Paleomagnetic correlation of sedimentary sequences: The use of secular geomagnetic variations for the differentiation and correlation of Holocene Aral Sea deposits

The paper presents results demonstrating the possibility of using data on paleosecular magnetic variations for correlation of young deposits. Using Holocene deposits of the Aral Sea as an example, it is shown that the combination of paleo-and petromagnetic data can be used to reliably correlate sections in presently isolated parts of a basin, as well as to correlate paleohydrologic events and estimate their age with regard for absolute radiocarbon datings. It is established that the most significant drop in the Aral Sea level occurred more than 2000–2500 yr ago and less significant drops that occurred later are dated at about 1500, 750–1050, and 270–500 yr ago.     

Petromagnetic features of sediments at the Mesozoic-Cenozoic boundary: Results from the Gams section

The paper continues a cycle of petromagnetic investigations of epicontinental deposits at the Mesozoic-Cenozoic (K/T) boundary and is devoted to the study of the Gams section (Austria). Using thermomagnetic analysis, the following magnetic phases are identified: goethite (T _C = 90–150°C), hemoilmenite (T _C = 200?300°C), metallic nickel (T _C = 350–360°C), magnetite and titanomagnetite (T _C = 550–610°C), Fe-Ni alloy (T _C = 640–660°C), and metallic iron (T _C = 740–770°C). Their concentrations are determined from M(T). In all samples, ensembles of magnetic grains have similar coercivity spectra and are characterized by a high coercivity. An exception is the lower coercivity of the boundary clay layer due to grains of metallic nickel and iron. With rare exceptions, the studied sediments are anisotropic and generally possess a magnetic foliation, which indicates a terrigenous accumulation of magnetic minerals. Many samples of sandy-clayey rocks have an inverse magnetic fabric associated with the presence of acicular goethite. The values of paramagnetic and diamagnetic components in the deposits are calculated. According to the results obtained, the K/T boundary is marked by a sharp increase in the concentration of Fe hydroxides. The distribution of titanomagnetite reflects its dispersal during eruptive activity, which is better expressed in the Maastrichtian and at the base of the layer J. The along-section distribution of metallic iron, most likely of cosmic origin, is rather uniformly chaotic. The presence of nickel, most probably of impact origin, is a particularly local phenomenon as yet. The K/T boundary is not directly related to an impact event.     

Deep 3D structure of the Sydney Basin using gravity modelling

A detailed deep 3D geological model is an important basis for many types of exploration and resource modelling. Renewed interest in the structure of the Sydney Basin, driven primarily by sequestration studies, geothermal studies and coal seam gas exploration, has highlighted the need for a model of deep basin geology, structure and thermal state. Here, we combine gravity modelling, seismic reflection surveys, borehole drilling results and other relevant information to develop a deep 3D geological model of the Sydney Basin. The structure of the Sydney Basin is characteristic of a typical intracontinental rift basin, with a deep north–south orientated channel in the Lachlan Fold Belt basement, filled with up to 4 km of rift volcanics, and overlain with Permo-Triassic sediments up to 4 km thick. The deep regional architecture presented in this study will form the framework for more detailed geological, hydrological and geothermal models.     

Changes in European precipitation seasonality and in drought frequencies revealed by a four-century-long tree-ring isotopic record from Brittany, western France

A new paleoclimatic reconstruction for western France is obtained from tree-ring cellulose stable isotopes. Living trees from Rennes Forest and beams from two ancient buildings in Rennes city have been combined to cover the past four centuries with a gap from 1730 to 1750. The cellulose ¹³C reflects the progressive changes in atmospheric CO₂ isotopic composition. The combined ¹³C and ¹⁸O measurements are used to propose a reconstruction of interannual fluctuations in local summer temperature and water stress. At the decadal time scale, the reconstructed water stress profile exhibits a significant similarity with the historical wine harvest dates, an indicator of warm and dry growth seasons, as well as with the summer central England and central Alps instrumental temperature records and climate model results. Combined with instrumental precipitation records from Paris, these reconstructions suggest a dramatic and widespread change in the seasonality of the precipitation at the beginning of the nineteenth century, with drier winters and wetter summers, which may have contributed to the Alpine glacier decline at the end of the Little Ice Age. The tree-ring isotope records also show a relationship with large-scale North Atlantic circulation changes and the interannual variability is modified between the nineteenth and twentieth centuries (7–8 year periodicities) and the seventeenth century (11–14 year periodicities). By classifying 20-year-long subsets of the reconstructed climatic parameters, we estimate that a decadal mean summer warming of 0.8±0.1°C induced extreme dry years to be 2.2±0.7 times more frequent.     

Petromagnetic and paleomagnetic characterization deposits at Mesozoic/Cenozoic boundary: The Tetritskaro section (Georgia)

Petromagnetic and magnetostratigraphic characteristics are obtained for the Tetritskaro section. The boundary layer at the Mesozoic/Cenozoic (K/T) boundary is fixed primarily by an abrupt rise in the paramagnetic magnetization (total Fe concentration) and, to a lesser degree, by an increase in the concentration of such magnetic minerals as goethite, hemoilmenite, and magnetite. The along-section distribution of titanomagnetite of volcanic origin and metallic iron of cosmic origin does not correlate with the K/T boundary and lithologic properties of the sediments.The boundary of the Mesozoic and Cenozoic geological eras lies within the reversed polarity chron C29r and is marked by an abrupt rise in the geomagnetic field paleointensity and an instability of paleomagnetic directions, rather than by a polarity change. The accumulation time of the boundary clay layer is about 1.5–2 kyr, while abrupt changes in the paleointensity and direction of the geomagnetic field encompass 30–40 kyr. Such long occurrence intervals of the events in question cannot be related to a short-term impact phenomenon.     

Control of wind strength and frequency in the Aral Sea basin during the late Holocene

Changing content of detrital input in laminated sediments traced by XRF scanning and microfacies analyses reflect prominent variations in sedimentation processes in the Aral Sea. A high-resolution record of titanium from a core retrieved in the northwestern Large Aral Sea allows a continuous reconstruction of wind strength and frequency in western Central Asia for the past 1500 yr. During AD 450–700, AD 1210–1265, AD 1350–1750 and AD 1800–1975, detrital inputs (bearing titanium) are high, documenting an enhanced early spring atmospheric circulation associated with an increase in intensity of the Siberian High pressure system over Central Asia. In contrast, lower titanium content during AD 1750–1800 and AD 1980–1985 reflects a diminished influence of the Siberian High during early spring with a reduced atmospheric circulation. A moderate circulation characterizes the time period AD 700–1150. Unprecedented weakened atmospheric circulation over western Central Asia are inferred during ca. AD 1180–1210 and AD 1265–1310 with a considerable decrease in dust storm frequency, sedimentation rates, lamination thickness and detrital inputs (screened at 40-μm resolution). Our results are concurrent with changes in the intensity of the Siberian High during the past 1400 yr as reported in the GISP2 Ice Core from Greenland.     

Magnetolithologic and magnetomineralogical characteristics of sediments at the Mesozoic/Cenozoic boundary: The Koshak section (Mangyshlak peninsula)

Results of a detailed petromagnetic study of sediments of the Koshak section, including the Mesozoic/Cenozoic (K/T) boundary, are presented. The rocks are shown to have a very low magnetization. A relatively high magnetization is characteristic of two thin clayey beds, one at the K/T boundary and the other 0.6 m above it: x up to 2.5 × 10^?9 m³/kg, M _s up to 0.6 × 10^?3 A m²/kg, and M _rs up to 0.4 × 10^?3 A m²/kg. This is related to relatively high concentrations of hemoilmenite (up to 0.2%), magnetite (up to 0.01%), and goethite (up to 0.24%) in these beds. It is evident that the distribution of these magnetic minerals is lithologically controlled (the predominant occurrence in clayey beds), which is expressed, in particular, in the relation between the paramagnetic (clayey) and diamagnetic (carbonate) contributions to the magnetization of the sediments. Thus, clayey interbeds are sharply distinguished by the value of the paramagnetic magnetization (M _p = (83–86) × 10^?5 A m²/kg) as compared with purely diamagnetic chalk (M _d = ?(26–35) × 10^?5 A m²/kg). Minor concentrations of metallic iron (up to ～0.002%) discovered in the sediments have a lithologically uncontrolled distribution (metallic iron is more often observed near the K/T boundary rather than in clayey beds). Most probably, magnetite, hemoilmenite, and goethite were accumulated mostly with clay and other terrigenous material, while fine particles of iron are likely to have been dispersed by air. The whole set of the data of this work suggests that the K/T boundary is not distinguished by characteristic magnetomineralogical and magnetolithologic features.     

Detrital and pedogenic magnetic mineral phases in the loess/palaeosol sequence at Lingtai (Central Chinese Loess Plateau)

A detailed rock magnetic investigation of loess/palaeosol samples from the section at Lingtai on the central Chinese Loess Plateau (CLP) is presented. Thermal demagnetisation of isothermal remanent magnetisation (IRM) and Curie temperature measurements suggest the presence of magnetite, maghemite and hematite as remanence carrying components. Bulk and grain size fractionated samples have been analysed using coercivity spectra of remanence acquisition/demagnetisation curves, which identify four main remanence carriers in different grain size fractions of loesses and palaeosols. A linear source mixing model quantifies the contribution of the four components which have been experimentally derived as dominating endmembers in specific grain size fractions. Up to two thirds of the total IRM of the palaeosols are due to slightly oxidised pedogenic magnetite. Two detrital components dominate up to 90% of the IRM of the loess samples and are ascribed to maghemite of different oxidation degree. Detrital hematite is present in all samples and contributes up to 10% of the IRM. The iron content of the grain size fractions gives evidence that iron in pedogenically grown remanence carriers does not originate from the detrital iron oxides, but rather from iron-bearing clays and mafic silicates. The contribution of pedogenic magnetite to the bulk IRM increases with the increasing degree of pedogenesis, which depends in turn on climate change.     

Effects of PCBs on reactive oxygen species (ROS) production by the immune cells of Paracentrotus lividus (Echinodermata)

The impact of four PCB congeners: 3,3',4,4'-tetrachlorobiphenyl (IUPAC congener #77), 3,3',4,4',5-pentachlorobiphenyl (IUPAC #126), 2,2',4,4',5,5'-hexachlorobiphenyl (IUPAC #153) and 3,3',4,4',5,5'-hexachlorobiphenyl (IUPAC #169) was investigated on the reactive oxygen species (ROS) production by coelomocytes of the echinoid Paracentrotus lividus, an important species in marine benthic ecosystems. PCBs were found to increase ROS production and to delay the time of peak production. These effects were stronger on bacteria-stimulated cells and were congener-specific: coplanar congeners (#77, 126 and 169) had more effect than the non-coplanar PCB #153. Among coplanar congeners, PCB #169 showed dose-dependent effects whereas PCB #77 and 126 were more toxic at high and low doses, respectively. The relative immunotoxicity of the different PCB congeners is discussed in the light of their structural properties and biological affinities.