 33.2 ppm, and potassium from 0.3 to 4.7%. The measured dose rates ranged from 115 to 582 nGy/h, the highest doses being at the copper ore. Concentrations in the solid samples were in the range of 20–1700 Bq/kg for uranium, 20–92.7 Bq/kg for thorium, and 7–1345 Bq/kg for potassium. The calculated doses were from 22 to 896 nGy/h; both measured and calculated dose rates are mostly related to uranium. Concentrations of radium in water samples were below 0.17 Bq/L. Uranium in water samples was significantly higher than the hydrogeological background; the maximum of 13 Bq/L was at the waste zone pool, but neither radium nor uranium were present in tap water. Radon concentration in the dwelling air was from 42 to 278 Bq/m³ for ²²²Rn and from 8 to 193 Bq/m³ for ²²⁰Rn. The estimated committed dose rates were principally related to ²²²Rn concentration and ranged from 1.1 to 8.1 mSv/y.     

Thermal conduction between an accretion disc and a corona in active galactic nuclei: vertical structure of the transition layer

We study the vertical structure of the transition layer between an accretion disc and a corona in the context of the existence of a two-phase medium in thermally unstable regions. The disc is illuminated by hard X-ray radiation, and satisfies the condition of hydrostatic equilibrium. We take into account the energy exchange between the hot, Compton-heated corona (∼10⁸ K) and cool disc (∼10⁴ K) arising from both radiative processes and thermal conduction. In the case including thermal conduction, we perform a local stability analysis, and conclude that thermal conduction does not suppress thermal instability. In spite of the continuous temperature profile T ( τ ) there are regions of strong temperature gradient, in which spontaneous perturbations can lead to cloud condensation in the transition layer. We determine the minimum size λ _TC of such a perturbation.     

Improvement of the geoid in local areas by satellite gradiometry

Summary Satellite gradiometry is studied as a means to improve the geoid in local areas from a limited data coverage. Least-squares collocation is used for this purpose because it allows to combine heterogeneous data in a consistent way and to estimate the integrated effect of the attenuated spectrum. In this way accuracy studies can be performed in a general and reliable manner. It is shown that only three second-order gradients contribute significantly to the estimation of the geoidal undulations and that it is sufficient to have gradiometer data in a 5°×5° area around the estimation point. The accuracy of the geoid determination is strongly dependent on the degree and order of the reference field used. An accuracy of about ±1 m can be achieved with a reference field of (12, 12). There is an optimal satellite altitude for each reference field and this altitude may be higher than 300 km for a field of low degree and order. The influence of measuring errors is discussed and it is shown that only gradiometer data with accuracies better than ±0.05 E will give a significant improvement of the geoid. Finally, some results on the combination of satellite gradiometry and terrestrial gravity measurements are given. The proposed method seems to be well suited for local geoid determinations down to the meter range. It is especially interesting for unsurveyed and difficult areas because no terrestrial measurements are necessary. Furthermore, it has the practical advantage that only a local data coverage is needed.     

Root‐related rhodochrosite and concretionary siderite formation in oxygen‐deficient conditions induced by a ground‐water table rise

Sedimentological, mineralogical, stable carbon and oxygen isotope determinations and biomarker analyses were performed on siderite concretions occurring in terrestrial silts to understand their formation and to characterize the sedimentary and diagenetic conditions favouring their growth. High δ¹³C values (6·4‰ on average) indicate that siderite precipitated in an anoxic environment where bacterial methanogenesis operated. The development of anoxic conditions during shallow burial was induced by a change in sedimentary environment from flood plain to swamp, related to a rise of the ground‐water table. Large amounts of decaying plant debris led to efficient oxygen consumption within the pore‐water in the peat. Oxygen depletion, in combination with a decrease in sedimentation rate, promoted anoxic diagenetic conditions under the swamp and favoured abundant siderite precipitation. This shows how a change in sedimentary conditions can have a profound impact on the early‐diagenetic environment and carbonate authigenesis. The concretions contain numerous rhizoliths; they are cemented with calcium‐rhodochrosite, a feature which has not been reported before. The rhodochrosite cement has negative δ¹³C values (?16·5‰ on average) and precipitated in suboxic conditions due to microbial degradation of roots coupled to manganese reduction. The exceptional preservation of the epidermis/exodermis and xylem vessels of former root tissues indicates that the rhodochrosite formed shortly after the death of a root in water‐logged sediments. Rhodochrosite precipitated during the initial stages of concretionary growth in suboxic microenvironments within roots, while siderite cementation occurred simultaneously around them in anoxic conditions. These suboxic microenvironments developed because oxygen was transported from the overlying oxygenated soil into sediments saturated with anoxic water via roots acting as permeable conduits. This model explains how separate generations of carbonate cements having different mineralogy and isotopic compositions, which would conventionally be regarded as cements precipitated sequentially in different diagenetic zones during gradual burial, can form simultaneously in shallow burial settings where strong redox gradients exist around vertically oriented permeable root structures.     

Differences in the abiotic parameters of water in coastal lakes in the light of the EU water framework directive: An example of the Polish southern Baltic coast

Coastal lakes have a specific hydrological regime determined by the influence of sea and inland water and the local hydrographic conditions. There are several problems concerning the protection and assessment of water quality of these bodies. The most important features differentiating coastal lakes from other lakes are: high salinity, a wide range of seasonal and short-term water quality changes, and specific aquatic ecosystems adapted to these conditions. These matters have not been sufficiently taken into account in the existing classifications and typologies of lakes in Poland. The problem has not been solved by the establishment of the adequate reference conditions and new guidelines for the classification of water status (which are being prepared according to the Common Strategy for the Implementation of the Water Framework Directive) regarding inland surface waters (rivers and lakes) and marine waters (coastal and transitional). An important issue is to define criteria which would help to distinguish all those hydrographic objects and to establish water quality standards for them.     

Sorption of carbon dioxide–methane mixtures

The paper reports the results of experiments concerning the sorption/desorption processes, observed under laboratory conditions, in two types of coal extracted from operational coal-mines in Poland, using CH₄ and CO₂ to observe their relative inter-reaction with the coal samples when introduced in varying proportions and conditions. Numerous studies concerning the sorption/desorption phenomena have described the operational mechanisms and the relationship of mine gases to the organically-created coal-body in mines. The differences in the behaviour of certain gases is twofold: firstly the essentially different characteristics of CO₂ and CH₄, and secondly the structure of the coal-bed itself: its degree of metamorphism and content of macerals. From the results yielded, it was observed that the divergence of the isotherms of sorption of CH₄ and other gases in comparison with the isotherms of sorption of CO₂ and a CO₂/CH₄ mixture differed and that the curve on the sorption isotherm was more clearly distinct after the introduction of CO₂ molecules to the system: coal with a higher degree of metamorphism—CH₄, which is closely related to the rigidity of the structure according to the level of metamorphism. Since coals with higher carbon content exhibit lower molecular bonding than low-carbonised coals, the characteristic feature of the bonds in the first case is their mobility. Knowledge of the physical and chemical properties of hard coals, as well as their interaction with mining gases, is of great use in solving problems concerned with the extraction of methane from mines or its storage in goafs.