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Results of experimental study at 7.0–8.5 GPa and 1300–1900°C of the systems pyrope Mg3Al2Si3O12 (Prp)-Na2MgSi5O12 (NaGrt) modeling solid solutions of Na-bearing garnets, Prp-jadeite NaAlSi2O6 (Jd) in a simplified mode demonstrating melting relations of Na-rich eclogite, and Prp-Na2CO3 are presented. Prp-Na2MgSi5O12 join is a pseudobinary that results from the decomposition of NaGrt on to coesite and Na-pyroxene. Synthesized garnets are characterized by Na admixture (>0.32 wt % Na2O) and excess Si (3.05–3.15 f.u.). Maximal Na2O concentrations (1.5 wt % Na2O) are reached on the solidus of the system at 8.5 GPa. Clear correlation between Na and Si was established in synthesized garnets; this provides evidence for heterovalent isomorphism of the Mg + Al → Na + Si type with the appearance of Na2MgSi5O12 component as a mechanism of such garnet formation. The Prp-Jd join is also pseudobinary that results from the formation of two series of solid solutions: (1) garnet (Prp-NaGrt-majorite) and (2) pyroxene (Jd-clinoenstatite-Eskola molecule), and the appearance of kyanite at the solidus of the system, where garnets with the highest Na2O contents (>0.8 wt %) are formed. In spite of quite a wide field of garnet crystallization (20–100 mol % Prp), garnets with significant sodium concentration (>0.3 wt % Na2O) are formed in a Jd-rich part of the system (20–50 mol % Prp). In the Prp-Na2CO3 system at 8.5 GPa garnet crystallizes in a wide range of starting compositions as a liquidus mineral containing up to 0.9 wt % Na2O. Our experiments demonstrate that melt alkalinity, as well as PT-parameters control the crystallization of Na-bearing majoritic garnets. The results obtained provide evidence for the fact that the majority of natural diamonds with inclusions of Na-bearing majoritic garnets containing <0.4 wt % Na2O were formed in alkaline silicate (carbonate-silicate) melts at a pressure of <7 GPa. Only a small portion of garnets with higher sodium concentrations (>1 wt % Na2O) could be formed at a pressure of >8.5 GPa. 1 This article was translated by the authors.  相似文献   
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The results of an experimental study of the pyrope (Mg3Al2Si3O12)-jadeite (NaAlSi2O6) system at P = 7.0 and 8.5 GPa and T = 1300?C1800°C are summarized in this paper. The main phases that were obtained in the experiments are garnet, pyroxene, kyanite (in some cases corundum), and quenched melt. Garnets are characterized by a stable Na2O admixture (up to 0.6 wt % at 7.0 GPa and up to 0.8 wt % at 8.5 GPa) and the high silicon content (Si = 3.016?C3.166). The maximal sodium concentrations in garnet were found at the solidus of the system, which results from an increase of the coefficient of sodium partitioning between garnet and melt during a temperature decrease.  相似文献   
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A new synchrotron X-ray diffraction study of chromium oxide Cr2O3 (eskolaite) with the corundum-type structure has been carried out in a Kawai-type multi-anvil apparatus to pressure of 15 GPa and temperatures of 1873 K. Fitting the Birch–Murnaghan equation of state (EoS) with the present data up to 15 GPa yielded: bulk modulus (K 0,T0), 206 ± 4 GPa; its pressure derivative K0,T , 4.4 ± 0.8; (?K 0,T /?T) = ?0.037 ± 0.006 GPa K?1; a = 2.98 ± 0.14 × 10?5 K?1 and b = 0.47 ± 0.28 × 10?8 K?2, where α 0,T  = a + bT is the volumetric thermal expansion coefficient. The thermal expansion of Cr2O3 was additionally measured at the high-temperature powder diffraction experiment at ambient pressure and α 0,T0 was determined to be 2.95 × 10?5 K?1. The results indicate that coefficient of the thermal expansion calculated from the EoS appeared to be high-precision because it is consistent with the data obtained at 1 atm. However, our results contradict α 0 value suggested by Rigby et al. (Brit Ceram Trans J 45:137–148, 1946) widely used in many physical and geological databases. Fitting the Mie–Grüneisen–Debye EoS with the present ambient and high-pressure data yielded the following parameters: K 0,T0 = 205 ± 3 GPa, K0,T  = 4.0, Grüneisen parameter (γ 0) = 1.42 ± 0.80, q = 1.82 ± 0.56. The thermoelastic parameters indicate that Cr2O3 undergoes near isotropic compression at room and high temperatures up to 15 GPa. Cr2O3 is shown to be stable in this pressure range and adopts the corundum-type structure. Using obtained thermoelastic parameters, we calculated the reaction boundary of knorringite formation from enstatite and eskolaite. The Clapeyron slope (with \({\text{d}}P/{\text{d}}T = - 0.014\) GPa/K) was found to be consistent with experimental data.  相似文献   
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Doklady Earth Sciences - Novel data from mineralogical studies of the peridotite xenoliths from the Komsomol’skaya–Magnitnaya kimberlite pipe, Upper Muna field, Siberian craton, are...  相似文献   
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The pseudo-binary system Mg3Al2Si3O12–Na2MgSi5O12 modelling the sodium-bearing garnet solid solutions has been studied at 7 and 8.5 GPa and 1,500–1,950°C. The Na-bearing garnet is a liquidus phase of the system up to 60 mol% Na2MgSi5O12 (NaGrt). At higher content of NaGrt in the system, enstatite (up to ∼80 mol%) and then coesite are observed as liquidus phases. Our experiments provided evidence for a stable sodium incorporation in garnet (0.3–0.6 wt% Na2O) and its control by temperature and pressure. The highest sodium contents were obtained in experiments at P = 8.5 GPa. Near the liquidus (T = 1,840°C), the equilibrium concentration of Na2O in garnet is 0.7–0.8 wt% (∼6 mol% Na2MgSi5O12). With the temperature decrease, Na concentration in Grt increases, and the maximal Na2MgSi5O12 content of ∼12 mol% (1.52 wt% Na2O) is gained at the solidus of the system (T = 1,760°С). The data obtained show that most of natural diamonds, with inclusions of Na-bearing garnets usually containing <0.4 wt% Na2O, could be formed from sodium-rich melts at pressures lower than 7 GPa. Majoritic garnets with higher sodium concentrations (>1 wt% Na2O) may crystallize at a pressure range of 7.0–8.5 GPa. However the upper pressure limit for the formation of naturally occurring Na-bearing garnets is restricted by the eclogite/garnetite bulk composition.  相似文献   
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Doklady Earth Sciences - The results of study secondary crystallized melt inclusions in olivine of a sheared peridotite xenolith from the Komsomolskaya–Magnitnaya kimberlite pipe (Upper Muna...  相似文献   
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