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Bruno Dhuime Delphine Bosch Olivier Bruguier Renaud Caby Carlos Archanjo 《Comptes Rendus Geoscience》2003,335(15):1081-1089
The Borborema Province (BP) of northeastern Brazil is a complex crustal assemblage, which has undergone a polycyclic evolution during the Proterozoic. In the Piancó-Alto Br??gida belt, a metamorphosed leucosome vein inserted in amphibolites has a trace element pattern suggesting a T-MORB protolith. Apatites yield a REE pattern indicating growth in equilibrium with garnet, thus pointing to its metamorphic origin. UPb analyses yield an age of 540±5 Ma interpreted as a cooling age following amphibolite facies regional metamorphism associated with granitic emplacement at ca. 580 Ma. The resulting slow cooling rates (ranging from ca. 2.5 to 5 °C Ma?1) are consistent with underplating of mafic magmas, or crustal thickening caused by nappe stacking, as possible processes governing the metamorphic evolution of the BP. To cite this article: B. Dhuime et al., C. R. Geoscience 335 (2003). 相似文献
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Delphine Yeghicheyan Cécile Bossy Martine Bouhnik Le Coz Chantal Douchet Guy Granier Alexie Heimburger Francois Lacan Aurélie Lanzanova Tristan C. C. Rousseau Jean‐Luc Seidel Mickaël Tharaud Frédéric Candaudap Jérôme Chmeleff Christophe Cloquet Sophie Delpoux Marie Labatut Rémi Losno Catherine Pradoux Yann Sivry Jeroen E. Sonke 《Geostandards and Geoanalytical Research》2013,37(4):449-467
The natural river water certified reference material SLRS‐5 (NRC‐CNRC) was routinely analysed in this study for major and trace elements by ten French laboratories. Most of the measurements were made using ICP‐MS. Because no certified values are assigned by NRC‐CNRC for silicon and 35 trace element concentrations (rare earth elements, Ag, B, Bi, Cs, Ga, Ge, Li, Nb, P, Rb, Rh, Re, S, Sc, Sn, Th, Ti, Tl, W, Y and Zr), or for isotopic ratios, we provide a compilation of the concentrations and related uncertainties obtained by the participating laboratories. Strontium isotopic ratios are also given. 相似文献
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Delphine PaillerEdouard Bard Frauke RostekYan Zheng Richard MortlockAlexander van Geen 《Geochimica et cosmochimica acta》2002,66(5):849-865
Authigenic metals (uranium, cadmium, and molybdenum), organic carbon (OC) and total C37 alkenone (totC37) concentrations were measured for the last 350 kyr in core MD900963, located in the eastern equatorial Arabian Sea. Authigenic metal concentrations on a carbonate-free basis range between 1 and 17 ppm, 0.5 and 6 ppm, and 0.5 and 4 ppm for U, Cd, and Mo, respectively. The profiles are characterized by well-defined 23 kyr cycles between oxic and mildly suboxic conditions. The redox-sensitive metal profiles also follow variations in the concentrations of OC (0.2-0.9%) and alkenones (0.2-6.7 ppm). The coupled variations in inorganic and organic constituents are attributed to a 23-kyr cycle in primary production above site MD900963, as suggested by clear correlations with independent micropaleontologic proxies (primary productivity indices based on foraminifera and coccoliths and fragmentation of foraminiferal shells). The 23-kyr cycles do appear to be primarily driven by productivity rather than changes in bottom water oxygen. Comparison with other records indicates that if this interpretation is correct, productivity variations across much of the Indian Ocean have been dominated by precessional forcing, with high productivity in phase with low summer insolation in the Northern Hemisphere. This interpretation contrasts with the traditional attribution of enhanced productivity in the Indian Ocean with periods of high summer insolation. 相似文献
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Among numerous methods for cation exchange capacity (CEC) determination for soils and sediments, the cobaltihexamine chloride method is frequently used due to its ability to measure CEC at soil pH. After exchange with Co(NH3)63+ ions, CEC is estimated via the measurement of the Co remaining in solution. The modified method proposed allows a more rapid determination of CEC based on the measurement of the absorbance at 472 nm of the cobaltihexamine chloride solution before and after exchange. This method has been applied to various soil's horizons from four sites, selected to cover a wide range of CEC and pH values. The model obtained allows one to calculate CEC from absorbance at 472 nm with 95% confidence intervals. As CEC is of relevant meaning in agronomical and environmental purposes, and more recently in ecotoxicological studies, this modified method can be proposed as a rapid test for CEC evaluation. 相似文献
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Komatiites are fascinating volcanic rocks. They are among the most ancient lavas of the Earth following the 3.8 Ga pillow basalts at Isua and they represent some of the oldest ultramafic magmatic rocks preserved in the Earth’s crust at 3.5 Ga. This fact, linked to their particular features (high magnesium content, high melting temperatures, low dynamic viscosities, etc.), has attracted the community of geoscientists since their discovery in the early sixties, who have tried to determine their origin and understand their meaning in the context of terrestrial mantle evolution. In addition, it has been proposed that komatiites are not restricted to our planet, but they could be found in other extraterrestrial settings in our Solar System (particularly on Mars and Io). It is important to note that komatiites may be extremely significant in the study of the origins and evolution of Life on Earth. They not only preserve essential geochemical clues of the interaction between the pristine Earth rocks and atmosphere, but also may have been potential suitable sites for biological processes to develop. Thus, besides reviewing the main geodynamic, petrological and geochemical characteristics of komatiites, this paper also aims to widen their investigation beyond the classical geological prospect, calling attention to them as attractive rocks for research in Planetology and Astrobiology. 相似文献
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Nathalie Fagel Sebastien Bertrand Nadine Mattielli Delphine Gilson Luis Chirinos Gilles Lepoint Roberto Urrutia 《第四纪科学杂志》2010,25(7):1100-1112
In this paper, we compare the elemental and isotopic (C, N, Pb) geochemistry of lake sediments from two contrasted environments in south‐central Chile. The first lake, Laguna Chica de San Pedro (LCSP), is situated in the urbanised area of the Biobio Region (36°S). The second lake, Lago Puyehue (40° S), is located 400 km to the southeast of LCSP and within an Andean national park. Our aim is to identify environmental impacts associated with increasing industrial activities and land degradation during the last 150 a. In LCSP, shifts in C/N atomic ratios, δ13C and δ15N from 1915–1937 to the late 1980s are attributed to successive land degradation episodes in the lake watershed. Based on a Pb isotopic mixing model, we estimate that up to 20% of lead in LCSP sediments is supplied from urban atmospheric pollution. By contrast, human impact in the watershed of Lago Puyehue is very limited. We observe no change in organic geochemistry during the last 150 a and lead contamination remains lower than 5%, even during the last decades. Although contamination levels are much higher in LCSP than in Lago Puyehue, a peak in anthropogenic Pb is recorded during the same period (1974–1976) at both sites. This maximum contamination level is consistent with increased industrial activity in the vicinity of Concepción. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
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F Delpy M Pagano J Blanchot F Carlotti D Thibault-Botha 《Marine pollution bulletin》2012,64(9):1921-1932
The Berre Lagoon has been under strong anthropogenic pressure since the early 1950s. The opening of the hydroelectric EDF power plant in 1966 led to large salinity drops. The zooplankton community was mainly composed of two common brackish species: Acartia tonsa and Brachionus plicatilis. Since 2006, European litigation has strongly constrained the input of freshwater, maintaining the salinity above 15. A study was performed between 2008 and 2010 to evaluate how these modifications have impacted the zooplankton community. Our results show that the community is more diverse and contains several coastal marine species (i.e., Centropages typicus, Paracalanus parvus and Acartia clausi). A. tonsa is still present but is less abundant, whereas B. plicatilis has completely disappeared. Strong predatory marine species, such as chaetognaths, the large conspicuous autochtonous jellyfish Aurelia aurita and the invasive ctenophore Mnemiopsis leidyi, are now very common as either seasonal or permanent features of the lagoon. 相似文献
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Farid Juillot Delphine Jouvin Philipe Telouk Philippe Ildefonse Steve Sutton Gordon E. Brown Jr. 《Geochimica et cosmochimica acta》2011,75(9):2295-2308
Zinc isotopes have been studied along two smelter-impacted soil profiles sampled near one of the largest Pb and Zn processing plants in Europe located in northern France, about 50 km south of Lille. Mean δ66Zn values along these two soil profiles range from +0.22 ± 0.17‰ (2σ) to +0.34 ± 0.17‰ (2σ) at the lowest horizons and from +0.38 ± 0.45‰ (2σ) to +0.76 ± 0.14‰ (2σ) near the surface. The δ66Zn values in the lowest horizons of the soils are interpreted as being representative of the local geochemical background (mean value +0.31 ± 0.38‰), whereas heavier δ66Zn values near the surface of the two soils are related to anthropogenic Zn. This anthropogenic Zn occurs in the form of franklinite (ZnFe2O4)-bearing slag grains originating from processing wastes at the smelter site and exhibiting δ66Zn values of +0.81 ± 0.20‰ (2σ). The presence of franklinite is indicated by EXAFS analysis of the topsoil samples from both soil profiles as well as by micro-XANES analysis of the surface horizon of a third smelter-impacted soil from a distant site. These results indicate that naturally occurring Zn and smelter-derived Zn exhibit significantly different δ66Zn values, which suggests that zinc isotopes can be used to distinguish between geogenic and anthropogenic sources of Zn in smelter-impacted soils. In addition to a possible influence of additional past sources of light Zn (likely Zn-sulfides and Zn-sulfates directly emitted by the smelter), the light δ66Zn values in the surface horizons compared to smelter-derived slag materials are interpreted as resulting mainly from fractionation processes associated with biotic and/or abiotic pedological processes (Zn-bearing mineral precipitation, Zn complexation by organic matter, and plant uptake of Zn). This conclusion emphasizes the need for additional Zn isotopic studies before being able to use Zn isotopes to trace sources and pathways of this element in surface environments. 相似文献