Effects of over-consolidation history on flow instability of clean and silty sands

Acta Geotechnica - This article presents an experimental program under the constant volume condition to investigate the influence of over-consolidation on flow instability of clean and silty sand...     

Primary alteration—oxidation of marine algal organic matter from oil source rocks of the North Sea and Norwegian Arctic: new findings

The presence of partially oxidized algal organic matter in oil-prone marine source rocks, is the rule rather than the exception. Partially oxidized, algal kerogen can still act as a significant source of liquid hydrocarbons. However, the corresponding peak of C₁₂ + hydrocarbon generation is shifted to a considerably lower maturity level compared with that of the classical Type II kerogen. The extent of primary alteration-oxidation of marine algal kerogen is monitored by means of solid state microfluorescence spectroscopy. A new parameter, the Primary Alteration Factor (PAF) is established, and the relationships between PAF and H/C, O/C, HI, TOC and between PAF and %₀δ¹³C are determined. The present data show large variations in the bulk chemistry of immature marine algal kerogens, and reveal evidence for gradational dehydrogenation/oxidation of the source organic matter. This contrasts with the recently proposed mechanism for kerogen formation. SEM analysis reveals a relationship between the physical breakdown of algal organic matter and the formation of liptodetrinite. FTIR analysis shows that the incorporation of primary oxygen in the kerogen macromolecules is not in the form of carbonyl or carboxyl functionalities. The presence of highly unreactive, stable oxygen, associated with aromatic structures in partially oxidized algal kerogen, is suggested by resistance of the kerogen to graphitization. The FTIR data also suggest the presence of aryl ether oxygen. The present findings raise fundamental questions regarding the mechanisms of kerogen cracking and kerogen formation, and have important implications for petroleum exploration.     

Phytoremediation potential of native plants grown in the vicinity of Ahangaran lead–zinc mine (Hamedan,Iran)

This study aims to assess the extent of metal accumulation by plants found in a mining area in Hamedan Province in the central west part of Iran. It also investigates to find suitable plants for phytoextraction and phytostabilization as two phytoremediation strategies. Plants with a high bioconcentration factor (BCF) and low translocation factor (TF) have the potential for phytostabilization while plants with both BCFs and TFs greater than one have the potential to be used for phytoextraction. In this study, shoots and roots of the 12 plant species and the associated soil samples were collected. The collected samples were then analyzed by measurement of total concentrations of trace elements (Pb, Zn, Mn and Fe) using atomic absorption spectrophotometer. Simultaneously, BCF and TF parameters were calculated for each element. Results showed that although samples suitable for phytoextraction of Pb, Zn, Mn and Fe and phytostabilization of Fe were not detected, Scrophularia scoparia was the most suitable for phytostabilization of Pb, Centaurea virgata, Echinophora platyloba and Scariola orientalis had the potential for phytostabilization of Zn and Centaurea virgata and Cirsium congestum were the most efficient in phytostabilization of Mn. Present study showed that native plant species growing on contaminated sites may have the potential for phytoremediation.     

Accumulation of heavy metals in soil and uptake by plant species with phytoremediation potential

Contamination of heavy metals represents one of the most pressing threats to water and soil resources, as well as human health. Phytoremediation can be potentially used to remediate metal contaminated sites. In this study, concentrations of copper, zinc, iron, and magnesium accumulated by native plant species were determined in field conditions of Hame Kasi iron and copper mine in the central part of Iran in Hamadan province. The results showed that metal accumulation by plants differed among species and tissue bodies. Species grown in substrata with elevated metals contained significantly higher metals in plants. Metals accumulated by plants were mostly distributed in root tissues, suggesting that an exclusion strategy for metal tolerance exists widely amongst them. The mentioned species could accumulate relatively higher metal concentrations far above the toxic concentration in the plant shoots. With high translocation factor, metal concentration ratio of plant shoots to roots indicates internal detoxification metal tolerance mechanism; thus, they have potential for phytoextraction. The factors affecting metal accumulation by plant species including metal concentrations, pH, electrical conductivity, and nutrient status in substrata were measured. Mostly, concentrations of zinc and copper in both aboveground and underground tissues of the plants were significantly, positively related to their total in substrata, while iron, zinc, and copper were negatively correlated to soil phosphorus.     

Geological and laboratory evidence for early generation of large amounts of liquid hydrocarbons from suberinite and subereous components

Suberinite, and subereous components of amorphous nature, comprise largely unrecognized, proficient sources of liquid hydrocarbons. Due to difficulties in recognizing the presence of subereous components and suberinite in organic sediments, the contributions of these liptinitic components to the organic input of source rocks are easily underestimated. Severe chemical alterations of suberinite in the vitrinite reflectance range of R_o = 0.35–0.60% are demonstrated. Organic geochemical data, obtained from samples subjected to natural maturation, reveal that subereous components/suberinite undergoes early thermal degradation to generate large amounts of hydrocarbons below R_o = 0.60%. Data obtained from laboratory maturation of immature, suberinite-rich coals indicate that about 50% of the potential of suberinite for generating C₁₂₊ hydrocarbons has already been exhausted during natural maturation of the samples, prior to the onset of the traditionally defined “oil window”. The present data (a) contradict the assumption that suberinite is mainly sourced by selective preservation/enrichment of a stable, highly aliphatic biopolymer, i.e. “suberan” and (b) suggest that suberinite contains appreciable amounts of aliphatic and aromatic moieties which are released at low thermal stress.     

Assessment of changes in urban green spaces of Mashad city using satellite data

Green spaces play important functions in urban environments. Reducing air pollution, providing shade and habitat for arboreal birds, producing oxygen, providing shelter against winds, recreational and aesthetic qualities and architectural applications are the main functions of urban green spaces. With the rapid change of urban area in Mashad city during the past decades, green spaces have been fragmented and dispersed causing impairment and dysfunction of these important urban elements. The objective of this study was to detect changes in extent and pattern of green areas of Mashad city and to analyze the results in terms of landscape ecology principles and functioning of the green spaces. In this research, we classified a Landsat TM and an IRS LISS-III image belonging to the years 1987 and 2006, respectively. We then used a post-classification comparison to determine the changes in green space areas of Mashad city during the 19 years covered by the images. Then, we applied landscape ecology calculations to derive metrics that quantified pattern of the changes in the green areas. The results showed that during 19 years from 1987, a significant decrease had occurred in the extent of urban green spaces with a concomitant fragmentation resulting in downgrading and destruction of the functions and services these areas provide. We conclude that the general quality of life in the central parts of the city has been diminished. We also state that a combination of remote sensing image classification, landscape metrics assessment and vegetation indices can provide a tool for assessing life quality and its trend for urban areas.     

Late Holocene beetle assemblages and environmental change in Gammelhemmet,northern Sweden

Analysis of insect fossil remains retrieved from a bog close to the abandoned farm at Gammelhemmet, near Lycksele in Swedish Lapland, enabled the reconstruction of environmental changes at the site over the last 2500 years. These results represent the first late Holocene palaeoentomological succession studied for insect remains in the Västerbotten interior, and they provide new evidence for landscape change in the area. Around 2000 years ago, at the end of the early Iron Age, disappearance of the tree and leaf litter fauna and an increase in aquatic species indicate the expansion of wetlands in the area. Patches of a multi‐aged mixed woodland with a diverse assemblage of forest‐dwelling beetles succeeded the wetland ～1500 years ago, at the beginning of the late Iron Age. A marked change to open and drier conditions, and the presence of species often found in grassland and cultivated ground took place during the post‐Medieval period. Our evidence indicates drainage of the area prior to the 18th century, placing the initiation of agricultural activities in Gammelhemmet earlier than the documentary record. Our research shows the potential of the use of fossil insects for understanding environmental change and also human impact on the landscape, even of limited scale, from natural contexts.     

Integrated evaluation of urban development suitability based on remote sensing and GIS techniques: contribution from the analytic hierarchy process

Urban, industrial, and tourist developments are considered of high priority in Egypt. In the current research, the site suitability investigation for rating the different environmental, geological, and geotechnical conditions facing civil engineering projects were assessed using a geographic information system (GIS) multi-criteria approach. The study area is one of the most promising areas for urban and touristic as well as industrial developments in Egypt, which is located on the NW coast of the Gulf of Suez. This area may face several geo-environmental problems that will limit its suitability for civil projects. Weighted GIS model, which integrates different types of data sources, such as land use/cover, geological, geomorphological, geophysical, environmental, remote sensing, and field data, can be achieved to create a site suitability map. In this paper, an analytical hierarchy process approach has been used to develop the weighted model for different factors. As a result of this study, areas of potential geotechnical and geo-environmental hazards that could impact the design and construction of civil projects were identified. Therefore, changes can be made early in the design process before significant design efforts are being invested.