Mineralogy and geochemistry of fine-grained Dahab stream sediments,Southeastern Sinai,Egypt: emphasis on the intergrowths of Fe–Ti oxides

Acta Geochimica - Mineralogical and geochemical characteristics of stream sediments collected from 30 stations in the Dahab-Wadi Kid area (southeastern Sinai, Egypt) are presented. The studied...     

Upgrading of Oil Shale by Flotation Without Collector

Natural Resources Research - Oil shale impurities prevent its direct usage as a source of energy. Removing or reducing of these impurities before retorting can reduce the cost of oil shale...     

Composition,radioactivity, and possible applications of kaolin deposits of Sinai,Egypt

This work discusses the composition, radioactivity, and possible utilization of the kaolin resources in Sinai which are hosted in thick sandstone sequences belonging to the Carboniferous (Wadi Khaboba) and Early Cretaceous (Wadi Iseila and Abansakar) ages. The characterization of kaolin was done by microscopic and SEM examination, supported by XRD and ICP-MS analyses. The studied kaolin resources consist of kaolinite, as the main constituent, associated with subsidiary dickite and halloysite, and minor contribution of smectite and illite. The most dominant non-clay mineral is quartz, besides minor gypsum, dolomite, and hematite. Ferrugination dominates, in most cases, at the upper boundaries of the kaolin lenses, suggesting possible supergene activity. The high Al₂O₃/SiO₂ ratio for the Cretaceous kaolin (0.54, in average) specifies its better grade relative to the Carboniferous kaolin (0.43, in average). The kaolin of the middle part of lens C in Wadi Iseila contains Si/Al molecular ratio of about unity, suggesting high-grade kaolin. The Carboniferous kaolin has enriched the radionuclides: U, Th, and Ra (at disequilibrium state due to leaching of eU relative to Ra) and the REE, relative to that of the Cretaceous age. The Carboniferous kaolin is characterized by a higher contribution of HREE (zircon signature), whereas LREE seems to be more influential for the Early Cretaceous kaolin (monazite signature). In spite of the very high CIA index (93 to 99), none of the analyzed kaolin deposits displays Ce abnormality. The high radioactivity of some Carboniferous kaolin can be a serious impediment for its utilization or its exportation. The kaolin of Sinai does not satisfy the international standards for paperwork industries and refractory manufacturing, but beneficiation may overcome this challenge. However, some lenses have high-grade kaolin with a low percentage of oxides of iron, magnesium, calcium, sodium, and potassium and a low radioactivity, hence nominated for the local refractory industry. The high-grade kaolin of Sinai fulfills the standards required for ceramics manufacturing in the global market. Grade 3 kaolin (< 30%, Al₂O₃) can be used in the manufacturing of white Portland cement and red glaze manufacturing on both local and global markets.     

Mineralogical and geochemical studies on Abou-Sabouna phosphorites (Mahamied-Sharawna), upper Egypt,A. R. E.

Summary The Phosphate Formation of the Campanian-Maestrichtian in the Abou-Sabouna-Mine on the eastern side of the Nile Valley near Mamied was investigated mineralogically and geochemically. The phosphorite deposits are of the bedded type, containing collophane, francolite, smaller amounts of quartz, calcite, geothite and chlorite, rarely zircon. The phosphate material contains F^– (F/P₂O₅=0.089–0.094), as is characteristic for francolite.The phosphorites were deposited in a shallow marine environment with strong agitation. Diagenetic processes have changed the mineralogical and geochemical composition. Silification can be observed during diagenesis associated with accumulation of hematite.

---

Mineralogische und chemische Untersuchungen an Phosphoriten von Abou-Sabouna (Mahamied-Sharawna), Ober-Ägypten, Arabische Republik Ägypten

Zusammenfassung Die Phosphatformation des Campan-Maastricht der Abou-Sabouna-Mine, östlich des Niltales bei Mamied, wurde mineralogisch und geochemisch untersucht. Die Phosphatlagerstätte ist von lagerartigem Typ; sie enthält Collophan, Frankolith, untergeordnet Quarz, Calcit, Goethit und Chlorit, als Seltenheit Zirkon. Im Phosphat ist F^– mit einem F/P₂O₅-Verhältnis von 0,089 bis 0,094 nachzuweisen, was für Frankolith charakteristisch erscheint.Die Phosphorite wurden in einem flach marinen, stark durchbewegten Milieu abgesetzt. Diagenetische Prozesse haben die mineralogische und geochemische Zusammensetzung durch Silifizierung und Hämatitbildung verändert.

---

---

With 4 Figures     

Oil shale resources in Egypt: the present status and future vision

In Egypt, organic-rich sediments in the Duwi and Dakhla Formations of the Campanian-Danian age are customarily assigned as “oil shale” that occupies the middle latitudes of the country but may extend southward to Kurkur Oases. This oil shale belt has a vast worldwide extension, and it is considered as major oil- and gas-prone source rock in many places, especially in the Middle East. The sedimentation of the oil shale was triggered by the major transgression event that occurred during the Late Cretaceous. The lithology, type of kerogen, organic richness, and thickness of these organic-rich sediments vary markedly both on lateral and vertical scales. In Quseir area, the in-place geological reserves, of oil shale of the 800-kcal/kg quality, is estimated to be more than 9 billion tons that can produce 5.48 bbls equivalent upon retorting. Very optimistic resources are expected in the unexplored Nile Valley region. The factor analysis of data rank representing 1176 core samples and analysis of 58 major and trace elements besides Rock-Eval analyses point to five main controlling factors that control deposition of oil shale. The terrestrial indicators Al₂O₃, TiO₂, Fe₂O₃, and K₂O and the marine indicators Ca and Sr are oppositely loaded in the first factor. The second factor expresses the reducing conditions that prevailed during the deposition of the organic-rich marine environments. The euxinity of the basin is recognized by the third factor where sulfide and vanadium seem to be mutual. The fourth factor expresses the role of dolomitization while the fifth factor points to the humble role of oxidation. Considering the metric core samples, the highest TOC content recorded in the borehole drilled in Abu Tartur plateau is 3.6%, but it is about 14% for Quseir area. Regarding the spot samples in Quseir area, the highest TOC measured about 24%. It is not only the low TOC in Abu Tartur but also the kerogen type that is of type II + III, mostly of terrestrial origin (gas-prone) and lithology dominated by argillites. Organic richness is remarkable in Quseir-Safaga area, where the average TOC of 160-m-thick sequence is about 5%, with kerogen of type I or mixed I + II, mostly of marine origin (oil prone). The Dakhla Formation (Maastrichtian-Danian) is the richest in organic matter while Quseir Formation (Campanian) has the least organic richness and lowest kerogen quality. Detailed investigation on biomarkers confirms the relations among transgression, organic richness, kerogen type, and anoxic conditions. The organic matter is immature as witnessed by the low S1 values (<5%, in average), the low T _max (<430 °C), the low vitrinite reflectance (<0.4%), and biomarker signature. The variation in the S1 values between 1 and 9% is attributed to the influence of tectonics associating the Red Sea rift. In Quseir-Safaga area, there are particular prolific horizons of oil shale that seem to be visible for utilization by different technologies of combustion and retorting. The content of the heavy metals and uranium, as well as the spent, is a significant benefit. The faulting, dragging, and steep tilting of beds in the Quseir-Safaga area shall remain a serious challenge for extensive utilization of the estimated in-place geological reserves.     

Dahab stream sediments, southeastern Sinai, Egypt: a potential source of gold, magnetite and zircon

The stream sediments of Dahab area, southeastern Sinai, Egypt, were studied for their content of economic minerals. These sediments are immature as indicated by poor sorting and other mechanical parameters. They are derived from Precambrian basement rocks, which are mostly represented by granitic rocks in addition to lesser amounts of volcanics and gabbros. The mineralogical investigation revealed that these sediments contain considerable amounts of placer gold, Fe–Ti oxides and zircon.The concentrated Fe–Ti oxides comprise homogeneous magnetite and ilmenite in addition to ilmeno-magnetite, hemo-ilmenite and rutile–hematite intergrowths. Isodynamic separation of some raw samples of SIZE=1 mm revealed that up to 15.12% magnetic minerals can be recovered. Zircon shows remarkable variations in morphology, colour, chemistry and provenance. U-poor and U-rich varieties of zircon were discriminated containing UO₂ in the ranges of 0.04–1.19 and 3.05–3.68 wt.%, respectively. REE-bearing minerals comprise monazite, allanite and La-cerianite.On mineralogical basis, the present work suggests that Dahab stream sediments represent a promising target for further geochemical exploration for precious metals, especially gold. Fire assay data indicate that placer gold in the studied sediments sometimes reaches 15.34 g/t. Narrow gullies and valleys cutting the basement manifest the development and preservation of gold in this arid environment. Background concentration of gold and variation in lithology suggest multiple source of the metal in the investigated sediments.     

Geochemical constraints and uranium potential of the younger granitic rocks in El Maghrbia area,Central Eastern Desert,Egypt

Acta Geochimica - The present work deals with the mineralogy, geochemical behavior and uranium potentiality of the monzogranites of El Maghrbia area, which comprise G. El Maghrbia and G. El Eredyia...