Adsorption of cobalt by using inorganic components of sediment samples from water bodies

The adsorption of cobalt ions was evaluated using sediment samples from water bodies to investigate the adsorption properties of sediment and the behavior of these natural materials in the presence of nuclear and industrial waste.The two sediments(S1 and S2)were treated to eliminate humic and fulvic acids and then they were characterized by several techniques.The minerals found in both the sediments(X-ray diffraction)were quartz and albite;plus,goethite and muscovite in S1,and kaolinite and montmorillonite in S2.Point of zero charge(PZC)of S1 and S2 was 6.00 and 5.22,respectively.The specific area of S1(63.3 m²/g)is higher than S2(1.5 m²/g).Adsorption kinetics data for S1 and S2 were best fitted to the pseudo second-order model.The removal efficiency of S1 for cobalt was 96%with an adsorption capacity(qe)of 0.93 mg/g,and for S2 was 45%with a qeof 0.40 mg/g.The experimental data of the adsorption isotherms were adjusted to Langmuir and Freundlich models for S1 and S2,respectively.The thermodynamic parameters(enthalpy,entropy,and Gibb’s free energy)indicated that the adsorption processes were endothermic,spontaneous,and chemisorption mechanism.The results show that the adsorption capacities of the sediments depend on their composition.These water sediments have important adsorption properties for cobalt,and they can be used in the treatment of nuclear and industrial aqueous wastes.     

A multi-tracer approach to delineate groundwater dynamics in the Rio Actopan Basin,Veracruz State,Mexico

Geochemistry and environmental tracers were used to understand groundwater resources, recharge processes, and potential sources of contamination in the Rio Actopan Basin, Veracruz State, Mexico. Total dissolved solids are lower in wells and springs located in the basin uplands compared with those closer to the coast, likely associated with rock/water interaction. Geochemical results also indicate some saltwater intrusion near the coast and increased nitrate near urban centers. Stable isotopes show that precipitation is the source of recharge to the groundwater system. Interestingly, some high-elevation springs are more isotopically enriched than average annual precipitation at higher elevations, indicating preferential recharge during the drier but cooler winter months when evapotranspiration is reduced. In contrast, groundwater below 1,200 m elevation is more isotopically depleted than average precipitation, indicating recharge occurring at much higher elevation than the sampling site. Relatively cool recharge temperatures, derived from noble gas measurements at four sites (11–20 °C), also suggest higher elevation recharge. Environmental tracers indicate that groundwater residence time in the basin ranges from 12,000 years to modern. While this large range shows varying groundwater flowpaths and travel times, ages using different tracer methods (¹⁴C, ³H/³He, CFCs) were generally consistent. Comparing multiple tracers such as CFC-12 with CFC-113 indicates piston-flow to some discharge points, yet binary mixing of young and older groundwater at other points. In summary, groundwater within the Rio Actopan Basin watershed is relatively young (Holocene) and the majority of recharge occurs in the basin uplands and moves towards the coast.     

NSVS 2569022:a peculiar binary among W UMa stars with extremely small mass ratios

Photometric observations of the W UMa binary NSVS 2569022 are presented. The light curve solution reveals that both components are of F spectral type(temperatures T_1= T_2= 6100 K). NSVS2569022 undergoes a total eclipse of W subtype and the mass ratio is well-determined. Its extremely small value of only 0.077 implies that the target will probably experience instability and a possible merger. This value ranks NSVS 2569022 in sixth place among binaries with the smallest mass ratio.Based on an empirical relation of "period – total mass" for low mass-ratio binaries, we estimate the global parameters of NSVS 2569022: masses M_1= 1.17 M⊙and M_2= 0.09 M⊙; radii R_1= 1.19 R⊙and R_2= 0.38 R⊙; luminosities L_1= 1.73 L⊙and L_2= 0.17 L⊙. An analysis of the characteristics of binaries with extremely low-mass ratios is made. NSVS 2569022 turns out to be a peculiar binary among W UMa stars with extremely small mass ratios due to its unexpectedly small fill-out factor of only 0.014(slightly overcontact configuration).     

New observations and transit solutions of the inflated exoplanets HAT-P-40b and HAT-P-51b

We present high-precision photometric observations of the transiting exoplanets HAT-P-40 b and HAT-P-51 b by the Rozhen 2-m telescope.The newly-observed transit of HAT-P-40 b is the first one with a complete curve.The orbital periods of the two targets were improved.We modeled the observed transits and found bigger stellar radii than those derived from the stellar models.The planet radii of HATP-40 b and HAT-P-51 b obtained from our transit solutions are bigger than the values calculated by the empirical relations for Jupiter-mass and Saturn-mass planets respectively.Their values reveal the highlyinflated nature of the two targets,especially that of HAT-P-51 b.We established that the best transit solutions correspond to a quadratic limb-darkening law.The fitted limb-darkening coefficients of HAT-P-40 are close to the theoretical ones while those of HAT-P-51 are a little different.The precise astrometric Gaia distances of the two targets are smaller by 6%–7%than the calculated values from the stellar models.We propose the Gaia distances to be used for improvement of the stellar models as well as for more reliable calculation of the parameters of the known exoplanets.     

Influence of Intra- and Interspecific Interactions on Short-term Movement of the Amphipod Corophium volutator in Varying Environmental Conditions

Movement of animals on intertidal mudflats can have profound consequences for population and community dynamics. Such movement is often influenced by biotic interactions, but the abiotic environment can also be important, affecting the strength of species’ interactions and even changing their outcome. Here, we focused on two biotic interactions and examined their effect on movement of the burrow-dwelling amphipod Corophium volutator: intraspecific interactions (specifically, the effect of conspecific density) and interspecific interactions with a competitor–predator, the mud snail Ilyanassa obsoleta (=Nassarius obsoletus). We assessed the magnitude of the temporal variation and examined the influence of pertinent abiotic variables (lunar cycle, presence of tide pools). Despite substantial temporal variation in movement levels, density of conspecifics did not influence emigration or immigration rates of C. volutator. Mud snails negatively affected immigration of C. volutator, and this was consistent across all lunar phases. However, mud snails influenced mortality and emigration of C. volutator in a contrasting way relative to lunar phases; sometimes amphipods evaded snails and survived, but at other times did not emigrate and were killed. The presence of tide pools did not change the nature or strength of the snail–amphipod interaction. Our results further clarify the complex interactions between C. volutator and I. obsoleta and suggest that resources on the mudflat are sufficient to sustain high densities of amphipods in a density-independent manner. Further, they highlight the importance of considering multiple environmental variables when examining interspecific interactions.     

Variations in exospheric density at heights near 1100km, derived from satellite orbits

In an earlier paper, values of exospheric density were obtained from the orbit of Echo 2 for the years 1964–1965. The results indicated a semi-annual variation in density by a factor of between 2 and 3, considerably larger than predicted by existing atmospheric models.

These studies have now been extended to the beginning of 1967, using both Echo 2 and Calsphere 1, to show how the density is responding to increasing solar activity. Variations in density during 1964 have been analysed in more detail. The long-term variation associated with the solar cycle and the short-term variations associated with magnetic and solar disturbances agree with the variations expected on the basis of current models. The semi-annual variation is persisting to higher levels of solar activity, and although its amplitude is diminishing the factor of variation was still 1.6 in 1966.     

Estimation of uncertainty sources in the projections of Lithuanian river runoff

Particular attention is given to the reliability of hydrological modelling results. The accuracy of river runoff projection depends on the selected set of hydrological model parameters, emission scenario and global climate model. The aim of this article is to estimate the uncertainty of hydrological model parameters, to perform sensitivity analysis of the runoff projections, as well as the contribution analysis of uncertainty sources (model parameters, emission scenarios and global climate models) in forecasting Lithuanian river runoff. The impact of model parameters on the runoff modelling results was estimated using a sensitivity analysis for the selected hydrological periods (spring flood, winter and autumn flash floods, and low water). During spring flood the results of runoff modelling depended on the calibration parameters that describe snowmelt and soil moisture storage, while during the low water period—the parameter that determines river underground feeding was the most important. The estimation of climate change impact on hydrological processes in the Merkys and Neris river basins was accomplished through the combination of results from A1B, A2 and B1 emission scenarios and global climate models (ECHAM5 and HadCM3). The runoff projections of the thirty-year periods (2011–2040, 2041–2070, 2071–2100) were conducted applying the HBV software. The uncertainties introduced by hydrological model parameters, emission scenarios and global climate models were presented according to the magnitude of the expected changes in Lithuanian rivers runoff. The emission scenarios had much greater influence on the runoff projection than the global climate models. The hydrological model parameters had less impact on the reliability of the modelling results.     

Similarities between Circular Polarization in Galactic Jet Sources and AGN

We compare the observational properties of the circular polarization in Galactic jet sources with that observed in AGN, and outline the constraints they place on the mechanism responsible for the circular polarization. We also discuss the implications of the time scale of polarization variations on the mechanism responsible for the circular polarization.     

Light curve morphology study of UW CrB – evidence for a 5 d superorbital period

Since its discovery in 1990, UW CrB (also known as MS1603+2600) has remained a peculiar source without firm classification. Our current understanding is that it is an accretion disc corona (ADC) low-mass X-ray binary. In this paper, we present results from our photometric campaign dedicated to studying the changing morphology of the optical light curves. We find that the optical light curves show remarkable evidence for strongly evolving light curve shapes. In addition, we find that these changes show a modulation at a period of ∼5 d. We interpret these changes as either due to strong periodic accretion disc warping or due to other geometrical changes because of disc precession at a period of 5 d. Finally, we have detected 11 new optical bursts, the phase distribution of which supports the idea of a vertically extended asymmetric accretion disc.