Modal metasomatism in the Kaapvaal craton lithosphere: constraints on timing and genesis from U–Pb zircon dating of metasomatized peridotites and MARID-type xenoliths

Modal metasomatism in the Kaapvaal craton lithosphere is well documented in upper mantle xenoliths sampled by both group I (mainly late Cretaceous) and group II (mainly early Cretaceous to late Jurassic) kimberlites in the Kimberley area. The metasomatic style is characterized by introduction of K, H and large ion lithophile/high field strength (LIL/HFS) elements into the lithospheric mantle leading to the crystallization of hydrous potassic phases such as phlogopite and/or K-amphibole. Textures indicate that the hydrous phases either replace pre-existing assemblages in peridotites, forming the metasomatized peridotite suite (phlogopite–K-richterite–peridotites: PKPs) or crystallize from K-rich melts, forming the mica–amphibole–rutile–ilmenite–diopside (MARID) suite of xenoliths. These K-rich assemblages become potential low melting source components for alkaline incompatible trace element enriched magmas. The timing of metasomatism and its temporal and possible genetic relation to kimberlite magmatism is poorly constrained because of the rarity of phases in the metasomatic assemblages suitable for precise dating. Here we present precise sensitive high resolution ion microprobe (SHRIMP) U–Pb formation ages of 88 ± 2 (1σ=1 standard deviation) and 82 ± 3 Ma data for zircons from a K-richterite–phlogopite-bearing metasomatized peridotite (PKP) and a MARID xenolith respectively, sampled by a group I kimberlite. Both average PKP and MARID zircon ages are indistinguishable from emplacement ages of group I kimberlites in the Kimberley area dated at 83 ± 4 (2σ) and 84 ± 0.9 Ma. One exceptionally old age spot of 102 ± 5 Ma from a PKP zircon provides evidence for modal metasomatism predating group I kimberlite emplacement by several millions of years with minor resetting of the U–Pb isotopic system of most analyzed PKP zircons to a group I emplacement age. Detailed textural and mineral chemical analysis, including high energy X-ray mapping and analysis of fluid inclusion daughter crystals, indicates a complex reaction history for both PKPs and MARIDs. U–Pb zircon ages from this study combined with literature data and experimentally derived models for MARID formation are used to suggest that MARID-formation is concurrent and genetically related to both group I and II kimberlite magmatism in the Kimberley area. MARID and PKP zircon ages are also consistent with the idea first proposed by Dawson and Smith (Geochim Cosmochim Acta 41: 309–323, 1977) that metasomatized peridotites may form from interaction of hydrous fluids expelled by solidifying MARID-type melts with peridotitic wall rocks. Received: 13 December 1999 / Accepted: 13 April 2000     

193nmLA-ICPMS对国际地质标准参考物质中42种主量和微量元素的分析

本文采用配备有 193nm Ar F准分子 (excimer)激光器的 Geo L as2 0 0 M剥蚀系统和 Elan6 10 0 DRC ICP- MS对 4个美国地质调查所 (USGS)玻璃标准参考物质以及 3个美国国家标准技术研究院 (NIST)人工合成硅酸盐玻璃标准参考物质中几乎覆盖整个质量数范围 (从 7L i到 2 38U)的 38个微量和 4个主量 (Na、Mg、Ti和 Mn)元素进行了分析。分析结果表明 ,无论是对 USGS还是 NIST玻璃 ,元素分析的相对标准偏差 RSDs和分析值与参考值之间的相对偏差 (RDs)一般优于 10 % ,RSD和RD较大的元素主要出现在含量很低或不均匀样品中。稀土元素的 RSD显示 ,除 AGV- 2 G可能存在不均匀现象外 ,其它所测样品在 6 0 μm尺度上 ,元素分布是均匀的。本研究证明 ,由于 ICP- MS具有 10 8cps(每秒计数 )的动态线性范围 ,本实验室的L A- ICPMS系统可定量分析含量在百分之几的主量元素及微量元素。分析精密度和准确度可与常规溶液雾化进样 ICP- MS方法相媲美     

Accurate U-Pb Age and Trace Element Determinations of Zircon by Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry

Various zircons of Proterozoic to Oligocene ages (1060-31 Ma) were analysed by laser ablation-inductively coupled plasma-mass spectrometry. Calibration was performed using Harvard reference zircon 91500 or Australian National University reference zircon TEMORA 1 as external calibrant. The results agree with those obtained by SIMS within 2s error. Twenty-four trace and rare earth elements (P, Ti, Cr, Y, Nb, fourteen REE, Hf, Ta, Pb, Th and U) were analysed on four fragments of zircon 91500. NIST SRM 610 was used as the reference material and ²⁹Si was used as internal calibrant. Based on determinations of four fragments, this zircon shows significant intra-and inter-fragment variations in the range from 10% to 85% on a scale of 120 μm, with the variation of REE concentrations up to 38.7%, although the chondrite-normalised REE distributions are very similar. In contrast, the determined age values for zircon 91500 agree with TIMS data and are homogeneous within 8.7 Ma (2 s ). A two-stage ablation strategy was developed for optimising U-Pb age determinations with satisfactory trace element and REE results. The first cycle of ablation was used to collect data for age determination only, which was followed by continuous ablation on the same spot to determine REE and trace element concentrations. Based on this procedure, it was possible to measure zircon ages as low as 30.37 0.39 Ma (MSWD = 1.4; 2 s ). Other examples for older zircons are also given.     

Spatial Patterns of Sea Level Variability Associated with Natural Internal Climate Modes

Sea level rise (SLR) can exert significant stress on highly populated coastal societies and low-lying island countries around the world. Because of this, there is huge societal demand for improved decadal predictions and future projections of SLR, particularly on a local scale along coastlines. Regionally, sea level variations can deviate considerably from the global mean due to various geophysical processes. These include changes of ocean circulations, which partially can be attributed to natural, internal modes of variability in the complex Earth’s climate system. Anthropogenic influence may also contribute to regional sea level variations. Separating the effects of natural climate modes and anthropogenic forcing, however, remains a challenge and requires identification of the imprint of specific climate modes in observed sea level change patterns. In this paper, we review our current state of knowledge about spatial patterns of sea level variability associated with natural climate modes on interannual-to-multidecadal timescales, with particular focus on decadal-to-multidecadal variability. Relevant climate modes and our current state of understanding their associated sea level patterns and driving mechanisms are elaborated separately for the Pacific, the Indian, the Atlantic, and the Arctic and Southern Oceans. We also discuss the issues, challenges and future outlooks for understanding the regional sea level patterns associated with climate modes. Effects of these internal modes have to be taken into account in order to achieve more reliable near-term predictions and future projections of regional SLR.     

On Boussinesq's problem for Maxwell continua subject to an external gravity field

Summary. Boussinesq's problem is solved for a uniform and incompressible Maxwell half-space subject to an external gravity field. The solution is based on momentum equations which account for stress advection in the hydrostatically pre-stressed continuum during its deformation. The analysis shows that disregarding the pre-stress term renders the theoretical stress distribution incorrect and the deformation singular in the inviscid limit of the Maxwell continuum. Our solution is contrasted with a recently published alternative solution of the same problem, where regularity in the inviscid limit was forced by modified boundary conditions.     

How well do integrated assessment models simulate climate change?

Integrated assessment models (IAMs) are regularly used to evaluate different policies of future emissions reductions. Since the global costs associated with these policies are immense, it is vital that the uncertainties in IAMs are quantified and understood. We first demonstrate the significant spread in the climate system and carbon cycle components of several contemporary IAMs. We then examine these components in more detail to understand the causes of differences, comparing the results with more complex climate models and earth system models (ESMs), where available. Our results show that in most cases the outcomes of IAMs are within the range of the outcomes of complex models, but differences are large enough to matter for policy advice. There are areas where IAMs would benefit from improvements (e.g. climate sensitivity, inertia in climate response, carbon cycle feedbacks). In some cases, additional climate model experiments are needed to be able to tune some of these improvements. This will require better communication between the IAM and ESM development communities.     

Climate benefits of changing diet

Climate change mitigation policies tend to focus on the energy sector, while the livestock sector receives surprisingly little attention, despite the fact that it accounts for 18% of the greenhouse gas emissions and for 80% of total anthropogenic land use. From a dietary perspective, new insights in the adverse health effects of beef and pork have lead to a revision of meat consumption recommendations. Here, we explored the potential impact of dietary changes on achieving ambitious climate stabilization levels. By using an integrated assessment model, we found a global food transition to less meat, or even a complete switch to plant-based protein food to have a dramatic effect on land use. Up to 2,700 Mha of pasture and 100 Mha of cropland could be abandoned, resulting in a large carbon uptake from regrowing vegetation. Additionally, methane and nitrous oxide emission would be reduced substantially. A global transition to a low meat-diet as recommended for health reasons would reduce the mitigation costs to achieve a 450 ppm CO₂-eq. stabilisation target by about 50% in 2050 compared to the reference case. Dietary changes could therefore not only create substantial benefits for human health and global land use, but can also play an important role in future climate change mitigation policies.     

The Consistency of IPCC's SRES Scenarios to 1990–2000 Trends and Recent Projections

The greenhouse gas emissions scenarios published by the IPCC in the Special Report on Emission Scenarios (SRES) continue to serve as a primary basis for assessing future climate change and possible response strategies. These scenarios were developed between 1996 and 1999 and sufficient time has now passed to make it worth examining their consistency with more recent data and projections. The comparison performed in this paper includes population, GDP, energy use, and emissions of CO₂, non-CO₂ gases and sulfur. We find the SRES scenarios to be largely consistent with historical data for the 1990–2000 period and with recent projections. Exceptions to this general observation include (1) in the long-term, relatively high population growth assumptions; in some regions, particularly in the A2 scenario; (2) in the medium-term, relatively high economic growth assumptions in the LAM (Latin America, Africa and Middle East) region in the A1 scenario; (3) in the short-term, CO₂ emissions projections in A1 that are somewhat higher than the range of current scenarios; and (4) substantially higher sulfur emissions in some scenarios than in historical data and recent projections. In conclusion, given the relatively small inconsistencies for use as global scenarios there seems to be no immediate need for a large-scale IPCC-led update of the SRES scenarios that is solely based on the SRES scenario performance vis-a-vis data for the 1990–2000 period and/or more recent projections. Based on reported findings, individual research teams could make, and in some cases already have made, useful updates of the scenarios.     

Ablation Characteristic of Ilmenite using UV Nanosecond and Femtosecond Lasers: Implications for Non‐Matrix‐Matched Quantification

Ilmenite (FeTiO₃) is a common accessory mineral and has been used as a powerful petrogenetic indicator in many geological settings. Elemental fractionation and matrix effects in ilmenite (CRN63E‐K) and silicate glass (NIST SRM 610) were investigated using 193 nm ArF excimer nanosecond (ns) laser and 257 nm femtosecond (fs) laser ablation systems coupled to an inductively coupled plasma‐mass spectrometer. The concentration‐normalised ⁵⁷Fe and ⁴⁹Ti responses in ilmenite were higher than those in NIST SRM 610 by a factor of 1.8 using fs‐LA. Compared with the 193 nm excimer laser, smaller elemental fractionation was observed using the 257 nm fs laser. When using 193 nm excimer laser ablation, the selected range of the laser energy density had a significant effect on the elemental fractionation in ilmenite. Scanning electron microscopy images of ablation craters and the morphologies of the deposited aerosol materials showed more melting effects and an enlarged particle deposition area around the ablation site of the ns‐LA‐generated crater when compared with those using fs‐LA. The ejected material around the ns crater predominantly consisted of large droplets of resolidified molten material; however, the ejected material around the fs crater consisted of agglomerates of fine particles with ‘rough' shapes. These observations are a result of the different ablation mechanisms for ns‐ and fs‐LAs. Non‐matrix‐matched calibration was applied for the analysis of ilmenite samples using NIST SRM 610 as a reference material for both 193 nm excimer LA‐ICP‐MS and fs‐LA‐ICP‐MS. Similar analytical results for most elements in ilmenite samples were obtained using both 193 nm excimer LA‐ICP‐MS at a high laser energy density of 12.7 J cm^?2 and fs‐LA‐ICP‐MS.