Oil-generation kinetics for organic facies with Type-II and -IIS kerogen in the Menilite Shales of the Polish Carpathians

The Menilite Shales (Oligocene) of the Polish Carpathians are the source of low-sulfur oils in the thrust belt and some high-sulfur oils in the Carpathian Foredeep. These oil occurrences indicate that the high-sulfur oils in the Foredeep were generated and expelled before major thrusting and the low-sulfur oils in the thrust belt were generated and expelled during or after major thrusting. Two distinct organic facies have been observed in the Menilite Shales. One organic facies has a high clastic sediment input and contains Type-II kerogen. The other organic facies has a lower clastic sediment input and contains Type-IIS kerogen. Representative samples of both organic facies were used to determine kinetic parameters for immiscible oil generation by isothermal hydrous pyrolysis and S₂ generation by non-isothermal open-system pyrolysis. The derived kinetic parameters showed that timing of S₂ generation was not as different between the Type-IIS and -II kerogen based on open-system pyrolysis as compared with immiscible oil generation based on hydrous pyrolysis. Applying these kinetic parameters to a burial history in the Skole unit showed that some expelled oil would have been generated from the organic facies with Type-IIS kerogen before major thrusting with the hydrous-pyrolysis kinetic parameters but not with the open-system pyrolysis kinetic parameters. The inability of open-system pyrolysis to determine earlier petroleum generation from Type-IIS kerogen is attributed to the large polar-rich bitumen component in S₂ generation, rapid loss of sulfur free-radical initiators in the open system, and diminished radical selectivity and rate constant differences at higher temperatures. Hydrous-pyrolysis kinetic parameters are determined in the presence of water at lower temperatures in a closed system, which allows differentiation of bitumen and oil generation, interaction of free-radical initiators, greater radical selectivity, and more distinguishable rate constants as would occur during natural maturation. Kinetic parameters derived from hydrous pyrolysis show good correlations with one another (compensation effect) and kerogen organic-sulfur contents. These correlations allow for indirect determination of hydrous-pyrolysis kinetic parameters on the basis of the organic-sulfur mole fraction of an immature Type-II or -IIS kerogen.     

Effect of temperature on embryonic and larval development of bream (Abramis brama L.)

Influence of water temperature on embryonic and larval development of bream (Abramis brama L.) was stdied. Eggs of bream were incubated at eight constant water temperatures between 13.2 and 26.8°C. The temperature of 21.1°C gave highest hatching success, with no abnormalities in the eleutheroembryos and lowest mortality observed between eyed egg stage and the time of hatching. Developmental rate increased with increasing temperature. Duration of embryonic development (y; hours) decreased with increasing incubation temperature (x; °C) according to the formula: y=910.1−65.88 x+1.318 x². Larvae were reared at eight constant temperatures ranging from 13.5 to 34.0°C. The instantaneous growth rate in wet weight increased with increasing test temperature from 13.5 to 29.9°C, and then decreased at higher temperatures. Individual growth of fish and biomass production rate were highest at 27.9°C. This temperature is considered optimal when food availability and photoperiod are no limiting factors.     

The use of heavy metal concentrations and dendrochronology in the reconstruction of sediment accumulation, Ma a Panew River Valley, southern Poland

Heavy metal concentrations were investigated in overbank sediments of the Mala Panew River, southern Poland. Samples were collected from seven vertical profiles located within channel infills of a 20th century floodplain at three sites, each up to 50 m wide. In each profile, 15–24 samples were collected and analysed for Ba, Cd, Cu, Pb, and Zn. Sequential extraction of these elements was carried out in the 0.063-mm fraction of selected samples. Additionally, the age of the oldest trees growing close to the profiles has been used to estimate the initiation of sediment accumulation there. Ba, Cu, and Pb, which occur mostly in less mobile, moderately reducible, and residual fractions, were used for sediment dating. Zn and Cd, which in 50–75% occur in the mobile exchangeable fraction, were not suitable for dating. Correlation of Ba, Cu, and Pb concentrations in vertical profiles with changes in the load of effluents discharged to the river showed abrupt changes in the thickness of the strongly polluted sediments across the floodplains. A comparison of the relative changes between heavy metal peaks in sediments of similar age in the different profiles suggests a variable rate of downward metal migration. In general, none of the heavy metals investigated seems to have been mobilised within the stratigraphic layers above the water table. In layers located at stratigraphically lower levels, the Zn and Cd peaks seem to migrate several centimetres to several decimetres down in the profile. In profiles inundated for several weeks every year, Zn and Cd, as well as the relatively less mobile Ba, Cu, and Pb, have migrated downward by several decimetres. The investigation shows that frequent fluctuations of the water table have blurred the original depositional metal patterns of metal concentrations within a period of less than 40 years.     

Estimation of parameters in a split functional model of geodetic observations (<Emphasis Type="Italic">M</Emphasis><Subscript>split</Subscript> estimation)

The paper presents a method of estimating parameters in two competitive functional models. The models considered here are concerned with the same observation set and are based on the assumption that an observation may result from a realization of either of two different random variables. These variables differ from one another at least in the main characteristic (for example, outliers can be realizations of one variable). A quantity that describes the opportunity of identifying a single observation with one random variable is assumed to be known. That quantity, called the elementary split potential, is strictly referred to the amount of information that an observation can provide about two competitive assumptions concerning the observation distribution. Parameter assessments that maximize the global elementary split potential (concerning all observations), are called M _split estimators. A generalization of M _split estimation presented in the paper refers to the theoretical foundation of M-estimation. An erratum to this article can be found at     

Versuch der Geschlechtsbestimmung beim Wels,Silurus glanis L., mit Hilfe der Diskriminanzanalyse von Brustflossendaten

Width of the first ray of the pectoral fin has been measured in two places for 154 young and 89 adult wels. Statistical relationships between the above characters and fish length as well as its maturity and sex have been proved. Three models of discriminant function for identification of adult fish sex have been derived and verified. The accuracy of sex separation has been 89,5% in a standard sample of wels, and 90,6% in a routine sample, after an adjustment in the procedure.     

中国地壳与上地幔结构的地球物理研究

地壳与上地幔是人类居住与获取各种资源、能源,改造和利用自然的重要场所,是地球科学的基础与生长点,六十年代以来发展迅猛。中国大陆、海域和过渡带地区的地壳和上地幔物理探索,在全球板块构造和驱动机制的研究具有特殊地位,文中分别就1)青藏高原地区的地壳结构,2)青海、甘肃地区地壳结构和地壳中的高速块层,3)中原地区的地壳与上地幔结构,4)京津及外围地区的地壳结构,5)隋县—南京—启东和隋县—安阳人工地震探测面的观测,6)利用面波和远震P波确定中国地壳和上地幔结构,7)中国地壳结构的基本轮廓等方面进行了讨论。     

Neotectonic Deformation of Pleistocene Deposits Along the Sudetic Marginal Fault,Southwestern Poland

The 160 km long Sudetic Marginal Fault (SMF) of Middle Silesia, southwestern Poland, is a main Alpine fault oriented NW–SE. This paper provides evidence of possible neotectonic activity in front of the SMF. The data are based on three exposures in the Roztoka–Mokrzeszow Graben near the city of Swidnica. Morphotectonic evidence in front of the SMF is also examined. Two sets of extensional deformation features are exposed and analysed. The main one includes gently inclined normal faults and flexures, with displacements in the bedrock of at least several metres. Based on the Quaternary stratigraphy of the region, the age of deformation is most probably Lower Saalian (Upper Pleistocene). The trigger for the deformation was probably the re-reactivation of the SMF and other faults due to the advance of the Lower Saalian Scandinavian ice-sheet into the Sudetic Mountains. The secondary deformation system includes sub-vertical, often conjugate faults with displacements up to 0·5 m superimposed on former structures. Its dominant normal faulting mode suggests an extensional stress regime that apparently coincides with the post-glacial glacioisostatic rebound. © 1997 John Wiley & Sons, Ltd.     

Brazil’s Financial Centers in the Twenty-first Century: Hierarchy,Specialization, and Concentration

The purpose of this article is to examine how the geography of Brazil’s financial centers changed since 2000 in terms of financial center hierarchy, specialization, and spatial concentration. To address these questions, we use data on employment and mergers and acquisitions in financial and business services, complemented with data on remuneration and bank assets. Our results show that São Paulo has consolidated its dominance as Brazil’s primary financial center, with market for corporate control as an important channel of this process. Rio’s decline as a financial center, which started more than fifty years ago, has continued into this century. At the same time, Brasília has emerged as the third most important financial center of Brazil. We document the recent dynamic of this territorial division of labor, with Rio’s specialization in insurance and Brasília’s dependence on government-owned banks. Finally, we show signs that Brazil’s financial center activities might be following an inverse U-shaped pattern whereby increasing geographical concentration is followed by its slow decline. Key Words: Brazil, concentration, financial centers, São Paulo, territorial division of labor.     

Human‐induced sedimentation patterns of a channelized lowland river

Channelization of the severely polluted Odra and Vistula Rivers in Poland induced intensive accumulation of fine‐grained deposits rich in organic matter and heavy metals. These sediments have been identified in vertical profiles in a narrow zone along river banks both in groyne‐created basins and on the floodplain. Grain size, organic matter, zinc (Zn), lead (Pb), copper (Cu) content and cesium‐137 (¹³⁷Cs) was used for sediment dating and, stratigraphy and chemistry have been diagnostic features for these deposits, named industrial alluvium. In the most polluted river reaches stabilized by bank reinforcements and groynes, 2‐m‐thick slack water groyne deposits are composed of uniform strata of polluted silts with organic matter content over 10%, Zn content over 1000 mg/kg and average Cu and Pb over 100 mg/kg. The average rate of sediment accretion in groynes is higher than on the floodplain and reaches 5 cm/yr. Stratification which appears at higher levels in the groyne fields and on the levees reflects a change from in‐channel to overbank deposition and is typified by dark layers separated by bright, sandy, and less polluted strata. Stratified, 4‐m‐thick, sediment sequences have been found in groyne fields of incised river reaches. The average rate of sediment accretion in these reaches is of the order of 5 cm/yr. In stable and relatively less polluted river reaches, vertical‐accretion organic deposits are finely laminated and the average rate of deposition amounts to a few millimeters per year. Investigations indicate that groyne construction favors conditions for long‐term storage of sediments at channel banks. For this reason, groynes should be considered as structures that efficiently limit sudden release of sediment‐associated heavy metals stored in channels and in floodplains of the historically polluted rivers. Copyright © 2014 John Wiley & Sons, Ltd.