Atomistic simulation of the mechanisms of noble gas incorporation in minerals

Atomistic simulations have been carried out to investigate the mechanisms of noble gas incorporation in minerals using both the traditional two-region approach and the “supercell” method. The traditional two-region approach has been used to calculate defect energies for Ne, Ar, Kr and Xe incorporation in MgO, CaO, diopside and forsterite in the static limit and at one atmosphere pressure. The possibilities of noble gas incorporation via both substitution and interstitial mechanisms are studied. The favored mechanism varies from mineral to mineral and from noble gas to noble gas. In all minerals studied, the variation of the solution energies of noble gas substitution with atomic radius appears approximately parabolic, analogous to those for 1⁺, 2⁺, 3⁺ and 4⁺ trace element incorporation on crystal lattice sites. Noble gas solution energies thus also fall on a curve, similar to those previously observed for cations with different charges, but with much lower curvature.The “supercell” method has been used to investigate the pressure dependence of noble gas incorporation in the same systems. Results indicate a large variation of the solubility of the larger noble gases, Kr and Xe with pressure. In addition, explicit simulation of incorporation at the (0 0 1) surface of MgO shows that the solubility of the heavier noble gases may be considerably enhanced by the presence of interfaces.     

海水中液-固界面的台阶型动力学曲线 Ⅰ.动力学曲线之台阶的消长和变化规律

对海水中Zn(Ⅱ),Ca(Ⅱ),Cd(Ⅱ)与高岭石、伊利石和蒙脱石等粘土矿物;无定形水合氧化铁、α-FeOOH等铁的水合氧化物;δ-MaO_2,γ-MnOOH,水锰矿等锰的水合氧化物等30个左右实验体系的液-固界面台阶型动力学曲线进行了系统的实验测定和全面的条件研究。在实验测定上提出两种方法、互为校核。对动力学曲线之台阶的消长和变化规律作了系统研究,确定主要影响因素是:金属离子初始浓度、固体交换剂量、体系的pH值和温度,以及搅拌速度等。     

Automated Target Detection and Discrimination Using Constrained Kurtosis Maximization

Exploiting hyperspectral imagery without prior information is a challenge. Under this circumstance, unsupervised target detection becomes an anomaly detection problem. We propose an effective algorithm for target detection and discrimination based on the normalized fourth central moment named kurtosis, which can measure the flatness of a distribution. Small targets in hyperspectral imagery contribute to the tail of a distribution, thus making it heavier. The Gaussian distribution is completely determined by the first two order statistics and has zero kurtosis. Consequently, kurtosis measures the deviation of a distribution from the background and is suitable for anomaly/target detection. When imposing appropriate inequality constraints on the kurtosis to be maximized, the resulting constrained kurtosis maximization (CKM) algorithm will be able to quickly detect small targets with several projections. Compared to the widely used unconstrained kurtosis maximization algorithm, i.e., fast independent component analysis, the CKM algorithm may detect small targets with fewer projections and yield a slightly higher detection rate.     

冀西北长城纪宣龙式铁矿层中微体植物化石的发现及其意义

本文研究的是笔者等在冀西北长城系串岭沟组宣龙式铁矿层中发现的微体植物化石,这些化石都保存在铁质叠层石(肾状赤铁矿)和铁质核形石(鲕状赤铁矿)的基本层中。微化石以丝状体为主,部分为球状体。归属于原核生物蓝藻门颤藻科的两个属和色球藻科的一个属。化石层同位素年龄约在1800—1757Ma。这些化石与北美冈弗林特组微化石比较,既有些相似,又有些区别。该化石的发现为研究铁矿的成因,指示沉积环境及层位对比都很有意义。     

广东河源盆地蛋化石

河源盆地沉积了白垩系-古近系，笔者将这套地层划分为3个岩石地层单位，新建仙塘组和东源组，沿用格岭组。在河源除发现恐龙骨骼、恐龙脚印、龟鳖化石外，于白垩系东源组中还产有大量蛋化石。该组蛋化石的分布，下部以圆形蛋为主，中-上部多见长形蛋。报道了三王坝村副圆形蛋(新种)Paraspheroolithus sanwangbacunensis Fang sp．nov．、风光村树枝蛋(新种)Dendroolithus fengguangcunensis Fang sp．nov．和瑶屯巨形蛋Macroolithus yaotunensis、长形长形蛋Elongatoolithus elongates。     

鄂尔多斯盆地的三维可视化及其应用

地形三维可视化作为测绘行业的一项新技术正处于蓬勃发展阶段。本文以鄂尔多斯盆地为例，着重介绍了基于ARCGIS9．0的三维可视化建库、实现过程，并指出其在矿产勘探中的具体应用。     

区域可持续发展评价:进展与展望

可持续发展的评价是目前可持续发展研究的热点和前沿。当前评价可持续发展的单项指标和指标体系在指标与可持续性的关系、指标权重的选择、指标的定量化、可持续性的总体判别方法、资本替代性与替代速度、指标阈值的确定等方面具有不同的局限性 ,这也是可持续发展评价的主要难点。可持续发展的评价必然要落实到不同尺度的空间地理单元上 ,区域发展是评价的对象 ,因而可持续发展的评价必然具有显著的区域性 ,不同区域的评价指标或指标体系必然会有所不同。社会、经济与人口的发展是人类社会发展的主要目标 ,而发展的可持续性依赖于自然环境的质量 ,包括自然资源的再生或替代、生命支持系统与生物多样性的维持或改善。据此 ,论文构建了区域可持续发展评价的理论框架和发展——可持续性二维评价坐标体系 ,并提出了“自上而下”和“自下而上”的指标遴选方法。     

西藏南部郎杰学群碎屑物质来源的古水流证据

新近对西藏山南琼果和贡嘎地区(特提斯喜马拉雅北亚带)弱变质的上三叠统深海—半深海沉积地层——郎杰学群地质填图调查,在出露槽模沉积构造的37个古水流点获得了43组数据。赤平投影数据恢复后发现,这一地区主力古水流有南东140°～160°和南西190°～210°两个方向。这一分析结果为郎杰学群沉积物来自北边(未知块体)而非印度次大陆的观点提供了有力证据。     

略阳煎茶岭铜镍硫化物矿床Re—Os同位素年龄及其地质意义

采用矿石Re-Os同位素方法对陕西省煎茶岭硫化镍矿床矿石进行了成矿年代学研究,获得了878士27 Ma(1σ)的等时线年龄,首次厘定了该矿床成矿时代为新元古代,成岩成矿基本同时.通过对878 Ma硫化镍矿石初始Re-Os同位素体系的γOs计算和Re/Os值分析表明,其yOs和Re/Os值变化范围大,深部条带状矿石的Re/Os值仅为0.05,yOs为-6.70;块状矿石的Re/Os值范围为4.24～24.43,γOs为-15.37～+280.65,说明成矿过程中有壳源物质的混染;两件样品的γOs为负值(-15.37,-6.70),可能指示其超镁铁质岩浆来源于Re亏损地幔.煎茶岭超基性岩体年龄及其镍矿石的Re-Os等时线年龄与扬子克拉通北缘火山岩浆活动时间相对应,它们是扬子克拉通西北缘晋宁期构造岩浆成矿作用的产物.